GB1572224A - Aerosol hair lacquer composition - Google Patents

Aerosol hair lacquer composition Download PDF

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Publication number
GB1572224A
GB1572224A GB4508777A GB4508777A GB1572224A GB 1572224 A GB1572224 A GB 1572224A GB 4508777 A GB4508777 A GB 4508777A GB 4508777 A GB4508777 A GB 4508777A GB 1572224 A GB1572224 A GB 1572224A
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Prior art keywords
composition
amount
container according
weight
mixture
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GB4508777A
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LOreal SA
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LOreal SA
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Publication of GB1572224A publication Critical patent/GB1572224A/en
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Description

(54) AEROSOL HAIR LACQUER COMPOSITION (71) We, L'OREAL, a French Body Corporate of 14, rue Royale - 75008, Paris, France, do hereby declare the invention for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement: The present invention relates to an aerosol hair lacquer composition, namely a pressurized sprayable aerosol hair lacquer composition.
Heretofore numerous propellants have been proposed for use in the production of aerosol hair lacquers, amongst which are principally halogenated hydrocarbons and mixtures thereof. Representative such halo enated hydrocarbons which have been used include the "Freons" (Registered Trade Mark , especially Freons 11, 12, 22 and 114. It has also been proposed to use mixtures of these materials and particularly the following mixtures: Freons 11/12, Freons 11/12/114, Freons 11/12/22, Freons 12/114, Freons 22/114 and Freons 12/22/114. It has also previously been proposed to use, as the aerosol propellant, either carbon dioxide gas or nitrous oxide but without other propellants such as halogenated hydrocarbons.
During the past few years, it has also been proposed to utilize as an aerosol propellant a mixture of certain halogenated hydrocarbons with carbon dioxide gas or nitrous oxide. The most widely employed of these are mixtures of Freon 11/12 with nitrous oxide or carbon dioxide gas or a mixture of Freon 12 with carbon dioxide gas or nitrous oxide. Although very widely used, these various aerosol propellants have not always provided complete satisfaction.
It has now been found, according to this invention, that is is possible to obtain excellent aerosol hair lacquer compositions when there is used as the aerosol propellant a mixture of "Freon 22" (monochlorodifluoromethane) and/or Freon 142b (monochlorodifluoroethane) with carbon dioxide gas or nitrous oxide. Although broadly this aerosol propellant could be categorized as a mixture of at least one "Freon" with carbon dioxide gas or nitrous oxide, the particular combination of "Freon 22" or "Freon 142b" or mixture thereof, with carbon dioxide gas or nitrous oxide has not, to our knowledge, ever been envisaged for use as an aerosol propellant in an aerosol hair lacquer composition.
This particular mixture provides excellent qualities; in particular it assures very good compatibility with a large number of cosmetic resins currently employed in the production of aerosol hair lacquer compositions. Moreover, with this propellant mixture, it is possible to obtain very fine sprays which provide excellent covering power of the hair. It is also important to note that the combination of "Freon 22" and/or "Freon 142b" with carbon dioxide gas or nitrous oxide provides significant ecologic advantages.
According to the present invention there is provided an aerosol container containing a hair lacquer composition (which must, of course, be suitable for application to hair) which composition comprises: i)at least one synthetic film-forming cosmetic resin (or polymer) capable of controlling the hair, for example by maintaining it in a desired configuration; (ii) at least one principal solvent which is ethanol or isopropanol; (iii) at least one auxiliary solvent in an amount from 0 to 40% by weight of said composition; (iv) water in an amount from 0 to 20% by weight of said composition; and (v) a propellant consisting of a mixture of (1) a monochlorodifluoromethane, mono chlorodifluroethane or a mixture thereof, in an amount of 15 to 40, preferably 20 to 35% by weight of said composition and (2) carbon dioxide gas or nitrous oxide or a mixture thereof, in an amount such as to provide in the aerosol container a total pressure of from 5 to 8 bars, preferably about 6 bars.
