GB1587894A - Thermoplastic resin compositions - Google Patents
Thermoplastic resin compositions Download PDFInfo
- Publication number
- GB1587894A GB1587894A GB10503/78A GB1050378A GB1587894A GB 1587894 A GB1587894 A GB 1587894A GB 10503/78 A GB10503/78 A GB 10503/78A GB 1050378 A GB1050378 A GB 1050378A GB 1587894 A GB1587894 A GB 1587894A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- glass
- thermoplastic resin
- microns
- note
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011342 resin composition Substances 0.000 title claims description 24
- 229920005992 thermoplastic resin Polymers 0.000 title claims description 21
- 239000000203 mixture Substances 0.000 claims description 40
- 239000000654 additive Substances 0.000 claims description 36
- 239000000835 fiber Substances 0.000 claims description 18
- 239000003365 glass fiber Substances 0.000 claims description 18
- 230000000996 additive effect Effects 0.000 claims description 17
- 239000000945 filler Substances 0.000 claims description 17
- 239000011521 glass Substances 0.000 claims description 11
- -1 polybutylene terephthalate Polymers 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 8
- 239000010445 mica Substances 0.000 claims description 7
- 229910052618 mica group Inorganic materials 0.000 claims description 7
- 239000012779 reinforcing material Substances 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011324 bead Substances 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 5
- 239000000920 calcium hydroxide Substances 0.000 claims description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 229920006324 polyoxymethylene Polymers 0.000 claims description 4
- AGVJBLHVMNHENQ-UHFFFAOYSA-N Calcium sulfide Chemical compound [S-2].[Ca+2] AGVJBLHVMNHENQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005909 Kieselgur Substances 0.000 claims description 3
- 229930182556 Polyacetal Natural products 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 239000002178 crystalline material Substances 0.000 claims description 3
- 239000011888 foil Substances 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052622 kaolinite Inorganic materials 0.000 claims description 3
- 229920002521 macromolecule Polymers 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- 235000012241 calcium silicate Nutrition 0.000 claims description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229920006122 polyamide resin Polymers 0.000 claims description 2
- 229920005989 resin Polymers 0.000 description 20
- 239000011347 resin Substances 0.000 description 20
- 238000000465 moulding Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000002657 fibrous material Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 238000000137 annealing Methods 0.000 description 3
- 239000012778 molding material Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920006038 crystalline resin Polymers 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003405 preventing effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
(54) THERMOPLASTIC RESIN COMPOSITIONS
(71) We, POLYPLASTICS COMPANY LIMITED, a Japanese Company of 30, 2-chome Azuchimachi, Higashi-ku, Osaka-shi, Japan, do hereby declare the invention for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:
This invention relates to thermoplastic resin compositions useful as molding materials which have small rates of heat deformation and high strength.
Although thermoplastic resins have been used per se for producing various molded articles-, they have also been used as compositions containing reinforcing materials such as glass fibers in such applications as the production of substrate plates, which will require higher rigidity and strength.
Further, for the purpose of imparting and improving the electroconductivity and incombustibility of thermoplastic resins, the addition of fibers, particles, etc. has also been conducted.
However, compositions which contain fibrous additives have a larger anisotropy in general, resulting in the deformation of molded articles during the molding or annealing thereof.
Although such deformation is a common phenomenon to be seen in thermoplastic resins, this phenomenon is particularly remarkable in such resins having a high crystallization during the molding as polyacetal and polybutylene terephthalate, and also in such resins whose crystallization is advanced by annealing as polyethylene terephthalate.
These resins are subject to a considerable deformation even per se. Accordingly, their adaptability as molding materials should be determined with an emphasis on the balance between their deformation properties and their rigidity and strength properties, as well as their chemical and thermal properties.
