GB1578783A - Applying a thin coating of a hardenable liquid material to the surface of a cylindrical substrate - Google Patents
Applying a thin coating of a hardenable liquid material to the surface of a cylindrical substrate Download PDFInfo
- Publication number
- GB1578783A GB1578783A GB32738/77A GB3273877A GB1578783A GB 1578783 A GB1578783 A GB 1578783A GB 32738/77 A GB32738/77 A GB 32738/77A GB 3273877 A GB3273877 A GB 3273877A GB 1578783 A GB1578783 A GB 1578783A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cylinder
- coating
- ring
- collar
- applicator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000576 coating method Methods 0.000 title claims description 46
- 239000011248 coating agent Substances 0.000 title claims description 44
- 239000000758 substrate Substances 0.000 title claims description 11
- 239000011344 liquid material Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 14
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims description 7
- 108091008695 photoreceptors Proteins 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 4
- 229920000126 latex Polymers 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000463 material Substances 0.000 description 18
- 239000006185 dispersion Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- -1 poly(vinylcarbazole) Polymers 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- VHQGURIJMFPBKS-UHFFFAOYSA-N 2,4,7-trinitrofluoren-9-one Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C2=C1 VHQGURIJMFPBKS-UHFFFAOYSA-N 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229920004943 Delrin® Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910001370 Se alloy Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000008365 aqueous carrier Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Inorganic materials [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/05—Organic bonding materials; Methods for coating a substrate with a photoconductive layer; Inert supplements for use in photoconductive layers
- G03G5/0525—Coating methods
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Apparatus (AREA)
Description
PATENT SPECIFICATION
( 21) Application No 32738/77 ( 22) Filed 4 Aug 1977 ( 31) Convention Application No 713764 ( 32) ( 33) ( 44) ( 51) Filed 12 Aug 1976 in United States of America (US)
Complete Specification published 12 Nov 1980
INT CL 3 BOSC 3/00 ( 52) Index at acceptance B 2 L 103 A B ( 72) Inventor ARTHUR C MARTELLOCK ( 54) APPLYING A THIN COATING OF A HARDENABLE LIQUID MATERIAL TO THE SURFACE OF A CYLINDRICAL SUBSTRATE ( 71) We, XEROX CORPORATION of Rochester, New York State, United States of America, a Body Corporate organized under the laws of the State of New York, United States of America, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:-
This invention relates to a novel method for the application of a thin layer of a hardenable liquid to the outer surface of a cylinder While not limited thereto, the method has special applicability for the application of a protective overcoating material to electrostatographic photoreceptors The art of electrostatographic copying, originally disclosed by C F.
Carlson in U S Patent 2,297,691, involves as an initial step the uniform charging of a plate or drum comprised of a conductive substrate normally bearing on its surface a non-conductive barrier layer which is covered by a layer of photoconductive insulating material The charged plate is exposed to activating radiation in imagewise configuration which results in dissipation of the electrostatic charge in the exposed areas while the non-exposed areas retain the charge in a pattern known as the latent image The latent image is developed by contacting it with an electroscopic marking material commonly referred to as toner This material is electrically attracted to the latent image which is, by definition, in the configuration of those portions of the photoreceptor which were not exposed to the activating radiation The toner image may be subsequently transferred to paper and fused to it to form a permanent copy.
Following this, the latent image is erased by discharging the drum and cleaning excess toner from it to prepare it for the next cycle.
The photoconductive insulating material is characterized in that it has a comparatively high electrical resistance in the dark which resistance decreases significantly upon exposure to activating radiation Both organic materials, such as 2,4,7 trinitro 9 fluorenone in poly(vinylcarbazole), and inorganic materials, such as amorphous selenium, have been successfully used as the photoconductive material in electrostatographic copiers.