According to the present invention, the synthetic polymer or resin is generally present in the composition in an amount from 0.5 to 10% by weight thereof.
Representative synthetic polymers or resins which can be used in the hair lacquer composition of the present invention include: (a) polyvinylpyrrolidone, for example that known under the name of "PVP K30" (M.W.
= 40,000) sold by GAF; (b) copolymers of vinylpyrrolidone and vinyl acetate and especially those (i) known under the commercial names of "PVP/VA E 335, S 630 and E 535" sold by GAF, viz. E 335 - 30% vinylpyrrolidone/70% vinyl acetate, S 630 - 60% vinylpyrrolidone/40% vinyl acetate and E535 - 50 %vinylpyrrolidone/ 50% vinyl acetate; and (ii) known under the Registered Trade Marks "Luviskol VA 37E, VA64 and VA28I", sold by BASF, viz VA37E - 30% vinylpyr rolidone/70%vinyl acetate, VA64 - 60%vinylpyrrolidone/40%vinyl acetate and VA28I 20% vinylpyrrolidone/80% vinyl acetate; (c) copolymers of vinyl acetate and crotonic acid, especially those sold under the commercial names of (i) "Resine 28-13-10" by National Starch, (ii) "Aresil 86.12" by Montanoir and (iii "Aristoflex C" by Hoechst; ) copolymers of methyl vinyl ether and maleic anhydride half-esterified with a lower aliphatic alcohol such as methanol, ethanol, butanol or isopropanol, and particularly copolymers known under the Registered Trade Marks "Gantrex ES225, ES335I and ES425" sold by GAF, viz. "ES-225" - monoethyl ester of methyl vinyl ether/maleic acid copolymer having viscosity of 3.7 cps, "ES-335I" - monoisopropyl ester of methyl vinyl ether/maleic acid copolymer and "ES425" - monobutyl ester of methyl vinyl ether/maleic acid copolymer having a viscosity of 5.1 cps; (e) amphoteric acrylic copolymers, especially those sold under the commercial name of "Amphomer" by National Starch; (f) vinylic terpolymers with carboxylic and acrylic ester groups, especially those sold by Barr under the commercial names of "VEM 640 and 649"; (g) terpolymers of vinyl acetate, crotonic acid and vinyl neodecanoate, especially those sold by National Starch under the commercial name of "Resine 28.2930"; or (h) those polymers described in the following French Patents Nos. 1,580,545; 1,584,053; and 75.09892.
Those copolymers carrying free carboxylic acid functions are generally employed in a form wherein they are neutralized to an extent of 10 to 100%with an organic base such as 2-amino -2-methyl -1,3-propanediol, 2-amino -2-methyl -1-propanol or triisopropanolamine.
It will be appreciated that while these polymers or resins have quite varied structures, nonetheless, they can all be employed in the compositions of the present invention without provoking any significant or appreciable incompatibility with the propellant mixture, which incompatibility is generally manifested by a clogging of the aerosol release valve of the container.
In accordance with the invention, the principal solvent is generally present in the hair lacquer composition in an amount from 5 to 79.5%by weight and, preferably, from 10 to 69.5% by weight.
The monochlorodifluoromethane, "Freon 22", which is used in the propellant mixture, has the chemical formula: CHC1F2; its molecular weight is about 86.475; it is a liquefied gas under pressure; it is non-flammable, non-corrosive and non-toxic; and its boiling point is -30.8 C/760mm Hg.
"Freon 142b" has the chemical formula: CH3-CC1F2; its molecular weight is about 100.5; it is a liquefied gas under pressure; it is only very slightly flammable; it is non-corrosive and non-toxic; and its boiling point is -9.8 C/760 mm Hg.
According to a preferred embodiment of the present invention, the aerosol hair lacquer composition includes at least one auxiliary organic solvent such as methylene chloride, trichloroethane, ethyl chloride, acetone, ethyl acetate or dichlorodinuoroethane, present in a maximum concentration of 40% by weight and preferably in an amount of 10 to 35% by weight of said composition.
The aerosol hair lacquer composition may also contain water in an amount which does not exceed 20% by weight, preferably from 0.5 to 6% by weight.