The balance between deformation and physical properties is important particularly in producing such materials as substrate plates and boxes. Looking at the conventionally employed raw materials from this standpoint, virgin resins, though their deformation is relatively small, are inferior in rigidity, and compositions containing particles are small in strength, though their deformation is relatively; small; and, on the contrary, compositions containing fibrous materials are relatively large in deformation, although their strength and rigidity are high. It is therefore very difficult to improve rigidity and other physical properties without deteriorating deformation, and, particularly, there are now no available satisfactory compositions for crystalline resins.
The inventors have investigated the phenomenon of deformation of thermoplastic resins and discovered that compositions which contain fibrous reinforcing materials and platelet fillers in combination are high in physical strength and are subject only to small deformation.
The balance of deformation and strength is an important criterion for all resins and thus the compositions according to this invention are useful regardless.of types of the base resin.
Although polyacetals, polybutylene terephthalate, polyethylene terephthalate and polyamides are optimum to be used as precision functional components owing to their chemical, thermal, and frictional properties, molding materials containing these resins as base resins are subject to significant deformation during molding or annealing and thus improved grades of such resin compositions have been desired; under such circumstances, this invention will bring about large economical effects particularly when these resins are employed as base resins.
The thermoplastic resin compositions according to the present invention, employing these resins as base resins, are, particularly in a composition range which will show a relatively small amount of deformation, subject to a smaller absolute amount of deformation even if compared with non-filled or particle filled ones, the latter of which have been said to show the smallest deformation, as well as compared to the conventional fiber-reinforced compositions.
Needless to say, such compositions according to this invention have a higher strength than that of particle filled compositions and remarkably better in the balance of the both qualities, i.e., deformation and strength.
The thermoplastic resin compositions according to this invention are thermoplastic resin compositions characterized by incorporating therein based on the total weight of the composition 1 to 50 weight percent fibrous additives and 5 to 59 weight percent platelet fillers in a range where the whole amount of the both does not exceed 60 weight percent of the total composition.
Fibrous additives to be used in this invention include glass fibers, carbon fibers, graphite fibers, metal fibers, silicon carbide fibers, mineral fibers e.g. asbestos and wollastonite, and organic fiber materials. These additives are used for such various purposes as increasing physical strength, imparting electroconductivity, improving frictional properties, and improving flame resistance. When such fibrous additive is used alone, the length/diameter ratio thereof should be preferably small in order to make the deformation of the resin composition small; e.g. in the case of glass fibers of about 10 micron diameter, the deformation of a resin composition containing 20 to 50 percent (by weight) of a fibrous additive having a length of 100 to 200 microns alone will be relatively small.However, in the resin compositions according to this invention, longer fibers are preferable and, for example, in the case of glass fibers of about 10 micron diameter, the glass fibers having a length of 300 to 600 microns will be preferable.
However, an excessive length of fibers in the compositions will remarkably deteriorate the moldability of the resin composition, and therefore a fiber length of less than one millimeter is desirable.
The platelet fillers to be used in this invention are preferably dry-crushed mica and glass platelets having a diameter of tens to hundreds of microns, but platelet minerals such as sericite having a diameter of several to tens of microns may be employed. Those having a smaller diameter or a smaller diameter/thickness ratio will not be as effective as platelet fillers and may deteriorate the moldability of the resin composition excessively. Talc, kaolinite, bilofilite, and metal foils may also be used as platelet fillers.
Although the addition of such platelet additives will improve electrical and frictional properties of the resin composition and will be more effective against the deformation of the molded products than the addition of particles (for this purpose, the addition of 1 to 60 percent by weight, particularly 30 to 50 percent is preferable), the combination of platelet fillers with fibrous materials according to this invention is much more effective.
Fibrous additives in the compositions according to this invention bring about unexpected unique effects as explained below as well as the improvement of rigidity and strength of the molded products.
Thus the deformation of the molded product when a fibrous material alone is added will be substantial at a low density of less than 10 weight percent and rather small at a high density of 30 to 40 weight percent as the fibrous additive content. However, when a fibrous material and a platelet filler are used together according to this invention, the deformation of the molded product will be smallest at a low density of 2 to 20 weight percent, particularly 3 to 10 weight percent, as the fibrous material content. In the case of crystalline resins, it is small even compared to the case when particle fillers are used.
