GB1584853A - Automatic analysis of alkali metals halides etc by means of the use ion-selective electrodes - Google Patents
Automatic analysis of alkali metals halides etc by means of the use ion-selective electrodes Download PDFInfo
- Publication number
- GB1584853A GB1584853A GB38429/77A GB3842977A GB1584853A GB 1584853 A GB1584853 A GB 1584853A GB 38429/77 A GB38429/77 A GB 38429/77A GB 3842977 A GB3842977 A GB 3842977A GB 1584853 A GB1584853 A GB 1584853A
- Authority
- GB
- United Kingdom
- Prior art keywords
- electrode
- solution
- sample
- ion
- measuring cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004458 analytical method Methods 0.000 title description 15
- 229910052783 alkali metal Inorganic materials 0.000 title description 2
- -1 alkali metals halides Chemical class 0.000 title 1
- 239000000243 solution Substances 0.000 claims description 37
- 150000002500 ions Chemical class 0.000 claims description 29
- 239000000523 sample Substances 0.000 claims description 29
- 239000012528 membrane Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 11
- 238000010790 dilution Methods 0.000 claims description 10
- 239000012895 dilution Substances 0.000 claims description 10
- 238000012360 testing method Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 5
- 239000003153 chemical reaction reagent Substances 0.000 claims description 4
- 239000012488 sample solution Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000010408 film Substances 0.000 claims description 3
- 239000010409 thin film Substances 0.000 claims description 3
- 230000001154 acute effect Effects 0.000 claims description 2
- 239000006193 liquid solution Substances 0.000 claims description 2
- 101000635799 Homo sapiens Run domain Beclin-1-interacting and cysteine-rich domain-containing protein Proteins 0.000 claims 1
- 102100030852 Run domain Beclin-1-interacting and cysteine-rich domain-containing protein Human genes 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000005259 measurement Methods 0.000 description 22
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 14
- 229910052700 potassium Inorganic materials 0.000 description 14
- 239000011591 potassium Substances 0.000 description 14
- 210000002966 serum Anatomy 0.000 description 11
- 239000011734 sodium Substances 0.000 description 10
- 239000002689 soil Substances 0.000 description 10
- 229910002651 NO3 Inorganic materials 0.000 description 9
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 239000003792 electrolyte Substances 0.000 description 8
- 239000000284 extract Substances 0.000 description 8
- 238000005048 flame photometry Methods 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 239000008280 blood Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000004401 flow injection analysis Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000012088 reference solution Substances 0.000 description 3
- 238000005070 sampling Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 102100032352 Leukemia inhibitory factor Human genes 0.000 description 2
- 108090000581 Leukemia inhibitory factor Proteins 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 238000002798 spectrophotometry method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- RRKTZKIUPZVBMF-IBTVXLQLSA-N brucine Chemical compound O([C@@H]1[C@H]([C@H]2C3)[C@@H]4N(C(C1)=O)C=1C=C(C(=CC=11)OC)OC)CC=C2CN2[C@@H]3[C@]41CC2 RRKTZKIUPZVBMF-IBTVXLQLSA-N 0.000 description 1
- RRKTZKIUPZVBMF-UHFFFAOYSA-N brucine Natural products C1=2C=C(OC)C(OC)=CC=2N(C(C2)=O)C3C(C4C5)C2OCC=C4CN2C5C31CC2 RRKTZKIUPZVBMF-UHFFFAOYSA-N 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000012482 calibration solution Substances 0.000 description 1
- GTKRFUAGOKINCA-UHFFFAOYSA-M chlorosilver;silver Chemical compound [Ag].[Ag]Cl GTKRFUAGOKINCA-UHFFFAOYSA-M 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- 229940031954 dibutyl sebacate Drugs 0.000 description 1
- 239000012470 diluted sample Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000004856 soil analysis Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010421 standard material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- QBVXKDJEZKEASM-UHFFFAOYSA-M tetraoctylammonium bromide Chemical compound [Br-].CCCCCCCC[N+](CCCCCCCC)(CCCCCCCC)CCCCCCCC QBVXKDJEZKEASM-UHFFFAOYSA-M 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
- G01N31/162—Determining the equivalent point by means of a discontinuity
- G01N31/164—Determining the equivalent point by means of a discontinuity by electrical or electrochemical means
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B2219/00—Program-control systems
- G05B2219/30—Nc systems
- G05B2219/35—Nc in input of data, input till input file format
- G05B2219/35543—Cartesian to polar and vice versa
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Biological Materials (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE7610221A SE427503B (sv) | 1976-09-15 | 1976-09-15 | Sett att analysera ett prov vid flow-injection-analys, genom kontinuerlig bestemning av joner samt anordning for utforande av settet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1584853A true GB1584853A (en) | 1981-02-18 |
Family
ID=20328878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB38429/77A Expired GB1584853A (en) | 1976-09-15 | 1977-09-14 | Automatic analysis of alkali metals halides etc by means of the use ion-selective electrodes |
Country Status (6)
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5784346A (en) * | 1980-11-15 | 1982-05-26 | Toyobo Co Ltd | Measuring apparatus of body liquid component |
| JPS6329241Y2 (US06623731-20030923-C00012.png) * | 1981-05-29 | 1988-08-05 | ||
| US4533456A (en) * | 1984-04-05 | 1985-08-06 | Critikon | Oxygen sensor for rapid blood gas analysis |
| DE3517131C1 (de) * | 1985-05-11 | 1986-11-13 | Eppendorf Gerätebau Netheler + Hinz GmbH, 2000 Hamburg | Verfahren zur Messung der Potentialdifferenz zwischen einer Probenfluessigkeit und einem Referenzelektrolyten sowie Vorrichtung zur Messung der Ionenkonzentration in der Probenfluessigkeit |
| US4798803A (en) * | 1985-07-10 | 1989-01-17 | The Dow Chemical Company | Method for titration flow injection analysis |
| US4958295A (en) * | 1986-05-21 | 1990-09-18 | Hercules Incorporated | Analyzing apparatus and method for analysis of liquid samples |
| US5291418A (en) * | 1991-07-05 | 1994-03-01 | Eastman Kodak Company | Adjustment of electric potential by automatic titration |
| CA2146177C (en) * | 1995-04-03 | 2000-09-05 | Adrian P. Wade | Intelligent flow analysis network |
| US8382974B2 (en) * | 2009-08-18 | 2013-02-26 | Ceramatec, Inc. | Sensor to measure a concentration of alkali alcoholate |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2108293A (en) * | 1936-01-10 | 1938-02-15 | Leeds & Northrup Co | Apparatus for measuring ion-concentration |
| NL275701A (US06623731-20030923-C00012.png) * | 1961-03-13 | |||
| US3296098A (en) * | 1962-01-15 | 1967-01-03 | Beckman Instruments Inc | Method and apparatus for gas analysis |
| US3241430A (en) * | 1962-09-24 | 1966-03-22 | Honeywell Inc | Three axis optical alignment device |
| SE322073B (US06623731-20030923-C00012.png) * | 1965-04-13 | 1970-03-23 | Bayer Ag | |
| US3427135A (en) * | 1966-07-11 | 1969-02-11 | Technicon Instr | Hematology apparatus |
| US3556950A (en) * | 1966-07-15 | 1971-01-19 | Ibm | Method and apparatus for automatic electrochemical analysis |
| US3572994A (en) * | 1968-02-27 | 1971-03-30 | Technicon Corp | Analysis system for a liquid stream for a gaseous constituent |
| DE1934793A1 (de) * | 1968-07-26 | 1970-01-29 | Vyzk Ustav Organ Syntez | Verfahren zum potentiometrischen Messen und Vorrichtung zur Durchfuehrung des Verfahrens |
| US3600953A (en) * | 1969-07-25 | 1971-08-24 | Technicon Corp | Method and apparatus for the introduction of auxiliary separating fluid in fluid sample analyses means |
| US3997420A (en) * | 1971-03-18 | 1976-12-14 | Beckman Instruments, Inc. | Automatic analyzer |
| US3853732A (en) * | 1972-04-10 | 1974-12-10 | Technicon Instr | Electrode structure for potentiometric sample analysis |
| US3840438A (en) * | 1972-04-10 | 1974-10-08 | Technicon Instr | Method of direct potentiometric analysis of a liquid sample |
| DK375773A (US06623731-20030923-C00012.png) * | 1973-07-06 | 1975-02-24 | E H Hansen | |
| DK150802C (da) * | 1974-09-16 | 1988-02-01 | Bifok Ab | Fremgangsmaade og apparat til kontinuerlig hoejhastighedsanalyse af en vaeskeproeve i en baererstroem |
-
1976
- 1976-09-15 SE SE7610221A patent/SE427503B/xx not_active IP Right Cessation
-
1977
- 1977-09-08 DE DE2740570A patent/DE2740570C2/de not_active Expired
- 1977-09-12 US US05/832,742 patent/US4227973A/en not_active Expired - Lifetime
- 1977-09-14 GB GB38429/77A patent/GB1584853A/en not_active Expired
- 1977-09-14 JP JP52110016A patent/JPS5933225B2/ja not_active Expired
- 1977-09-15 FR FR7727888A patent/FR2365122A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2365122B1 (US06623731-20030923-C00012.png) | 1981-12-24 |
| SE7610221L (sv) | 1978-03-16 |
| US4227973A (en) | 1980-10-14 |
| DE2740570C2 (de) | 1992-10-22 |
| JPS5341290A (en) | 1978-04-14 |
| DE2740570A1 (de) | 1978-03-16 |
| JPS5933225B2 (ja) | 1984-08-14 |
| SE427503B (sv) | 1983-04-11 |
| FR2365122A1 (fr) | 1978-04-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19970913 |