When the hair lacquer composition of the present invention contains water in an amount of 0.5 to 6%, it is also preferable to avoid the use of a chlorinated auxiliary solvent or at least to use this material in as small amounts as possible.
The aerosol hair lacquer composition of the present invention can also contain other conventional cosmetic adjuvants such as plasticizers, neutralizing agents, brightening agents, perfumes and hair dyes.
The following Examples further illustrate the present invention. Unless otherwise specified, all parts and percentages are by weight.
EXAMPLE I A pressurized sprayable aerosol hair lacquer composition is prepared by admixing the following components and packaging the resulting mixture, under pressure, in an aerosol container: "Resine 28-13-10" by National starch ...................................................... 2.90 g 2-amino-2-methyl- 1- propanol 0.26 g Perfume 0.04 g Ethanol 61.80 g "Freon 22" ..........................................................35.00 g Carbon dioxide gas, sufficient for a pressure of 6 bars within the container.
EXAMPLE II A pressurized sprayable aerosol hair lacquer composition is prepared by admixing the following components and packaging the resulting mixture, under pressure, in an aerosol container: Gantrez ES-225, sold GAF .......................................... 5.70 g Triisopropanolamine - 0.48 g Methylene chloride ...................................................20.00 g "Solulan 16" (lanolin alcohols ethoxylated with 16 moles of ethylene oxide per mole of alcohol) ................................................ 0.15 g "Freon 22" ..........................................................30.00 g Ethanol 43.67 g Carbon dioxide gas, sufficient for a pressure of 6 bars within the container.
EXAMPLE Ill A pressurized sprayable aerosol hair lacquer composition is prepared by admixing the following components and packaging the resulting mixture, under pressure, in an aerosol container: PVP K 30, sold by GAF ............................................... 4.00 g Ethanol 76.00 g "Freon 22" ...........................................................20.00 g Nitrous oxide, sufficient for a pressure of 6 bars within the container.
EXAMPLE W A pressurized sprayable aerosol hair lacquer composition is prepared by admixing the following components and packaging the resulting mixture, under pressure, in an aerosol container: Gantrez ES-225, sold by GAF .......................................... 2.90 g Triisopropanolamine 0.24 g Perfume 0.03 g "Isopropylan 33" (transesteri fication product of lanolin with isopropanol) ..................................................... 0.2 g Ethanol 61.63 g "Freon 142b" 35 g Carbon dioxide gas, sufficient for a pressure of 6 bars -within the container.
EXAMPLE V A pressurized sprayable aerosol hair lacquer composition is prepared by admixing the following components and packaging the resulting mixture, under pressure, in an aerosol container: "Amphomer" sold by National Starch 1.5 g 2-amino-2-methyl- 1- propanol 0.27 g "Solulan 5" (lanolin alcohols ethoxylated with 5 moles of ethylene oxide) ...................................................... 0.15 g Perfume 0.03 g Methylene chloride ...................................................35 g "Freon 142b" 30 g Ethanol 33.05 g Nitrous oxide, sufficient for a pressure of 6 bars within the container.
EXAMPLE VI A pressurized sprayable aerosol hair lacquer composition is prepared by admixing the following components and packaging the resulting mixture, under pressure, in an aerosol container: "Resine 28-13-10" sold by National Starch 4 g 2-amino2-methyl- 1- propanol 0.35 g Silicone oil ........................................................... 0.4 g Perfume 0.06 g Ethanol ..............................................................75.19 g "Freon 142b" 20 g Carbon dioxide gas, sufficient for a pressure of 6 bars within the container.
EXAMPLE VII A pressurized sprayable aerosol hair lacquer composition is prepared by admixing the following components and packaging the resulting mixture, under pressure, in an aerosol container: "Resine 28-13-10" sold by National Starch 4 g 2-amino-2-methyl-1 propanol 0.35 g Silicone oil ........................................................... 0.4 g Perfume 0.06 g Ethanol 75.19 g "Freon 22" ...........................................................10 g "Freon 142b" 10 g Carbon dioxide gas, sufficient for a pressure of 6 bars within the container.