Accordingly, the addition of 2 to 20 weight percent, particularly 3 to 10 weight percent of the fibrous additive will be preferable. However when rigidity should be especially emphasized or in the case electroconductivity is required, a higher density of the fibrous additive may be used; even in this case, the deformation of the molded product will be small compared to the case where a fibrous additive is used alone or it is used with an additive in the form of particles.
As mentioned above, a platelet filler used in this invention exhibits its unique deformation reduction effect owing to its synergistic action with a fibrous additive and a smaller reduction of strength compared with a particle-like additive.
The more platelet filler is added the larger is its deformation preventing effect. and, as the reduction of strength of the moulded product is relatively small, the amount used should be preferably large. However an excessive amount affects the mouldability of the resin composition. About 60 weight percent of the platelet filler is practically the upper limit of the total amount of the platelet filler with the fibrous reinforcing material. About 30 to 50 weight percent of the total amount of the additives is preferable. When a lower elasticity of the moulded product is preferable, lower densities of the additives may be used.
A particulate additive may also be included in the compositions of the invention in a range where the mouldability of the resin composition is not remarakbly deteriorated. Such particulate additives include magnesium hydroxide, calcium sulphide, clay, diatomaceous earth, alumina glass beads, calcium hydroxide, quartz powder, siliceous sand, glass powder, metal powder, antimony trioxide, graphite, organic macromolecules e.g. fluorine resins, and organic crystalline material e.g, brominatèd diphenyl. The particulate additives may be used for the purpose of reducing the amount of platelet fillers to be used. Further, they can be used for the purpose of improving the electroconductivity, flame retardance, and frictional properties of the molded product, which are characteristic of such particle additives.Those various additives may be used without any pretreatment or with a surface treatment by use of compounds of for example silane or titanium.
These treatments are useful for improving physical properties and fluidity of the resin composition. Base resins and the above various kinds of additives may be of one type respectively or two or more types thereof may be used together.
The compositions according to this invention may contain other ingredients such as antistatic agents, coloring agents, lubricants, stabilizers and flame retarders.
The thermoplastic resin compositions according to this invention may be easily prepared by the methods which have been usually employed for the preparation of reinforced plastic resins and filler-incorporated resins.
For example, respective additives can be mixed with the base resin by means of an extruding machine to produce resin pellets having the composition according to this invention, which can then be molded. (In this case, the fibrous additive may be used in a bundled or non-bundled state or as long or short fibers.) Further, pellets having different compositions can be mixed in molding, or respective components can be directly charged into a moulding machine.
The effects of this invention will be shown below by employing polybutylene terephthalate, which is particularly suitable to the present invention, as an example.
The invention is hereinafter particularly described and illustrated by the accompanying drawings, and the Examples.
The accompanying drawings show the test pieces used in the Examples and Comparative
Examples. Figure 1 is a plan view and Figure 2 is a cross-sectional view.
Examples 1 to 10
The resin mixtures containing the additives having the compositions as described in Table, respectively, which comprise polybutylene terephthalate as the base resin were extruded through an extruding machine of 300 mm diameter to produce pellets. The glass fiber was used as bundled fibers of 6 mm length.
From these pellets, plate test pieces as shown in Figures 1 and 2 were molded, the test pieces containing a projection, depression and holes to simulate practical mouldings. The difference between the highest part and the lowest part in the test piece was measured, which was taken as the amount of deformation. Further, the load at break was measured by supporting the circumference of the test piece and compressing the center part thereof, which was taken as strength.
The ratio of the both was calculated, taking it as a measure of balance between deformation and strength. The results are shown in Table.