In some instances, it has been found to be desirable to overcoat the layer of photoconductive insulating material with a thin layer of an organic material These overcoatings are applied for a variety of reasons One reason for using an overcoating is to protect the photoconductive material from physical abrasion during the copying cycle Overcoatings of this type are disclosed in U S Patent 2,860,040 (where polyvinylacetal or polyvinylformal are used) and U S Patent 2,886,434 (where inorganic materials such as Zn S, Si O 2 and Ti O 2 are used) In certain instances, an overcoating material is applied to the layer of photoconductive material to enhance its cleanability An example of this type of overcoating is to be found in U S Patent 3,793,018 wherein it is disclosed that a hydrophobic bivalent or trivalent metal salt of a half ester of a branched chain or straight chain aliphatic dicarboxylic acid of a mono or di-ester of a phosphorous oxyacid can be applied to the photoreceptor Still another use of an overcoating is to protect the photoconductive material from chemical constituents in the ambient atmosphere which may detrimentally react with it U K.
Patent Specification No 1,500,777 discloses this type of overcoating In addition, certain polymeric overcoatings have been found to increase the electrophotographic speed of the photoreceptor Many of these overcoating materials are applied from their liquid solutions or dispersions.
Application of the solution or dispersion oo k_ ( 1) 1 578 783 2 1578783 2 with subsequent evaporation of the liquid leaves a thin layer of the overcoating material on the outer surface of the cylinder When an organic polymeric material is used as the overcoating, it is typically applied from a synthetic latex, i e.
a finely divided emulsion of polymer particles in an aqueous carrier The carrier normally contains a basic material such as ammonia or an amine, e g isopropylamine, to form a salt with weakly ionized carboxylic acid groups on the polymer backbone and thereby increase the solubility of the polymer Evaporation of the water leaves a thin layer of the polymer.
In order to get a polymer layer of uniform thickness it is, of course, necessary to apply a layer of the dispersion uniformly.
One method of applying the liquid to the cylinder involves applying a wetted sponge to the cylinder's surface and rotating the cylinder about its axis of rotation while moving the wetted sponge laterally along the cylinder This method can be effective in applying a uniform coating but requires a fairly high level of operator skill, especially when the liquid is of the type which hardens rapidly Another method is to apply the hardenable liquid to the cylinder with a spray gun and allowing it to drain and dry.
This method is quite wasteful of material, however, since enough liquid must be applied so all the bubbles generated by the spray drain off.
According to the present invention, there is provided a method for applying a thin coating of a hardenable liquid material to the surface of a cylindrical substrate, the method comprising:
(a) mounting the cylindrical substrate, with its axis of rotation disposed vertically, on a vertically extending pedestal having the same diameter as that of the cylinder; (b) slideably mounting an applicator collar on the outside of the cylinder at one end thereof, said applicator collar comprising a ring having an inside diameter larger than the outside diameter of the cylinder, said ring having along its inside surface a resilient ring-shaped gasket attached to the ring in such a manner that a substantially leakproof trough is formed when the collar is slideably mounted on the cylinder as aforesaid, and said applicator collar having guide fingers depending from said ring whereby to maintain said collar in a perpendicular relationship with the cylinder's axis; (c) adding the hardenable liquid to the trough formed by the ring, gasket and cylinder while the axis of rotation of the cylinder is vertically disposed; and (d) sliding the applicator collar down the cylinder and onto the pedestal to leave a thin coating of the liquid on the outer surface of the cylinder.
The preferred method of practising the present invention is more fully illustrated by the drawings.
Fig 1 represents a cylinder 10 having a coating collar, shown schematically at 12, mounted on it.
Fig 2 depicts the collar 12 in some detail as well as showing the pedestal on which the cylinder 10 is mounted The ring of the coating collar 12 is made up of two separate brass rings 22 and 24 The resilient gasket, which may be made of such material as polyethylene, Delrin (registered Trade Mark) or Teflon (registered Trade Mark), is fabricated so as to form a leak-proof seal with the cylinder, and is in the form of a flat ring 26 which is inserted between the two brass rings to form a sandwich which is held together by clamp screws 28 Guide finger is attached to the bottom of the ring The coating collar is normally equipped with three guide fingers spaced at 1200 intervals along the ring's underside to maintain the coating collar in a perpendicular relationship with the axis of rotation of the cylinder In Fig 2, the cylinder is depicted as being supported by support base 32 The support base comprises a pedestal supporting a cylindrical member of the same outside diameter as the cylinder to be coated Use of the support base enables the operator to coat the entire lateral surface of the cylinder by sliding the coating collar over the support base as it reaches the lower end of the cylinder.
