GB169758A - Method of preparing colloidal metallic elements and compounds thereof - Google Patents
Method of preparing colloidal metallic elements and compounds thereofInfo
- Publication number
- GB169758A GB169758A GB1505520A GB1505520A GB169758A GB 169758 A GB169758 A GB 169758A GB 1505520 A GB1505520 A GB 1505520A GB 1505520 A GB1505520 A GB 1505520A GB 169758 A GB169758 A GB 169758A
- Authority
- GB
- United Kingdom
- Prior art keywords
- waste
- colloidal
- liquor
- cellulose
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0004—Preparation of sols
- B01J13/0034—Additives, e.g. in view of promoting stabilisation or peptisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Colloid Chemistry (AREA)
Abstract
Colloidal solutions of copper, silver, mercury, cerium, arsenic and antimony, or of their insoluble compounds, are prepared by treating these metals or their compounds for some time at temperatures above 100 DEG C. with waste sulphite cellulose liquor or waste soda cellulose liquor. The metal or its insoluble compound in the powder form may comprise the starting material; or a soluble salt of the metal may be added to the cellulose waste liquor and the metal or its insoluble compound formed therein during the process either by the addition of precipitants, such as alkali, or by the reducing action of the cellulose waste liquor itself, with or without other reducing agents, such as sulphuretted hydrogen. The colloidal product may be precipitated or purified in any known manner and utilized in medicine, veterinary surgery, tanning, the preparation of cosmetics, for the protection of plants, and the impregnation of wood or fabric. The colloidal products may be employed per se, or in conjunction with oil, resin and other organic emulsions, or with the addition of colloids or filling substances. In the case of plant protection, such materials as aluminium hydrate, aluminium sulphate, gypsum, barium carbonate, lime, or copper-lime mixtures may be added to the colloidal products. According to the examples:-(1) colloidal mercury is prepared by heating mercuric chloride with purified waste sulphite cellulose liquor, preferably with addition of caustic soda or potash; or by heating mercuric oxide with the lignine substances extracted from waste sulphite cellulose liquid in the known way; (2) copper sulphate, on heating with waste sulphate cellulose liquor and soda lye, is converted first into colloidal copper protoxide and then into colloidal copper; a similar result is obtained by heating powdered copper oxide with a mixture of waste soda cellulose liquor and waste sulphite cellulose liquor; (3) colloidal silver is obtained by the heat treatment of silver oxide with waste sulphite cellulose liquor; (4) colloidal sulphide of arsenic results from the introduction of sulphuretted hydrogen into a hot solution of arsenious acid in cellulose waste liquor.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1505520A GB169758A (en) | 1920-06-03 | 1920-06-03 | Method of preparing colloidal metallic elements and compounds thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1505520A GB169758A (en) | 1920-06-03 | 1920-06-03 | Method of preparing colloidal metallic elements and compounds thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
GB169758A true GB169758A (en) | 1921-10-03 |
Family
ID=10052233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1505520A Expired GB169758A (en) | 1920-06-03 | 1920-06-03 | Method of preparing colloidal metallic elements and compounds thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB169758A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2580025A (en) * | 1948-09-04 | 1951-12-25 | Standard Oil Dev Co | Antifouling pipe line enamel |
CN114835287A (en) * | 2022-04-15 | 2022-08-02 | 东北大学 | Method for circularly purifying metallurgical arsenic-containing acidic waste liquid and recycling sulfur |
-
1920
- 1920-06-03 GB GB1505520A patent/GB169758A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2580025A (en) * | 1948-09-04 | 1951-12-25 | Standard Oil Dev Co | Antifouling pipe line enamel |
CN114835287A (en) * | 2022-04-15 | 2022-08-02 | 东北大学 | Method for circularly purifying metallurgical arsenic-containing acidic waste liquid and recycling sulfur |
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