Explanation of the symbols shown in Figures 1 and 2 and the dimensions of the test piece are shown below:
X : lateral width of test plate . .. 50 (unit: mm.
the following
are the same)
Y : longitudinal width of test plate . . 45
t : thickness of test plate . . 2
1 : moulding gate . . pin of
1.5 mm
diameter
(The following parts are indicated by
their co-ordinates, of which the
original point is the moulding gate 1.) 2 : projection on the plate surface, the co-ordinates
of the center thereof (2.25 mm, 2 mm), diameter
3 mm, height 2.5 mm
3 : hole, the co-ordinates of the center
thereof (0, 1.25), diameter 5 mm 4 : hole, the co-ordinates of the center
thereof (-1.5, 1.25), diameter 5 mm
5 : hole, the co-ordinates of the center
thereof (0, -1.5), diameter 8 mm
6 : circular depression on the plate surface, the co-ordinates
of the center thereof (1.5, -1), diameter 15 mm,
depth 1 mm
Comparative Examples 1 to 10
The deformation and strength were measured in the same manner as shown in the
Examples on various resin compositions to be compared with those compositions according to the present invention as exemplified in Examples 1 to 10. The results are shown in Table 2.
The comparison of the two tables indicates that the compositions according to the present invention are good materials having larger ratios of strength/deformation than those of the
Comparative Examples. Further, the absolute amounts of deformation are smaller in the optimum composition of the Examples. compared to the Comparative Examples. Table 1
Compositions (% by weight)
Examples Glass Mica Glass Calcium Strength Deformation Ratio of
Fiber (3) Bead Hydroxide (Kg) (mm) Strength/Deformation (1) (4) (5) 1 20 10 35.1 0.605 58.0 2 20 20 35.2 0.594 59.3 3 10 30 31.0 0.444 69.8 4 3 40 24.5 0.305 78.7 5 20 20 10 33.2 0.575 57.7 6 10 15 15 30.5 0.541 56.4 7 3 20 20 23.9 0.320 74.7 8 20 10 20 32.8 0.625 52.5 9 6 20 15 27.2 0.410 66.3 10 3 20 20 22.3 0.380 58.7 Table 2
Compositions (% by weight)
Comparative Strength Deformation Ratio of examples Additive Amount Additive Amount (Kg) (mm) Strength/Deformation 1 Glass Fiber 30 36.1 0.777 46.5 (1) 2 Glass Fiber 10 31.5 1.240 25.4 (1) 3 Glass Fiber 30 28.0 0.598 46.8 (2) 4 Mica (3) 40 25.5 0.501 50.9 5 Glass Bead 30 24.6 0.501 49.1 (4) 6 Calcium 50 24.5 0.522 46.9
Hydroxide (5) 7 Wollasto- 40 26.8 0.525 51.0 nite (6) 8 Glass Fiber 15 Calcium 25 29.0 0.824 35.2 (1) Hydroxide 9 Glass Fiber 30 Glass 10 34.1 0.922 37.0 (1) Bead 10 Glass Fiber 15 Calcium 35 14.4 0.663 21.7 (2) Hydroxide 11 Mica 20 Glass 20 24.5 0.515 47.6
Bead Note 1: Glass Fiber (1) average length of 400 microns,
10 micron diameter
Note 2 : Glass Fiber (2) average length of 100 microns,
10 microns diameter
Note 3 : Mica crushed product, tens of
microns diameter
Note 4 : Glass Bead 6 to 66 microns
Note 5 : Calcium heavy calcium hydroxide,
Hydroxide several microns
Note 6 :. Wollastonite calcium metasilicate produced
in U.S.A.
WHAT WE CLAIM IS:
1. A thermoplastic resin composition comprising a thermoplastic resin containing as additives from 1 to 50 percent by weight, based on the total weight of the composition, of a fibrous reinforcing material, and from 5 to 59 percent by weight of a platelet filler, wherein the sum of the said additives does not exceed 60 weight percent of the total composition.
