GB1582287A - Process catalyst and catalyst component for the manufacture of homopolymers and copolymers of a-monoolefins - Google Patents
Process catalyst and catalyst component for the manufacture of homopolymers and copolymers of a-monoolefins Download PDFInfo
- Publication number
- GB1582287A GB1582287A GB3083277A GB3083277A GB1582287A GB 1582287 A GB1582287 A GB 1582287A GB 3083277 A GB3083277 A GB 3083277A GB 3083277 A GB3083277 A GB 3083277A GB 1582287 A GB1582287 A GB 1582287A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vanadium
- catalyst component
- weight
- carbon atoms
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims description 134
- 238000000034 method Methods 0.000 title claims description 49
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- 229920001519 homopolymer Polymers 0.000 title claims description 7
- 229920001577 copolymer Polymers 0.000 title claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 85
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 85
- 239000000047 product Substances 0.000 claims description 53
- 238000006116 polymerization reaction Methods 0.000 claims description 51
- 229910052782 aluminium Inorganic materials 0.000 claims description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 29
- 125000004432 carbon atom Chemical group C* 0.000 claims description 29
- 239000007790 solid phase Substances 0.000 claims description 29
- 229910052739 hydrogen Chemical group 0.000 claims description 26
- 239000001257 hydrogen Chemical group 0.000 claims description 26
- 229910052751 metal Inorganic materials 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 26
- -1 aluminum compound Chemical class 0.000 claims description 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- 229910052801 chlorine Inorganic materials 0.000 claims description 19
- 239000000460 chlorine Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 15
- 239000005977 Ethylene Substances 0.000 claims description 15
- 235000012239 silicon dioxide Nutrition 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 13
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 11
- 150000005826 halohydrocarbons Chemical class 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 239000011148 porous material Substances 0.000 claims description 9
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 8
- 229910052681 coesite Inorganic materials 0.000 claims description 8
- 229910052906 cristobalite Inorganic materials 0.000 claims description 8
- 229910052682 stishovite Inorganic materials 0.000 claims description 8
- 229910052905 tridymite Inorganic materials 0.000 claims description 8
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052794 bromium Inorganic materials 0.000 claims description 7
- 238000001704 evaporation Methods 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 6
- 239000012071 phase Substances 0.000 claims description 6
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 150000002431 hydrogen Chemical group 0.000 claims description 5
- 150000002736 metal compounds Chemical class 0.000 claims description 5
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000012265 solid product Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical class CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 96
- 239000000725 suspension Substances 0.000 description 38
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 36
- 238000003756 stirring Methods 0.000 description 31
- VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 13
- 230000001105 regulatory effect Effects 0.000 description 13
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000470 constituent Substances 0.000 description 8
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 8
- 238000001914 filtration Methods 0.000 description 8
- 239000007858 starting material Substances 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000003746 solid phase reaction Methods 0.000 description 6
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 5
- 229940073608 benzyl chloride Drugs 0.000 description 5
- 239000002904 solvent Substances 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical compound [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 description 1
- RFONJRMUUALMBA-UHFFFAOYSA-N 2-methanidylpropane Chemical compound CC(C)[CH2-] RFONJRMUUALMBA-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000001399 aluminium compounds Chemical class 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical class CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19762633109 DE2633109A1 (de) | 1976-07-23 | 1976-07-23 | Verfahren zum herstellen von homo- und copolymerisaten von alpha- monoolefinen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1582287A true GB1582287A (en) | 1981-01-07 |