Claims (13)

WHAT WE CLAIM IS:
1. An aerosol container containing a hair lacquer composition, which composition compnses (i) at least one synthetic film-forming cosmetic polymer capable of controlling the hair; (ii) at least one principal solvent which is ethanol or isopropanol; (iii) at least one auxiliary solvent in an amount from 0 to 40 % by weight of said composition; (iv) water in an amount from 0 to 20% by weight of said composition; and (v) a propellant which is a mixture of (1) monochlorodifluoromethane, monochiorodif- luoroethane or a mixture thereof, in an amount from 15 to 40%byweight of said composition and (2) carbon dioxide or nitrous oxide or a mixture thereof, in an amount such as to provide in the container a total pressure of 5 to 8 bars.
2. A container according to claim 1 wherein component (i) is present in an amount from 0.5 to 10% by weight of said composition.
3. A container according to claim 1 or 2 wherein component (ii) is present in an amount from 5 to 79.5% by weight of said composition.
4. A container according to claim 3 wherein component (ii) is present in an amount from 10 to 69.5% by weight of said composition.
5. A container according to any one of claims 1 to 4, wherein component (ifi) is present in an amount from 10 to 35% by weight of said composition.
6. A container according to any one of claims 1 to 5, wherein said auxiliary solvent is methylene chloride, trichloroethane, ethyl chloride, acetone, ethyl acetate or dichlorodifluoroethane.
7. A container according to any one of claims 1 to 6, wherein the composition contains water in an amount from 0.5 to 6% by weight of said composition.
8. A container according to any one of claims 1 to 7, wherein the internal pressure is about 6 bars.
9. A container according to any one of the preceding claims wherein the propellant (1) is present in an amount from 20 to 35% by weight of the composition.
10. A container according to any one of the preceding claims, wherein the composition contains at least one of a plasticizer, brightening agent, perfume, or hair dye.
11. A container according to claim 1 substantially as hereinbefore described.
12. A container according to claim 1 substantially as described in any one of Examples I to VII.
13. An aerosol propellant which comprises a mixture of (1) monochlorodifluoromethane, monochlorodifluoroethene or a mixture thereof and (2) carbon dioxide or nitrous oxide or a mixture thereof.
GB4508777A 1976-10-29 1977-10-28 Aerosol hair lacquer composition Expired GB1572224A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7632842A FR2368947A1 (en) 1976-10-29 1976-10-29 NEW LACQUERS TO FIX THE HAIR IN THE FORM OF AEROSOLS

Publications (1)

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GB1572224A true GB1572224A (en) 1980-07-30

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GB4508777A Expired GB1572224A (en) 1976-10-29 1977-10-28 Aerosol hair lacquer composition

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DE (1) DE2748475A1 (en)
FR (1) FR2368947A1 (en)
GB (1) GB1572224A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2327881A (en) * 1997-08-06 1999-02-10 Reckitt & Colman Inc Control of dust particles

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2486394A1 (en) * 1979-11-28 1982-01-15 Oreal COMPOSITION FOR THE TREATMENT OF KERATIN FIBERS BASED ON AMPHOTERIC POLYMERS AND ANIONIC POLYMERS
DE3044754C2 (en) 1979-11-28 1995-06-01 Oreal Agents and processes for the treatment of keratin fibers
DE19934701C1 (en) * 1999-07-23 2001-05-03 Wella Ag Hydrous aerosol hair spray with a reduced content of volatile organic compounds

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3144391A (en) * 1960-03-28 1964-08-11 Gillette Co Hair-setting composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2327881A (en) * 1997-08-06 1999-02-10 Reckitt & Colman Inc Control of dust particles
GB2327882A (en) * 1997-08-06 1999-02-10 Reckitt & Colman Inc Aerosol compositions for controlling dust mites and the allergens produced by them
US6117440A (en) * 1997-08-06 2000-09-12 Reckitt Benckiser Inc. Compositions effective for controlling dust mites and the allergens produced by dust mites
US6428801B1 (en) 1997-08-06 2002-08-06 Reckitt Benckiser Inc. Methods for controlling dust mites and the allergens produced by dust mites

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Publication number Publication date
FR2368947A1 (en) 1978-05-26
DE2748475A1 (en) 1978-05-03
FR2368947B1 (en) 1979-07-27

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PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19921028