2. A composition as claimed in Claim 1, wherein the said fibrous reinforcing material is glass fibre, carbon fibre, graphite fibre, metal fibres, silicon-carbide fibre, mineral fibres or an organic fibre material.
3. A composition as claimed in Claim 1 or Claim 2, wherein the said platelet filler is mica, glass platelets, sericite, talc, kaolinite, bilofilite or metal foils.
4. A composition as claimed in Claim 1, wherein a particulate additive is incorporated in said composition.
5. A composition as claimed in Claim 4, wherein the said particulate additive is particulate calcium hydroxide, magnesium hydroxide, calcium sulphide, clay, diatomaceous earth, alumina, quartz powder, siliceous sand, glass beads, glass powder, metal powder, antimony trioxide, graphite, organic macromolecules or organic crystalline material.
6. A thermoplastic resin composition as claimed in any of Claims 1 to 5, wherein the said thermoplastic resin is a polyacetal, polybutylene terephthalate, polyethylene terephthalate or a polyamide resin.
7. A thermoplastic resin composition as claimed in Claim 1, substantially as hereinbefore described, with particular reference to the Examples.
**WARNING** end of DESC field may overlap start of CLMS **.
Claims (7)
- **WARNING** start of CLMS field may overlap end of DESC **.Note 1: Glass Fiber (1) average length of 400 microns,10 micron diameter Note 2 : Glass Fiber (2) average length of 100 microns,10 microns diameter Note 3 : Mica crushed product, tens of microns diameter Note 4 : Glass Bead 6 to 66 microns Note 5 : Calcium heavy calcium hydroxide, Hydroxide several microns Note 6 :. Wollastonite calcium metasilicate produced in U.S.A.WHAT WE CLAIM IS: 1. A thermoplastic resin composition comprising a thermoplastic resin containing as additives from 1 to 50 percent by weight, based on the total weight of the composition, of a fibrous reinforcing material, and from 5 to 59 percent by weight of a platelet filler, wherein the sum of the said additives does not exceed 60 weight percent of the total composition.
- 2. A composition as claimed in Claim 1, wherein the said fibrous reinforcing material is glass fibre, carbon fibre, graphite fibre, metal fibres, silicon-carbide fibre, mineral fibres or an organic fibre material.
- 3. A composition as claimed in Claim 1 or Claim 2, wherein the said platelet filler is mica, glass platelets, sericite, talc, kaolinite, bilofilite or metal foils.
- 4. A composition as claimed in Claim 1, wherein a particulate additive is incorporated in said composition.
- 5. A composition as claimed in Claim 4, wherein the said particulate additive is particulate calcium hydroxide, magnesium hydroxide, calcium sulphide, clay, diatomaceous earth, alumina, quartz powder, siliceous sand, glass beads, glass powder, metal powder, antimony trioxide, graphite, organic macromolecules or organic crystalline material.
- 6. A thermoplastic resin composition as claimed in any of Claims 1 to 5, wherein the said thermoplastic resin is a polyacetal, polybutylene terephthalate, polyethylene terephthalate or a polyamide resin.