For a given material, the coating thickness is a function of the solid phase dilution and the relative humidity of the ambient atmosphere Alternatively stated, the thickness depends on the viscosity and the rate of drying of the hardenable liquid material This relationship is more fully elucidated by H F Payne in Ind Eng.
Chem, 1943 15, 48 for flat plate dip coating studies and C D Denson in Ind Eng.
Chem, Fundam, 1970, 9, 443-8 and Trans Soc Rheol, 1972, 16, 697-709 on the rheology of draining films on flat surfaces.
At slow coating speeds, i e 12 inches per minute or less, the coating thickness varies with coating speed, with coating speed and coating thickness being in a direct relationship, and a relatively thin coating can be applied In addition, taper of the coating from the top to bottom of the cylinder can be reduced or eliminated by the use of a slow coating speed A mechanical device comprising a constant speed drive applicator can be employed to control the linear speed of the applicator collar and thereby take advantage of the benefits of slow application However, at 1,578,783 1,578,783 higher speeds, i e at speeds greater than 12 inches per minute, and with typical low viscosity emulsion formulations, rapid application is possible which is extremely convenient, and a relatively thick coating can be applied.
It has been observed that the coating thickness of liquid emulsions will vary inversely with relative humidity Humidity control for this process is easily achieved A metal or plastic container with a tightfitting lid, such as a 10 gallon tall pail is lined with a sheet of blotter paper or absorbent cloth This lining is wetted, by capillary action, with a saturated solution of a salt Potassium bromide, for example, controls the relative humidity at 84 % over a broad temperature range Typically, the cylinder is coated with a heavy film by rapid draw-down and then immediately placed in the controlled relative humidity container to control the rate of drying, and therefore the final film thickness.
As previously mentioned, slow coating speeds are desirable in some instances and can be conveniently obtained by the use of automated coating techniques This can be achieved by driving the collar down the cylinder via three coupled lead screws This method will permit the slow, uniform rates needed for taper-free, extremely uniform coatings The device can be built into a metal cabinet which will also serve to maintain a constant relative humidity Air, pumped through e container full of saturated salt solution, can be used to supply the needed moisture.
The following Experiments illustrate certain factors affecting the thickness and evenness of the applied coating For the purposes of these experiments, it was sufficient to employ an application method which, while generally in accordance with the present invention, did not make use of guide fingers for the applicator collar or of a pedestal for the cylindrical substrate.
Experiment I An electrostatographic photoreceptor comprising an aluminum cylinder, 9 5 inches in diameter with a 60 p thick layer of a selenium/arsenic alloy on its surface, is selected for coating.
A coating device comprising a 9 75 inch diameter aluminum ring with a Teflon (Registered Trade Mark) gasket distributed internally thereto is provided The internal diameter of the gasket is sufficiently close to the outside diameter of the cylinder to provide a snug, leak-proof fit when the coating ring is placed over the cylinder The trough formed by the coating collar and cylinder is 1/8 inch in width.
The cylinder is positioned vertically and the coating device is slipped over its top end About 30 milliliters of an air-setting, aqueous latex dispersion is placed in the trough formed by the cylinder, the aluminum ring and the Teflon gasket The coating device is then pushed down the length of the cylinder smoothly and rapidly during which time a heavy film of the latex dispersion is evenly applied to the outside surface of the cylinder At this point, the cylinder is removed to a chamber maintained at 80-85 % relative humidity and allowed to drain and dry undisturbed for at least an hour.
