GB1598289A - Process for the catalytic cracking of hydrocarbon oils - Google Patents
Process for the catalytic cracking of hydrocarbon oils Download PDFInfo
- Publication number
- GB1598289A GB1598289A GB19801/78A GB1980178A GB1598289A GB 1598289 A GB1598289 A GB 1598289A GB 19801/78 A GB19801/78 A GB 19801/78A GB 1980178 A GB1980178 A GB 1980178A GB 1598289 A GB1598289 A GB 1598289A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- tin
- weight
- catalytic cracking
- cracking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 22
- 238000004523 catalytic cracking Methods 0.000 title claims description 14
- 229930195733 hydrocarbon Natural products 0.000 title claims description 14
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 13
- 239000003921 oil Substances 0.000 title claims description 11
- 239000003054 catalyst Substances 0.000 claims description 43
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 28
- 238000005336 cracking Methods 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 13
- 238000002474 experimental method Methods 0.000 claims description 12
- 229910000510 noble metal Inorganic materials 0.000 claims description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229910001385 heavy metal Inorganic materials 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 6
- 239000010457 zeolite Substances 0.000 claims description 6
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims description 5
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 239000001119 stannous chloride Substances 0.000 claims description 5
- 235000011150 stannous chloride Nutrition 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 238000005342 ion exchange Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- 239000000571 coke Substances 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 125000005609 naphthenate group Chemical group 0.000 description 2
- 150000003606 tin compounds Chemical class 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- YXTDAZMTQFUZHK-ZVGUSBNCSA-L (2r,3r)-2,3-dihydroxybutanedioate;tin(2+) Chemical compound [Sn+2].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O YXTDAZMTQFUZHK-ZVGUSBNCSA-L 0.000 description 1
- USYAMXSCYLGBPT-UHFFFAOYSA-L 3-carboxy-3-hydroxypentanedioate;tin(2+) Chemical compound [Sn+2].OC(=O)CC(O)(C([O-])=O)CC([O-])=O USYAMXSCYLGBPT-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000001609 comparable effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- -1 dilaurate Chemical compound 0.000 description 1
- VDEKURXOWJYWCG-UHFFFAOYSA-N dodecyltin Chemical compound CCCCCCCCCCCC[Sn] VDEKURXOWJYWCG-UHFFFAOYSA-N 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229940007163 stannous tartrate Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 description 1
- RWWNQEOPUOCKGR-UHFFFAOYSA-N tetraethyltin Chemical compound CC[Sn](CC)(CC)CC RWWNQEOPUOCKGR-UHFFFAOYSA-N 0.000 description 1
- JTGNPNLBCGBCMP-UHFFFAOYSA-N tetraoctylstannane Chemical compound CCCCCCCC[Sn](CCCCCCCC)(CCCCCCCC)CCCCCCCC JTGNPNLBCGBCMP-UHFFFAOYSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- SBXWFLISHPUINY-UHFFFAOYSA-N triphenyltin Chemical compound C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 SBXWFLISHPUINY-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7715318A FR2391264A1 (fr) | 1977-05-18 | 1977-05-18 | Procede de craquage catalytique d'hydrocarbures, et catalyseur pour la mise en oeuvre du procede |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1598289A true GB1598289A (en) | 1981-09-16 |
Family
ID=9191022
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB19801/78A Expired GB1598289A (en) | 1977-05-18 | 1978-05-16 | Process for the catalytic cracking of hydrocarbon oils |
Country Status (15)
Country | Link |
---|---|
JP (1) | JPS53142406A (pt) |
AR (1) | AR223462A1 (pt) |
AU (1) | AU519866B2 (pt) |
BE (1) | BE866885A (pt) |
BR (1) | BR7803074A (pt) |
CA (1) | CA1223835A (pt) |
DE (1) | DE2821308A1 (pt) |
ES (1) | ES469871A1 (pt) |
FR (1) | FR2391264A1 (pt) |
GB (1) | GB1598289A (pt) |
IN (1) | IN148037B (pt) |
IT (1) | IT1096215B (pt) |
MX (1) | MX148049A (pt) |
NL (1) | NL189919C (pt) |