- 7. A thermoplastic resin composition as claimed in Claim 1, substantially as hereinbefore described, with particular reference to the Examples.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3704277A JPS53121843A (en) | 1977-04-01 | 1977-04-01 | Thermoplastic resin mold composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1587894A true GB1587894A (en) | 1981-04-15 |
Family
ID=12486534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB10503/78A Expired GB1587894A (en) | 1977-04-01 | 1978-03-16 | Thermoplastic resin compositions |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS53121843A (en) |
| AU (1) | AU522577B2 (en) |
| BE (1) | BE865101A (en) |
| BR (1) | BR7801739A (en) |
| DE (1) | DE2811795A1 (en) |
| FR (1) | FR2393016A1 (en) |
| GB (1) | GB1587894A (en) |
| IT (1) | IT1095554B (en) |
| MX (1) | MX149060A (en) |
| NL (1) | NL7803537A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2117388A (en) * | 1982-03-19 | 1983-10-12 | Hepworth Plastics Ltd | Moulding compounds |
| US4806586A (en) * | 1987-03-25 | 1989-02-21 | Polyplastics Co., Ltd. | Reinforced molding resin composition |
| US7019048B2 (en) * | 2001-02-10 | 2006-03-28 | Merck Gesellschaft Mit Beschraenkter Haftung | Plastic part comprising lustrous pigments and filler particles |
| US7713460B2 (en) | 1995-04-27 | 2010-05-11 | Tech-Wood International Ltd. | Method and apparatus for manufacturing of plastic-based composite product |
| US8404763B2 (en) | 2008-06-11 | 2013-03-26 | Wintech Polymer Ltd. | Method for forming an insert injection-molded article exhibiting improved resistance to heat shock comprising a specifically defined polybutylene terephthalate composition |
| US20200224028A1 (en) * | 2017-10-03 | 2020-07-16 | Mitsubishi Engineering-Plastics Corporation | Thermoplastic resin composition, resin molding, method for manufacturing plated resin molding, and method for manufacturing portable electronic device part |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6017223B2 (en) * | 1977-05-25 | 1985-05-01 | 帝人株式会社 | polyester composition |
| US4168259A (en) * | 1977-07-11 | 1979-09-18 | Gaf Corporation | Glass reinforced PBT resins |
| US4195011A (en) * | 1977-07-11 | 1980-03-25 | Gaf Corporation | Injection molding compositions |
| US4212791A (en) * | 1979-02-23 | 1980-07-15 | Rohm And Haas | Poly(alkyleneterephthalate) molding compositions containing oligomeric polyester and segmented copolyester-polyether elastomer |
| JPS56100845A (en) * | 1980-01-17 | 1981-08-13 | Mitsubishi Chem Ind Ltd | Polyester resin composition |
| JPS56114854A (en) * | 1980-02-08 | 1981-09-09 | Asahi Chemical Ind | Resin porous sintered body containing inorganic substance |
| DE3011902C2 (en) * | 1980-03-27 | 1996-11-28 | Siemens Ag | Optoelectronic coupling device |
| JPS5763355A (en) * | 1980-10-03 | 1982-04-16 | Dainippon Ink & Chem Inc | Mica reinforced polyallylene sulfide resin composition |
| JPS57137762A (en) * | 1981-02-18 | 1982-08-25 | Aisin Chem Co Ltd | Resin made gear for engine |
| US4404125A (en) * | 1981-10-14 | 1983-09-13 | General Electric Company | Polyphenylene ether resin compositions for EMI electromagnetic interference shielding |
| BE894510A (en) * | 1981-11-04 | 1983-01-17 | Dart Ind Inc | COMPOSITIONS CONTAINING POLYETHYLENE TEREPHALATE AND ANTIMONY OXIDE, AND THEIR PREPARATION |
| JPS58127761A (en) * | 1982-01-25 | 1983-07-29 | Dai Ichi Seiko Co Ltd | High specific gravity composite material reinforced with organic fiber |
| JPS58206663A (en) * | 1982-05-25 | 1983-12-01 | Toyobo Co Ltd | Polyester composition |
