GB1569026A - Method and instrument for amperometric measurement of the free chlorine content in a solution - Google Patents
Method and instrument for amperometric measurement of the free chlorine content in a solution Download PDFInfo
- Publication number
- GB1569026A GB1569026A GB5221377A GB5221377A GB1569026A GB 1569026 A GB1569026 A GB 1569026A GB 5221377 A GB5221377 A GB 5221377A GB 5221377 A GB5221377 A GB 5221377A GB 1569026 A GB1569026 A GB 1569026A
- Authority
- GB
- United Kingdom
- Prior art keywords
- free
- solution
- sample
- instrument
- chlorine content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052801 chlorine Inorganic materials 0.000 title claims description 48
- 239000000460 chlorine Substances 0.000 title claims description 48
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims description 46
- 238000000034 method Methods 0.000 title claims description 27
- 238000005259 measurement Methods 0.000 title claims description 11
- 238000004458 analytical method Methods 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 14
- 238000002474 experimental method Methods 0.000 claims description 9
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims description 2
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical class ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 10
- 239000012530 fluid Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 108700024827 HOC1 Proteins 0.000 description 1
- 101100178273 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) HOC1 gene Proteins 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- -1 chlorine ions Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 150000001913 cyanates Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- FIRHQRGFVOSDDY-UHFFFAOYSA-N ethyl 1-hydroxytriazole-4-carboxylate Chemical compound CCOC(=O)C1=CN(O)N=N1 FIRHQRGFVOSDDY-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/404—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors
- G01N27/4045—Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid, e.g. Clark-type oxygen sensors for gases other than oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
- G01N33/182—Specific anions in water
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Immunology (AREA)
- Engineering & Computer Science (AREA)
- Pathology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7639204A FR2374641A1 (fr) | 1976-12-17 | 1976-12-17 | Procede et appareil de mesure amperometrique de la teneur en chlore libre d'une solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1569026A true GB1569026A (en) | 1980-06-11 |
Family
ID=9181580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5221377A Expired GB1569026A (en) | 1976-12-17 | 1977-12-15 | Method and instrument for amperometric measurement of the free chlorine content in a solution |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5383791A (enExample) |
| BE (1) | BE861675A (enExample) |
| CA (1) | CA1105084A (enExample) |
| DE (1) | DE2752450A1 (enExample) |
| FR (1) | FR2374641A1 (enExample) |
| GB (1) | GB1569026A (enExample) |
| IT (1) | IT1192214B (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2368838A (en) * | 2000-11-13 | 2002-05-15 | Wellby Water Systems Ltd | Maintaining the water in a swimming pool in a safe state |
| WO2004013623A3 (en) * | 2002-05-03 | 2004-04-22 | Rosemount Analytical Inc | Amperometric chloramine sensor |
| US7790006B2 (en) | 2002-05-03 | 2010-09-07 | Rosemount Analytical Inc. | Free chlorine sensor |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2472751A1 (fr) * | 1979-11-13 | 1981-07-03 | Saunier Bernard | Procede de mesure separee de la teneur en ozone et/ou en bioxyde de chlore et, eventuellement, en chlorite et autres oxydants residuels d'une solution |
| FR2469708A1 (fr) * | 1979-11-13 | 1981-05-22 | Saunier Bernard | Procede de mesure amperometrique de la teneur en brome libre et en halogenes oxydants residuels presents dans une solution |
| FR2778463A1 (fr) * | 1998-05-06 | 1999-11-12 | Sagem | Procede et installation de controle d'eau chloree |
-
1976
- 1976-12-17 FR FR7639204A patent/FR2374641A1/fr active Granted
-
1977
- 1977-11-24 DE DE19772752450 patent/DE2752450A1/de not_active Ceased
- 1977-12-09 BE BE183305A patent/BE861675A/xx not_active IP Right Cessation
- 1977-12-14 IT IT3067777A patent/IT1192214B/it active
- 1977-12-15 GB GB5221377A patent/GB1569026A/en not_active Expired
- 1977-12-16 CA CA293,256A patent/CA1105084A/fr not_active Expired
- 1977-12-17 JP JP15229277A patent/JPS5383791A/ja active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2368838A (en) * | 2000-11-13 | 2002-05-15 | Wellby Water Systems Ltd | Maintaining the water in a swimming pool in a safe state |
| WO2002038507A1 (en) * | 2000-11-13 | 2002-05-16 | Wellby Water Systems Limited | Method and apparatus for maintaining the water in a swimming pool in a safe state |
| WO2004013623A3 (en) * | 2002-05-03 | 2004-04-22 | Rosemount Analytical Inc | Amperometric chloramine sensor |
| US7087150B2 (en) | 2002-05-03 | 2006-08-08 | Rosemount Analytical Inc. | Chloramine amperometric sensor |
| US7790006B2 (en) | 2002-05-03 | 2010-09-07 | Rosemount Analytical Inc. | Free chlorine sensor |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1105084A (fr) | 1981-07-14 |
| IT1192214B (it) | 1988-03-31 |
| DE2752450A1 (de) | 1978-06-22 |
| FR2374641B1 (enExample) | 1980-04-04 |
| JPS5383791A (en) | 1978-07-24 |
| FR2374641A1 (fr) | 1978-07-13 |
| JPS61579B2 (enExample) | 1986-01-09 |
| BE861675A (fr) | 1978-03-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19921215 |