GB169863A - Manufacture of azo dyestuffs and intermediate products - Google Patents
Manufacture of azo dyestuffs and intermediate productsInfo
- Publication number
- GB169863A GB169863A GB2209120A GB2209120A GB169863A GB 169863 A GB169863 A GB 169863A GB 2209120 A GB2209120 A GB 2209120A GB 2209120 A GB2209120 A GB 2209120A GB 169863 A GB169863 A GB 169863A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- diaminobenzene
- toluenesulphone
- monoacetyl
- monophthalamic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/24—Monoazo dyes prepared by diazotising and coupling from coupling components containing both hydroxyl and amino directing groups
- C09B29/28—Amino naphthols
- C09B29/30—Amino naphtholsulfonic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
Monoacidyldiaminodiarylsulphones are obtained by treating with acidylating agents diaminodiarylsulphones derived from phenylene- or naphthylene-diamines. According to examples, the following derivatives are obtained using acetic acid, acetic anhydride, benzoyl chloride or phthalic anhydride as acidylating agent in the presence of a solvent such as alcohol, ethyl acetate, or diluted acetic acid:-monoacetyl- or monobenzoyl-2 : 5 -diaminobenzene-1-p-toluenesulphone, the monophthalamic acid of 2 : 5 - diaminobenzene-1-p-toluenesulphone, monoacetyl - 2 : 5 - diaminobenzene-1-p-chlorobenzenesulphone, the monophthalamic acid of 2 : 5 - diaminobenzene 1 -p-chlorbenzenesulphone, monoacetyl - 2 : 4 - diaminobenzene-1-p-toluenesulphone, and monoacetyl - 1 : 4 - naphthylenediamine-2-p-toluenesulphone; the anils corresponding with the two -phthalamic acids are also described. 2 : 4 - Diaminobenzene-1-p-toluenesulphone is made by condensing 2 : 4 - dinitrochlorbenzene with p-toluenesulphinic acid and reducing. Azodyes are obtained by diazotizing the above monoacidyl derivatives and coupling in acid solution with b -naphthylamine or a derivative or substitution product thereof. Monoazo dyes are specified from monoacetyl-2 : 5 - diaminobenzene-1-p-toluenesulphone and 2-aminonaphthalene-6-sulphonic acid or 2 : 8 : 6-acid or phenyl - 2 : 8 : 6 - acid; monoethylcarboxy - 2 : 5 - diaminobenzene-1-p-toluenesulphone and 2 : 8 : 6-acid; monobenzoyl - 2 : 5 - diaminobenzene - 1-p-toluenesulphone and 2 : 8 : 6 - acid; the monophthalamic acid of 2 : 5 - diaminobenzene-1-p-toluenesulphone and 2 : 8 : 6 - acid or phenyl - 2 : 8 : 6 - acid; monoacetyl - 2 : 5 - diaminobenzene - 1-p-chlorobenzene-sulphone and 2 : 8 : 6 - acid; the monophthalamic acid of 2 : 5 - diaminobenzene-1-p-chlorobenzene-sulphone and 2 : 8 : 6 - acid; monoacetyl - 2 : 4 - diaminobenzene-1-p-toluenesulphone and 2-aminonaphthalene-6-sulphonic acid or 2 : 8 : 6-acid; monoacetyl - 1 : 4 - naphthylenediamine - 2 - p-toluenesulphone-6 (7)-sulphonic acid and ethyl-b -naphthylamine. A disazo dyestuff is prepared from the urea of 2 : 5 - diaminobenzene-1-p-toluenesulphone and 2 : 8 : 6-acid. The dyestuffs dye wool from an acid bath in orange-red to reddish-violet shades fast to washing and light.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2209120A GB169863A (en) | 1920-07-23 | 1920-07-23 | Manufacture of azo dyestuffs and intermediate products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2209120A GB169863A (en) | 1920-07-23 | 1920-07-23 | Manufacture of azo dyestuffs and intermediate products |
Publications (1)
Publication Number | Publication Date |
---|---|
GB169863A true GB169863A (en) | 1921-10-13 |
Family
ID=10173764
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2209120A Expired GB169863A (en) | 1920-07-23 | 1920-07-23 | Manufacture of azo dyestuffs and intermediate products |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB169863A (en) |
-
1920
- 1920-07-23 GB GB2209120A patent/GB169863A/en not_active Expired
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