ZA (1) | ZA782792B (pt) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2159168A (en) * | 1984-05-25 | 1985-11-27 | Gulf Research Development Co | Process for cracking high metals content feedstocks using a cracking catalyst mixture containing antimony and/or tin |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4255287A (en) | 1978-09-12 | 1981-03-10 | Phillips Petroleum Company | Cracking catalyst |
US4321129A (en) | 1978-09-12 | 1982-03-23 | Phillips Petroleum Company | Cracking process employing catalyst having combination of antimony and tin |
JPS5734188A (en) * | 1980-08-08 | 1982-02-24 | Nippon Oil Co Ltd | Fluid catalytic cracking of heavy petroleum including distillation residue |
EP0033791B1 (en) * | 1980-02-07 | 1985-05-15 | United Industries Corporation | Preparations containing cocodiethanolamide |
US5358630A (en) * | 1980-11-17 | 1994-10-25 | Phillips Petroleum Company | Regenerating zeolitic cracking catalyst |
US4397767A (en) * | 1982-02-12 | 1983-08-09 | Phillips Petroleum Company | Catalyst poisons passivated with tin compounds plus both sulfur and phosphorus |
JPS60258288A (ja) * | 1984-06-01 | 1985-12-20 | ガルフ・リサ−チ・エンド・デベロツプメント・コンパニ− | 接触分解方法 |
US4601815A (en) * | 1984-12-27 | 1986-07-22 | Betz Laboratories, Inc. | Passivation of FCC catalysts |
AU572733B2 (en) * | 1985-07-08 | 1988-05-12 | David Ambrose Brett | A method of fixing jambs |
US4889617A (en) * | 1986-03-24 | 1989-12-26 | Chevron Research Company | Method of suppressing sodium poisoning of cracking catalysts during fluid catalytic cracking |
JP6660458B1 (ja) * | 2018-12-27 | 2020-03-11 | 株式会社アマダホールディングス | 金型管理装置及び金型管理方法 |
JP6920273B2 (ja) * | 2018-12-27 | 2021-08-18 | 株式会社アマダ | 金型管理装置及び金型管理方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3711422A (en) * | 1970-09-08 | 1973-01-16 | Phillips Petroleum Co | Cracking catalyst restoration with antimony compounds |
US3977963A (en) * | 1975-04-17 | 1976-08-31 | Gulf Research & Development Company | Method of negating the effects of metals poisoning on cracking catalysts |
US4101417A (en) * | 1976-10-04 | 1978-07-18 | Gulf Research & Development Company | Method of negating the effects of metals poisoning on zeolitic cracking catalysts |
-
1977
- 1977-05-18 FR FR7715318A patent/FR2391264A1/fr active Granted
-
1978
- 1978-04-07 CA CA000300701A patent/CA1223835A/en not_active Expired
- 1978-04-10 IN IN260/DEL/78A patent/IN148037B/en unknown
- 1978-05-10 BE BE1008872A patent/BE866885A/xx not_active IP Right Cessation
- 1978-05-12 MX MX173489A patent/MX148049A/es unknown
- 1978-05-16 AR AR272195A patent/AR223462A1/es active
- 1978-05-16 ZA ZA00782792A patent/ZA782792B/xx unknown
- 1978-05-16 BR BR7803074A patent/BR7803074A/pt unknown
- 1978-05-16 JP JP5724878A patent/JPS53142406A/ja active Granted
- 1978-05-16 NL NLAANVRAGE7805233,A patent/NL189919C/xx not_active IP Right Cessation
- 1978-05-16 AU AU36152/78A patent/AU519866B2/en not_active Expired
- 1978-05-16 ES ES469871A patent/ES469871A1/es not_active Expired
- 1978-05-16 IT IT23450/78A patent/IT1096215B/it active
- 1978-05-16 DE DE19782821308 patent/DE2821308A1/de active Granted
- 1978-05-16 GB GB19801/78A patent/GB1598289A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2159168A (en) * | 1984-05-25 | 1985-11-27 | Gulf Research Development Co | Process for cracking high metals content feedstocks using a cracking catalyst mixture containing antimony and/or tin |
GB2159168B (en) * | 1984-05-25 | 1989-05-10 | Gulf Research Development Co | Process for cracking high metals content feedstocks using a cracking catalyst mixture containing antimony and/or tin |
Also Published As
Publication number | Publication date |
---|---|
FR2391264B1 (pt) | 1981-01-09 |
ZA782792B (en) | 1979-05-30 |
JPS53142406A (en) | 1978-12-12 |
DE2821308C2 (pt) | 1987-11-26 |
IT7823450A0 (it) | 1978-05-16 |
AR223462A1 (es) | 1981-08-31 |
BE866885A (nl) | 1978-11-10 |
BR7803074A (pt) | 1979-01-02 |
NL189919C (nl) | 1993-09-01 |
MX148049A (es) | 1983-03-09 |
AU519866B2 (en) | 1981-12-24 |
NL7805233A (nl) | 1978-11-21 |
CA1223835A (en) | 1987-07-07 |
JPS6328957B2 (pt) | 1988-06-10 |
DE2821308A1 (de) | 1978-11-30 |
AU3615278A (en) | 1979-11-22 |
IN148037B (pt) | 1980-10-04 |
FR2391264A1 (fr) | 1978-12-15 |
ES469871A1 (es) | 1978-12-16 |
IT1096215B (it) | 1985-08-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19970516 |