GB1588756A - Agent and process to make starch glues water insoluble - Google Patents
Agent and process to make starch glues water insoluble Download PDFInfo
- Publication number
- GB1588756A GB1588756A GB28557/77A GB2855777A GB1588756A GB 1588756 A GB1588756 A GB 1588756A GB 28557/77 A GB28557/77 A GB 28557/77A GB 2855777 A GB2855777 A GB 2855777A GB 1588756 A GB1588756 A GB 1588756A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glue
- starch
- formaldehyde
- cyanamide
- resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003292 glue Substances 0.000 title claims description 83
- 229920002472 Starch Polymers 0.000 title claims description 64
- 235000019698 starch Nutrition 0.000 title claims description 64
- 239000008107 starch Substances 0.000 title claims description 64
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 23
- 239000003795 chemical substances by application Substances 0.000 title claims description 17
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 84
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 19
- MVXMNHYVCLMLDD-UHFFFAOYSA-N 4-methoxynaphthalene-1-carbaldehyde Chemical compound C1=CC=C2C(OC)=CC=C(C=O)C2=C1 MVXMNHYVCLMLDD-UHFFFAOYSA-N 0.000 claims description 18
- 239000011111 cardboard Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 229920002261 Corn starch Polymers 0.000 claims description 12
- 239000008120 corn starch Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- PVLLDNCOXINNLS-UHFFFAOYSA-N cyanamide;potassium Chemical compound [K].[K].NC#N PVLLDNCOXINNLS-UHFFFAOYSA-N 0.000 claims description 11
- 235000013336 milk Nutrition 0.000 claims description 11
- 239000008267 milk Substances 0.000 claims description 11
- 210000004080 milk Anatomy 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 7
- 229920000294 Resistant starch Polymers 0.000 claims description 6
- 235000021254 resistant starch Nutrition 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000012429 reaction media Substances 0.000 claims description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 230000006978 adaptation Effects 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 240000003183 Manihot esculenta Species 0.000 claims description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 2
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000002474 experimental method Methods 0.000 claims description 2
- 238000007689 inspection Methods 0.000 claims description 2
- 239000002655 kraft paper Substances 0.000 claims description 2
- 229920001592 potato starch Polymers 0.000 claims description 2
- 238000009877 rendering Methods 0.000 claims description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 26
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 24
- 235000019256 formaldehyde Nutrition 0.000 description 18
- 229960004279 formaldehyde Drugs 0.000 description 18
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical compound [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 13
- 229940072033 potash Drugs 0.000 description 12
- 235000015320 potassium carbonate Nutrition 0.000 description 12
- 229910000027 potassium carbonate Inorganic materials 0.000 description 7
- 235000011181 potassium carbonates Nutrition 0.000 description 7
- WUCWIJJTGDSQNU-UHFFFAOYSA-N dipotassium iminomethylideneazanide Chemical compound [K+].[K+].N=C=[N-].N=C=[N-] WUCWIJJTGDSQNU-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001912 cyanamides Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000005997 Calcium carbide Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 description 2
- ICGQLNMKJVHCIR-UHFFFAOYSA-N 1,3,2-dioxazetidin-4-one Chemical compound O=C1ONO1 ICGQLNMKJVHCIR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000024675 Eruca sativa Species 0.000 description 1
- 235000014755 Eruca sativa Nutrition 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- ZNGJJFVBATWVCO-UHFFFAOYSA-N calcium;iminomethylideneazanide Chemical compound [Ca+2].[NH-]C#N.[NH-]C#N ZNGJJFVBATWVCO-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- FXKSOWVXKXQPLQ-UHFFFAOYSA-N potassium cyanoazanide Chemical compound [K]NC#N FXKSOWVXKXQPLQ-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7621140A FR2357624A1 (fr) | 1976-07-09 | 1976-07-09 | Agent et procede pour insolubiliser les colles d'amidon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1588756A true GB1588756A (en) | 1981-04-29 |
Family
ID=9175538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28557/77A Expired GB1588756A (en) | 1976-07-09 | 1977-07-07 | Agent and process to make starch glues water insoluble |
Country Status (10)
| Country | Link |
|---|---|
| BE (1) | BE856609A (enrdf_load_stackoverflow) |
| DE (1) | DE2637391C3 (enrdf_load_stackoverflow) |
| DK (1) | DK143945C (enrdf_load_stackoverflow) |
| ES (1) | ES460603A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2357624A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1588756A (enrdf_load_stackoverflow) |
| IT (1) | IT1081533B (enrdf_load_stackoverflow) |
| NL (1) | NL186456C (enrdf_load_stackoverflow) |
| NO (1) | NO147074C (enrdf_load_stackoverflow) |
| SE (1) | SE438683B (enrdf_load_stackoverflow) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE839794C (de) * | 1949-11-23 | 1952-04-17 | American Cyanamid Company, New York,· N. Y. (V. St. A) | Verfahren zur Herstellung eines ein saures Alkalicyanamid enthaltenden Produktes |
| US3019120A (en) * | 1959-03-25 | 1962-01-30 | Hubinger Co | Adhesive compositions |
-
1976
- 1976-07-09 FR FR7621140A patent/FR2357624A1/fr active Granted
- 1976-08-19 DE DE2637391A patent/DE2637391C3/de not_active Expired
-
1977
- 1977-07-05 SE SE7707841A patent/SE438683B/xx not_active IP Right Cessation
- 1977-07-06 NO NO772408A patent/NO147074C/no unknown
- 1977-07-07 DK DK308277A patent/DK143945C/da not_active IP Right Cessation
- 1977-07-07 GB GB28557/77A patent/GB1588756A/en not_active Expired
- 1977-07-08 NL NLAANVRAGE7707619,A patent/NL186456C/xx not_active IP Right Cessation
- 1977-07-08 BE BE179175A patent/BE856609A/xx not_active IP Right Cessation
- 1977-07-08 IT IT25538/77A patent/IT1081533B/it active
- 1977-07-09 ES ES460603A patent/ES460603A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL186456B (nl) | 1990-07-02 |
| DK308277A (da) | 1978-01-10 |
| NL7707619A (nl) | 1978-01-11 |
| DE2637391A1 (de) | 1978-01-12 |
| FR2357624B1 (enrdf_load_stackoverflow) | 1978-12-15 |
| SE7707841L (sv) | 1978-01-10 |
| DK143945B (da) | 1981-11-02 |
| BE856609A (fr) | 1978-01-09 |
| NO772408L (no) | 1978-01-10 |
| IT1081533B (it) | 1985-05-21 |
| DK143945C (da) | 1982-04-19 |
| NO147074B (no) | 1982-10-18 |
| NL186456C (nl) | 1990-12-03 |
| ES460603A1 (es) | 1978-12-01 |
| NO147074C (no) | 1983-01-26 |
| DE2637391B2 (de) | 1979-11-29 |
| FR2357624A1 (fr) | 1978-02-03 |
| DE2637391C3 (de) | 1980-08-28 |
| SE438683B (sv) | 1985-04-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19970706 |