The resulting coating is slightly tapered being about 0 5 micrometers thick at the top and about 0 7 micrometers thick at the bottom The coating thickness will, of course, depend on the specific material being employed; the higher the viscosity the thicker the coating Where tapering of the coating is undesirable, it can be cancelled by applying two coatings in opposite directions The coating thickness is readily measured with a reflectance spectrophotometer, and calculated using the relation:
d2 N G 11-A 2) 3 In the above equation, A, is the wavelength of an absorption maximum (or minimum) and A 2 is the wavelength of the adjacent maximum (or minimum); N is the 95 refractive index of the coating material and d is the thickness of the coating.
Experiment II It is observed that with the use of low viscosity emulsion formulations, e g 1 8 to 6 centipoise viscosity, a rapid application is possible In this experiment a collar containing one ounce of material is drawn down the 15 inch length of the cylinder being coated in about three seconds, depositing a fairly heavy film After draining and drying as above, the film thickness is found to be a function of relative humidity, with films coated at 25 % relative humidity being about twice as thick as films coated at 84 % These films have a taper but are found acceptable for electrostatographic photoreceptor use.
From the foregoing, it will be appreciated that it is possible, in accordance with the invention, to apply a thin, uniform layer of a hardenable liquid to the surface of a cylindrical substrate, by a method which is relatively easy to carry out, which employs simple, inexpensive equipment, and which is economical in terms of coating liquid consumption.
Claims (9)
1 A method for applying a thin coating A 1,578783 of a hardenable liquid material to the surface of a cylindrical substrate, the method comprising:
(a) mounting the cylindrical substrate, with its axis of rotation disposed vertically, on a vertically extending pedestal having the same diameter as that of the cylinder; (b) slideably mounting an applicator collar on the outside of the cylinder at one end thereof, said applicator collar comprising a ring having an inside diameter larger than the outside diameter of the cylinder, said ring having along its inside surface a resilient ring-shaped gasket attached to the ring in such a manner that a substantially leakproof trough is formed when the collar is slideably mounted on the cylinder as aforesaid, and said applicator collar having guide fingers depending from said ring whereby to maintain said collar in a perpendicular relationship with the cylinder's axis.
(c) adding the hardenable liquid to the trough formed by the ring, gasket and cylinder while the axis of rotation of the cylinder is vertically disposed; and (d) sliding the applicator collar down the cylinder and onto the pedestal to leave a thin coating of the liquid on the outer surface of the cylinder.
2 A method according to claim 1 wherein the cylinder is an electrostatographic photoreceptor.
3 A method according to claim 1 or claim 2 wherein the hardenable liquid is a latex emulsion.
4 A method according to any one of claims 1 to 3 wherein the guide fingers are spaced around the ring at 1200 intervals.
A method according to any one of claims 1 to 4 wherein a relatively thin coating is applied by sliding the applicator down the cylinder at a rate of no greater than 12 inches per minute.
6 A method according to any one of claims 1 to 4 wherein a relatively thick coating is applied by sliding the applicator down the cylinder at a rate of greater than 12 inches per minute.
7 A method according to any one of claims 1 to 6 wherein the coated cylinder is dried in a chamber having a controlled relative humidity.
8 A method according to any one of claims 1 to 7 wherein the coating is slightly tapered and the cylinder is again coated in the opposite direction.
9 A method of coating a cylindrical substrate, the method being substantially as described with reference to the accompanying drawings.
A cylindrical substrate whenever coated by a method in accordance with any one of claims 1 to 9.
For the Applicant(s) A POOLE & CO, Chartered Patent Agents, 54 New Cavendish Street, London WIM 8 HP.
Printed for Her Majesty's Stationery Office, by the Courier Press, Leamington Spa, 1980 Published by The Patent Office, 25 Southampton Buildings, London, WC 2 A i AY, from which copies may be obtained.