Family
ID=5983726
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3083277A Expired GB1582287A (en) | 1976-07-23 | 1977-07-22 | Process catalyst and catalyst component for the manufacture of homopolymers and copolymers of a-monoolefins |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5313690A (enrdf_load_stackoverflow) |
| AT (1) | AT354726B (enrdf_load_stackoverflow) |
| BE (1) | BE857100A (enrdf_load_stackoverflow) |
| DE (1) | DE2633109A1 (enrdf_load_stackoverflow) |
| ES (1) | ES460960A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2359156A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1582287A (enrdf_load_stackoverflow) |
| IT (1) | IT1076790B (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4525550A (en) * | 1982-11-13 | 1985-06-25 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of α-monoolefins using a ziegler catalyst system |
| US4710552A (en) * | 1984-05-10 | 1987-12-01 | Basf Aktiengesellschaft | Preparation of homopolymers of ethene and copolymers of ethene with higherα-monolefins using a Ziegler catalyst system |
| US4864005A (en) * | 1982-11-13 | 1989-09-05 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of α-monoolefins using a Ziegler catalyst system |
| US5374597A (en) * | 1993-02-12 | 1994-12-20 | Quantum Chemical Corporation | Vanadium based olefin polymerization catalyst |
| US5405817A (en) * | 1993-02-12 | 1995-04-11 | Quantum Chemical Corporation | V/TI multi-site olefin polymerization catalyst |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3117397A1 (de) * | 1981-05-02 | 1982-11-18 | Basf Ag, 6700 Ludwigshafen | Verfahren zum herstellen von homo- und copolymerisaten von monoolefinen durch polymerisation des bzw. der monomeren mittels eines ziegler-katalysatorsystems auf der basis einer vanadium enthaltenden katalysatorkomponente |
| US4378304A (en) * | 1981-06-03 | 1983-03-29 | Chemplex Company | Catalyst and methods |
| DE3144311A1 (de) * | 1981-11-07 | 1983-05-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zum herstellen einer vanadium enthaltenden katalysatorkomponente fuer ziegler-katalysatorsysteme |
| US5030605A (en) * | 1989-12-29 | 1991-07-09 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst for regulating the molecular weight distribution of ethylene polymers |
| US5670439A (en) * | 1995-03-29 | 1997-09-23 | Quantum Chemical Corporation | Vanadium-containing catalyst system |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3301834A (en) * | 1963-09-11 | 1967-01-31 | Hercules Inc | Polymerization of olefins |
| BE756644A (fr) * | 1969-09-25 | 1971-03-25 | Naphtachimie Sa | Polymeres huileux de propylene et/ou de butylene |
| FR2082153A5 (fr) * | 1970-03-05 | 1971-12-10 | Solvay | Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines |
-
1976
- 1976-07-23 DE DE19762633109 patent/DE2633109A1/de active Granted
-
1977
- 1977-05-31 IT IT2422777A patent/IT1076790B/it active
- 1977-07-22 FR FR7722687A patent/FR2359156A1/fr active Granted
- 1977-07-22 ES ES460960A patent/ES460960A1/es not_active Expired
- 1977-07-22 AT AT535377A patent/AT354726B/de not_active IP Right Cessation
- 1977-07-22 GB GB3083277A patent/GB1582287A/en not_active Expired
- 1977-07-22 JP JP8748577A patent/JPS5313690A/ja active Pending
- 1977-07-25 BE BE179587A patent/BE857100A/xx not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4525550A (en) * | 1982-11-13 | 1985-06-25 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of α-monoolefins using a ziegler catalyst system |
| US4864005A (en) * | 1982-11-13 | 1989-09-05 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of α-monoolefins using a Ziegler catalyst system |
| US4710552A (en) * | 1984-05-10 | 1987-12-01 | Basf Aktiengesellschaft | Preparation of homopolymers of ethene and copolymers of ethene with higherα-monolefins using a Ziegler catalyst system |
| US5374597A (en) * | 1993-02-12 | 1994-12-20 | Quantum Chemical Corporation | Vanadium based olefin polymerization catalyst |
| US5405817A (en) * | 1993-02-12 | 1995-04-11 | Quantum Chemical Corporation | V/TI multi-site olefin polymerization catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| AT354726B (de) | 1979-01-25 |
| ATA535377A (de) | 1979-06-15 |
| BE857100A (fr) | 1978-01-25 |
| JPS5313690A (en) | 1978-02-07 |
| DE2633109A1 (de) | 1978-02-02 |
| ES460960A1 (es) | 1978-05-16 |
| FR2359156B1 (enrdf_load_stackoverflow) | 1981-04-30 |
| DE2633109C2 (enrdf_load_stackoverflow) | 1987-12-03 |
| FR2359156A1 (fr) | 1978-02-17 |
| IT1076790B (it) | 1985-04-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19940722 |