| US4610808A (en) * | 1982-07-19 | 1986-09-09 | Mitech Corporation | Conductive resinous composites |
| JPS59189170A (en) * | 1983-04-13 | 1984-10-26 | Polyplastics Co | Thermoplastic resin molding composition |
| JPH01144452A (en) * | 1987-11-30 | 1989-06-06 | Toyobo Co Ltd | Polyester composition |
| KR890017296A (en) * | 1988-05-18 | 1989-12-15 | 나가이 아쯔시 | Olefin-based resin composite composition for molding, molded article thereof, slide member and tape guide, molded cartridge and magnetic tape cartridge |
| DE4040602A1 (en) * | 1990-12-19 | 1992-07-02 | Schock & Co Gmbh | CAST PLASTIC PARTS |
| DK0830424T3 (en) * | 1995-04-27 | 2003-02-24 | Tech Wood Internat Ltd | Composite product based on plastic material and method and apparatus for making same |
| JP2960334B2 (en) * | 1995-06-07 | 1999-10-06 | ポリプラスチックス株式会社 | Fiber reinforced polybutylene terephthalate resin composition |
| ATE556833T1 (en) | 2003-03-17 | 2012-05-15 | Tech Wood Internat Ltd | METHOD FOR PRODUCING A REINFORCED PLASTIC PROFILE |
| JP5911426B2 (en) * | 2010-09-30 | 2016-04-27 | ユニチカ株式会社 | Polyamide resin composition and molded product obtained therefrom |
| CN103522560B (en) * | 2013-10-14 | 2015-08-19 | 哈尔滨工业大学 | The preparation method of a kind of uvioresistant, heat-resisting BOPET film |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2064432B1 (en) * | 1969-10-20 | 1974-09-20 | Eastman Kodak Co | |
| GB1369589A (en) * | 1970-11-18 | 1974-10-09 | Tba Industrial Products Ltd | Thermoplastic moulding compositions |
| JPS4920930A (en) * | 1972-06-17 | 1974-02-23 | ||
| JPS4974224A (en) * | 1972-11-17 | 1974-07-17 | ||
| US3931094A (en) * | 1973-07-02 | 1976-01-06 | Allied Chemical Corporation | Filled thermoplastic containing fibrous dispersion aid |
| DE2408531B2 (en) * | 1974-02-22 | 1979-12-06 | Basf Ag, 6700 Ludwigshafen | Glass fiber reinforced polyester molding compounds with reduced flammability |
| CA1035880A (en) * | 1974-05-07 | 1978-08-01 | Polysar Limited | Filled polystyrene composition |
| GB1485271A (en) * | 1974-08-05 | 1977-09-08 | Ici Ltd | Thermoplastic polyester composition |
| DE2444584C3 (en) * | 1974-09-18 | 1982-01-21 | Basf Ag, 6700 Ludwigshafen | Thermoplastic polyester molding compounds |
| GB1537240A (en) * | 1975-04-03 | 1978-12-29 | Tba Industrial Products Ltd | Process for producing thermoplastic moulding compositions |
| JPS51136736A (en) * | 1975-05-22 | 1976-11-26 | Mitsui Toatsu Chem Inc | Polyolefin composition |
| US4124561A (en) * | 1976-12-06 | 1978-11-07 | General Electric Company | Reinforced thermoplastic polyester compositions having improved shatter resistance |
| GB1592205A (en) * | 1976-12-23 | 1981-07-01 | Gen Electric | Reinforced thermoplastic compositions of polyester resins and glass fibers in combination with fine ground mica |
-
1977
- 1977-04-01 JP JP3704277A patent/JPS53121843A/en active Granted
-
1978
- 1978-03-16 GB GB10503/78A patent/GB1587894A/en not_active Expired
- 1978-03-17 DE DE19782811795 patent/DE2811795A1/en active Granted
- 1978-03-21 BR BR7801739A patent/BR7801739A/en unknown
- 1978-03-21 BE BE2056780A patent/BE865101A/en unknown
- 1978-03-27 MX MX172867A patent/MX149060A/en unknown
- 1978-03-29 FR FR7809151A patent/FR2393016A1/en active Granted
- 1978-03-30 IT IT21772/78A patent/IT1095554B/en active
- 1978-03-31 AU AU34658/78A patent/AU522577B2/en not_active Expired
- 1978-04-03 NL NL7803537A patent/NL7803537A/en not_active Application Discontinuation
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2117388A (en) * | 1982-03-19 | 1983-10-12 | Hepworth Plastics Ltd | Moulding compounds |
| US4806586A (en) * | 1987-03-25 | 1989-02-21 | Polyplastics Co., Ltd. | Reinforced molding resin composition |
| US7713460B2 (en) | 1995-04-27 | 2010-05-11 | Tech-Wood International Ltd. | Method and apparatus for manufacturing of plastic-based composite product |
| US7019048B2 (en) * | 2001-02-10 | 2006-03-28 | Merck Gesellschaft Mit Beschraenkter Haftung | Plastic part comprising lustrous pigments and filler particles |
| US8404763B2 (en) | 2008-06-11 | 2013-03-26 | Wintech Polymer Ltd. | Method for forming an insert injection-molded article exhibiting improved resistance to heat shock comprising a specifically defined polybutylene terephthalate composition |
| US20200224028A1 (en) * | 2017-10-03 | 2020-07-16 | Mitsubishi Engineering-Plastics Corporation | Thermoplastic resin composition, resin molding, method for manufacturing plated resin molding, and method for manufacturing portable electronic device part |
Also Published As
| Publication number | Publication date |
|---|---|
| BE865101A (en) | 1978-07-17 |
| FR2393016A1 (en) | 1978-12-29 |
| FR2393016B1 (en) | 1984-01-06 |
| DE2811795A1 (en) | 1978-10-12 |
| DE2811795C2 (en) | 1993-03-25 |
| AU522577B2 (en) | 1982-06-17 |
| JPS6229450B2 (en) | 1987-06-26 |
| MX149060A (en) | 1983-08-16 |
| NL7803537A (en) | 1978-10-03 |
| JPS53121843A (en) | 1978-10-24 |
| AU3465878A (en) | 1979-10-04 |
| BR7801739A (en) | 1978-12-19 |
| IT1095554B (en) | 1985-08-10 |
| IT7821772A0 (en) | 1978-03-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1587894A (en) | Thermoplastic resin compositions | |
| KR930003378B1 (en) | Fiber-reinforced thermoplastic resin composition | |
| KR920010613B1 (en) | Reinforced molding resin composition | |
| US3830777A (en) | Reinforced polyamides containing fibrous alkali metal titanates | |
| EP0094773A2 (en) | Polyamide resin composition | |
| US4582864A (en) | Carbonaceous filler-containing vinylidene fluoride resin composition | |
| US5041258A (en) | Injection process for long fiber-containing resin | |
| EP0339910A1 (en) | Polyoxymethylene resin composition and process for the preparation thereof | |
| DE2737908A1 (en) | POLYAMIDE MOLDING COMPOUNDS AND THEIR USE | |
| JPH0560492B2 (en) | ||
| KR920007529B1 (en) | Polyarylene sulfide resin composition | |
| US5116540A (en) | Free-radical modified carbon black filled polypropylenes | |
| EP0375170B1 (en) | Process for producing aromatic polysulfone molding compositions improved in mold-release characteristics and the compositions obtained by this process. | |
| KR20050114459A (en) | Polycarbonate/abs resin nanocomposites containing montmorillonite | |
| KR930008196B1 (en) | Polyphenylene sulfide resin composition | |
| JPS6248987B2 (en) | ||
| EP0485644A1 (en) | Poly(arylene sulfide) compositions with strengthened weldline | |
| KR100219796B1 (en) | Thermoplastic composition | |
| JPH0314871A (en) | Poly (arylenesulfide) compounds containing glass | |
| KR940001077B1 (en) | Polyphenylene sulfide resin composition | |
| JPH05255571A (en) | Composite resin composition | |
| JPH05112672A (en) | Fiber-reinforced thermoplastic resin composition | |
| KR20090112495A (en) | Calsium carbonate filler having nano-capsule, Preparing method thereof and Plastic resin composition containing thereof | |
| KR100226457B1 (en) | Thermoplastic resin composition having superior injection molding property | |
| JPS59157150A (en) | Polyether ketone resin composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 729S | Offer to surrender (sect. 29/1977) | ||
| 729A | Offer accepted by the comptroller (sect. 29/1977) |