1,578,783
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/713,764 US4018953A (en) | 1976-08-12 | 1976-08-12 | Coating method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1578783A true GB1578783A (en) | 1980-11-12 |
Family
ID=24867449
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB32738/77A Expired GB1578783A (en) | 1976-08-12 | 1977-08-04 | Applying a thin coating of a hardenable liquid material to the surface of a cylindrical substrate |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4018953A (en) |
| JP (1) | JPS5322544A (en) |
| BR (1) | BR7704311A (en) |
| DE (1) | DE2724977A1 (en) |
| GB (1) | GB1578783A (en) |
| NL (1) | NL7708926A (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0634956B2 (en) * | 1987-08-06 | 1994-05-11 | セントラル硝子株式会社 | Thin film coating method and apparatus |
| US4912209A (en) * | 1988-06-15 | 1990-03-27 | National Starch And Chemical Corporation | Starch based corrugating adhesives |
| IT1231384B (en) * | 1988-08-26 | 1991-12-02 | Central Glass Co Ltd | PROCEDURE AND DEVICE FOR COATING THE SURFACE OF A PLATE WITH A THIN LIQUID FILM. |
| US4976877A (en) * | 1989-09-15 | 1990-12-11 | Eastman Kodak Company | Ceramic cupric oxide coated pressure roll for image fixing |
| US5650196A (en) * | 1993-05-05 | 1997-07-22 | Steag Microtech Gmbh | Device for coating substrates in semiconductor production |
| US5561507A (en) * | 1994-07-08 | 1996-10-01 | Page Station Technology, Inc. | Apparatus and method for producing an electrostatic image using water-base toner |
| US6117488A (en) * | 1998-09-25 | 2000-09-12 | Erickson; Dennis | Non-sag liquid application method |
| AU4879401A (en) | 2000-04-21 | 2001-11-07 | Toagosei Co., Ltd. | Process for producing water-soluble polymer |
| US7981475B2 (en) * | 2003-11-05 | 2011-07-19 | Ibiden Co., Ltd. | Manufacturing method of honeycomb structural body, and sealing material |
| WO2013145217A1 (en) * | 2012-03-29 | 2013-10-03 | イビデン株式会社 | Application jig and method for manufacturing honeycomb structure body |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH173774A (en) * | 1932-08-01 | 1934-12-15 | Ringier & Co Aktiengesellschaf | Process for applying layers to printing forms. |
| US2482021A (en) * | 1945-01-08 | 1949-09-13 | Pipe Line Service Corp | Pipe coating machine |
| US2545792A (en) * | 1946-03-11 | 1951-03-20 | Perrault Bros | Pipe coating shoe |
| US3117028A (en) * | 1959-12-10 | 1964-01-07 | Bekk & Kaulen Chem Fab Gmbh | Apparatus for coating printing forms for photogravure and the like |
| US3188371A (en) * | 1960-10-13 | 1965-06-08 | Weeldey Goldwyn | Coating apparatus and method therefor |
| FR1314146A (en) * | 1962-01-18 | 1963-01-04 | Kronprinz Ag | Method and installation for applying plastic coatings to metal pipes |
| CH454551A (en) * | 1966-07-14 | 1968-04-15 | Richards Ltd | Method for forming inner and / or outer coatings on a flexible tubular part and device for carrying out the method |
-
1976
- 1976-08-12 US US05/713,764 patent/US4018953A/en not_active Expired - Lifetime
-
1977
- 1977-06-02 DE DE19772724977 patent/DE2724977A1/en not_active Withdrawn
- 1977-06-30 BR BR7704311A patent/BR7704311A/en unknown
- 1977-08-04 GB GB32738/77A patent/GB1578783A/en not_active Expired
- 1977-08-05 JP JP9407377A patent/JPS5322544A/en active Pending
- 1977-08-12 NL NL7708926A patent/NL7708926A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| NL7708926A (en) | 1978-02-14 |
| JPS5322544A (en) | 1978-03-02 |
| BR7704311A (en) | 1978-05-16 |
| US4018953A (en) | 1977-04-19 |
| DE2724977A1 (en) | 1978-02-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |