GB1567742A - Shampoo composition - Google Patents
Shampoo composition Download PDFInfo
- Publication number
- GB1567742A GB1567742A GB10114/78A GB1011478A GB1567742A GB 1567742 A GB1567742 A GB 1567742A GB 10114/78 A GB10114/78 A GB 10114/78A GB 1011478 A GB1011478 A GB 1011478A GB 1567742 A GB1567742 A GB 1567742A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lauryl sulfate
- composition
- shampoo composition
- weight
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 91
- 239000002453 shampoo Substances 0.000 title claims description 37
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 39
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 26
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 26
- 239000003599 detergent Substances 0.000 claims description 19
- 235000002639 sodium chloride Nutrition 0.000 claims description 14
- 235000019270 ammonium chloride Nutrition 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 claims description 8
- 229940063953 ammonium lauryl sulfate Drugs 0.000 claims description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 229940117927 ethylene oxide Drugs 0.000 claims description 6
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 6
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 239000011668 ascorbic acid Substances 0.000 claims description 4
- 229960005070 ascorbic acid Drugs 0.000 claims description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004327 boric acid Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011591 potassium Chemical group 0.000 claims description 4
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 3
- 239000003205 fragrance Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- 229960003975 potassium Drugs 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000002535 acidifier Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229940071264 lithium citrate Drugs 0.000 description 1
- WJSIUCDMWSDDCE-UHFFFAOYSA-K lithium citrate (anhydrous) Chemical compound [Li+].[Li+].[Li+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WJSIUCDMWSDDCE-UHFFFAOYSA-K 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
Description
(54) SHAMPOO COMPOSITION +71) We, S. C. JOHNSON & SON, INC., a Corporation organized and existing under the laws of the State of Wisconsin, United
States of America, of 1525 Howe Street,
Racine, Wisconsin, 53403, United States of
America, do hereby declare the invention for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:
This invention relates to an acidic shampoo composition. More particularly this invention relates to an acidic shampoo composition having improved cleaning.
Acid side shampoos, i.e. shampoos with with à pH of less than seven, have been known and in fact there are a number of shampoos currently on the market having a pH within the range of 5 to 7. It is known that high alkaline shampoos tend to damage hair and accordingly there has been a recent switch towards shampoo compositions which are less alkaline.
US. Patents 2,289,004, 2,303,932, 2,599,665 and 2,892,756 describe acid side slmmpoo hair treating compositions. These patents describe compositions having pHs with the range of from 2 to 7 and indicate that damage to the hair can be minimized by using a shampoo having a pH near the isoelectric point of hair, i.e. pH 4.5.
Also there are a number of patents and publications which describe the use of anionic detergents as the cleaning agent in the shampoo composition. The most commonly used anionic detergent is sodium lauryl sulfate. This detergent is an effective dealer for the hair and has reasonable solubility.
It has been found that an improved cleaning shampoo composition can be prepared by incorporating 12.5 to 25% by weight of an anionic detergent selected from the group consisting of M-lauryl sulfate, mixtures of M-lauryl sulfate and M-lauryl sulfate plus from 1 to 10 moles of ethyleneoxide and mixtures of M-lauryl sulfate and triethanola- mine lauryl sulfate wherein M is selected from sodium, potassium and ammonium, from 1.0 to 3.5% by weight of an inorganic salt soluble in the composition and from 0.25 to 1% by weight of an acid selected from citric acid, boric acid, hydrochloric acid, phosphoric acid, ascorbic acid and mixtures thereof, the composition having a pH within the range of 3 to 4.5 and a viscosity within the range of from 4000 to 15,000 centipoise at 20"C.
It is surprisingly found that the composi-tion having an increased viscosity performs significantly better than a similar composition having a lower viscosity and that compositions having lower pHs perform better than compositions having higher pHs, furthermore the compositions having lower pH and higher viscosity perform better than the similar compositions having either higher pH or lower viscosity. The improvement in performance appears to be synergistic since the combined effects of increased viscosity and decreased pH are exceeded by the composition having increased viscosity and decreased pH.
The prime cleaning component of the composition of the present invention is the anionic detergent. Anionic detergents useful in the present invention are selected from the group of M-lauryl sulfate, mixtures of
M-lauryl sulfate and M-lauryl sulfate plus 1 to 10 moles of ethyleneoxide and mixtures of M-lauryl sulfate and triethanolamine lauryl sulfate wherein M is selected from sodium, potassium and ammonium. The total anionic detergent present in the composition in the present invention should be within the range of from 12.5 to 25% by weight and particularly within the range from 14 to 21% by weight anionic detergent.. When mixtures of M-lauryl sulfate are used with the other anionic detergents as described above, the mixture should be within the range of from 0 to 9 parts other anionic detergent per 1 part M-lauryl-sul- fate. The preferred M-lauryl sulfate for use in the composition of the pressent invention is ammonium lauryl sulfate.
The second component of the composition of the present invention is an inorganic salt.
The primary function of the inorganic salt is to provide free electrolyte which increases the viscosity of the composition. Within a certain range of inorganic salts, the viscosity of the composition increases, however, above or below the range, i.e. from 1.0 to 3.5% by weight. the viscosity of the resultant shampoo composition decreases. It is within this maximum range of viscosity that the performance properties of the shampoo are most surprising. Any non-toxic inorganic salt which is soluble in the composition of the present invention is suitable such as sodium chloride, potassium chloride, lithium chloride, ammonium chloride, sodium citrate, potassium citrate, lithium citrate and ammonium citrate. The preferred inorganic salts are ammonium chloride, sodium chloride and potassium chloride. The most preferred salt is ammonium chloride. As noted above, these salts may be present in a range of from 1.0 to 3.5% and is preferred that the salt be present in the range of about 1.4 to 2.75% by weight of the total composition.
The viscosity of the composition should be within the range of 4000 to 15,000 centipoise and preferably within the range of 5000 to 10,000 centipoise. The viscosity is measured at 20CC using a Brookfield viscometer equipped with a number LV4 spindle set at 30 RPM.
The third component of the present invention is an acidifying agent. The prime purpose of these acidifying or pH control agents is to lower the pH of the resultant composition. Although any suitable acid can be utilized to control the pH of the composition it has been found particularly acceptiblet to use the following acids: citric acid, boric acid, hydrochloric acid, phosphoric acid, ascorbic acid and mixtures.
These acids tend to have a buffering effect within the desired pH range when used in combination with the lauryl sulfate anionic detergent and the ionrganic salt. Although the exact amount of the acid is not critical, it is important to add sufficient acid to the composition so that the pH is maintained within the range of from 3 to 4.5 and preferably within the range of 3.3A.0. Generally from 0.25 to 1% by weight is satisfactory.
The bulk of the composition of the present invention comprises water. Substantially any water can be utilized in the composition although good manufacturing procedures require that the water be deionized and substantially free of major contaminants and impurities.
In addition to the above noted ingredients compositions of the present invention can include a number of other conventional additives including dyes, pigments, pearlessing agents, perfumes, preservatives and the like. These ingredients should be present in the composition preferably in combined amounts of less than 5% and in individual amounts of less than 2% each.
The composition of the present invention will now be illustrated by way of the following examples which are for the purpose of illustration only and are in no way to be considered as limiting.
EXAMPLE I
A shampoo composition having the following composition was preparel: ammonium lauryl sulfate (28%) 60%, ammonium chloride 2.5%, citric acid 0.35%, fragrance 0.5%, formalin 0.134%, color QS, deionized water to 100%. The composition as prepared had a pH of 3.65 and a viscosity of 10,000.
Coiitparattive Examples I, II and III
Compositions similar to the composition in Example I were prepared with the exeep- tion that the level of citric acid and ammonium chloride was varied as shown in
Table I.
TABLE I
Example Citric Acid NH4C1 pH Visc A L I .. . . ... . 0.35 2.5 3.65 10,200 254
Comparative Ex. 1 - 0.5 6.0 29 180
Comparative Ex. 2 - 2,5 5.6 10,800 199
Comparative Ex. 3 0.35 0.5 3.7 45 220
The compositions of the comparative
Examples I, II and III and Example I were all tested on about 30 women in half head tests comparing 2 different formulations. The composition of Example I was preferred over each of the comparative examples,
Furthermore, each of these compositions was tested in a Terg-O-Tometer for cleaning.
The cleaning scores AL for Example I were higher than the cleaning scores from comparative examples I, II and m and the improvement in cleaning from comparative example I to Example I is greater than the combined increase from comparative 'Examples II and III.
EXAMPLES 24 The following shampoo formulations were prepared:
Example 2 Example 3 Example 4
Ammonium Lauryl Sulfate (28%) .. 50.0 60.0 75.0
Ammonium Chloride . 2.75 2.0 1.4
Citric Acid 0.35 0.35 0.35
Color qs qs qs
Fragrance qs qs qs
Formalin qs qs qs
D.I. Water qs qs qs
100.0 100.0 100.0 pH ... 3.6 3.6 3.6
Viscosity 6000 6000 6000
Each of the above formula performed in a manner similar to the formula of Example 1.
WHAT WE CLAIM IS:- 1. A shampoo composition comprising from 12.5 to 25% by weight of an anionic detergent selected from the group consisting of M-lauryl sulfate, mixtures of M-lauryl sulfate with M-lauryl sulfate plus 1 to 10 moles of ethyeneoxide and mixtures of Mlauryl sulfate and triethanolamine lauryl sulfate wherein M is sodium, potassium and ammonium, from 0.25 to 1% by weight of an acid selected from citric acid, boric acid, hydrochloric acid, phosphoric acid, ascorbic acid and mixtures thereof, from 1.0 to 3.5% by weight of an inorganic salt soluble in the composition and water! the composition having a pH within the range of from 3 to 4.5 and a viscosity of from 4000 to 15,000 centipoise at 200 C.
2. The shampoo composition of claim 1 where the pH is 3.3 to 4.0.
3. The shampoo composition of claim 1 or 2 wherein said acid is citric acid.
4. The shampoo composition of claim 1, 2 or 3 wherein said salt is selected from the group consisting of ammonium chloride.
sodium chloride, potassium chloride and mixtures.
5. The shampoo composition of claim 4 wherein said salt is ammonium chloride.
6. The shampoo composition of any of claims 1 to 5 wherein the detergent is present in an amount of from 14 to 21% by weight.
7. The shampoo composition of any of claims 1 to 6 wherein said detergent is ammonium lauryl sulfate.
8. The shampoo composition of any of claims 1 to 7 wherein said detergent is a mixture of M-lauryl sulfate and M-lauryl sulfate plus 1 to 10 moles ethyleneoxide in a ratio of M-lauryl sulfate plus 1 to 10 moles ethyleneoxide to M-lauryl sulfate of 0 to 9:1.
9. A shampoo composition comprising from 14.0 to 21.0% by weight of an ammonium lauryl sulfate to 0.35% by weight of citric acid, from 1.4 to 2.75% by weight of ammonium chloride and water to 100%; the composition having a pH within the range of from 3.3 to 4.5 and a viscosity of from 5000 to 15,000 centipoise at 20"C.
10. The shampoo composition substantially as derein described with reference to the Examples in the accompanying disclosure.
**WARNING** end of DESC field may overlap start of CLMS **.
Claims (10)
1. A shampoo composition comprising from 12.5 to 25% by weight of an anionic detergent selected from the group consisting of M-lauryl sulfate, mixtures of M-lauryl sulfate with M-lauryl sulfate plus 1 to 10 moles of ethyeneoxide and mixtures of Mlauryl sulfate and triethanolamine lauryl sulfate wherein M is sodium, potassium and ammonium, from 0.25 to 1% by weight of an acid selected from citric acid, boric acid, hydrochloric acid, phosphoric acid, ascorbic acid and mixtures thereof, from 1.0 to 3.5% by weight of an inorganic salt soluble in the composition and water! the composition having a pH within the range of from 3 to 4.5 and a viscosity of from 4000 to 15,000 centipoise at 200 C.
2. The shampoo composition of claim 1 where the pH is 3.3 to 4.0.
3. The shampoo composition of claim 1 or 2 wherein said acid is citric acid.
4. The shampoo composition of claim 1, 2 or 3 wherein said salt is selected from the group consisting of ammonium chloride.
sodium chloride, potassium chloride and mixtures.
5. The shampoo composition of claim 4 wherein said salt is ammonium chloride.
6. The shampoo composition of any of claims 1 to 5 wherein the detergent is present in an amount of from 14 to 21% by weight.
7. The shampoo composition of any of claims 1 to 6 wherein said detergent is ammonium lauryl sulfate.
8. The shampoo composition of any of claims 1 to 7 wherein said detergent is a mixture of M-lauryl sulfate and M-lauryl sulfate plus 1 to 10 moles ethyleneoxide in a ratio of M-lauryl sulfate plus 1 to 10 moles ethyleneoxide to M-lauryl sulfate of 0 to 9:1.
9. A shampoo composition comprising from 14.0 to 21.0% by weight of an ammonium lauryl sulfate to 0.35% by weight of citric acid, from 1.4 to 2.75% by weight of ammonium chloride and water to 100%; the composition having a pH within the range of from 3.3 to 4.5 and a viscosity of from 5000 to 15,000 centipoise at 20"C.
10. The shampoo composition substantially as derein described with reference to the Examples in the accompanying disclosure.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78285577A | 1977-03-30 | 1977-03-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1567742A true GB1567742A (en) | 1980-05-21 |
Family
ID=25127390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB10114/78A Expired GB1567742A (en) | 1977-03-30 | 1978-03-14 | Shampoo composition |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS53143613A (en) |
| AR (1) | AR217839A1 (en) |
| AU (1) | AU515143B2 (en) |
| CA (1) | CA1100044A (en) |
| FR (1) | FR2385793A1 (en) |
| GB (1) | GB1567742A (en) |
| IT (1) | IT1156180B (en) |
| NL (1) | NL7803157A (en) |
| NZ (1) | NZ186708A (en) |
| PH (1) | PH13266A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3206350A1 (en) * | 1981-02-23 | 1982-09-23 | Kao Soap Co., Ltd., Tokyo | LIQUID DETERGENT MIXTURE |
| WO2001007010A1 (en) * | 1999-07-26 | 2001-02-01 | Alberto-Culver Company | Personal cleansing composition and method |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19504914C1 (en) * | 1995-02-15 | 1995-11-16 | Goldwell Gmbh | Hair washing agent giving gloss and body, and easy combing |
| JP3887283B2 (en) * | 2002-08-09 | 2007-02-28 | 花王株式会社 | Shampoo composition |
-
1978
- 1978-03-14 GB GB10114/78A patent/GB1567742A/en not_active Expired
- 1978-03-16 NZ NZ186708A patent/NZ186708A/en unknown
- 1978-03-23 NL NL7803157A patent/NL7803157A/en not_active Application Discontinuation
- 1978-03-28 JP JP3491278A patent/JPS53143613A/en active Granted
- 1978-03-28 IT IT48622/78A patent/IT1156180B/en active
- 1978-03-29 AR AR271590A patent/AR217839A1/en active
- 1978-03-29 CA CA299,935A patent/CA1100044A/en not_active Expired
- 1978-03-29 PH PH20951A patent/PH13266A/en unknown
- 1978-03-29 AU AU34563/78A patent/AU515143B2/en not_active Expired
- 1978-03-29 FR FR7809051A patent/FR2385793A1/en active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3206350A1 (en) * | 1981-02-23 | 1982-09-23 | Kao Soap Co., Ltd., Tokyo | LIQUID DETERGENT MIXTURE |
| WO2001007010A1 (en) * | 1999-07-26 | 2001-02-01 | Alberto-Culver Company | Personal cleansing composition and method |
| US6365559B1 (en) | 1999-07-26 | 2002-04-02 | Alberto-Culver Company | Personal cleansing composition and method |
| US6566314B1 (en) * | 1999-07-26 | 2003-05-20 | Alberto-Culver Company | Personal cleansing composition and method |
| AU778938B2 (en) * | 1999-07-26 | 2004-12-23 | Alberto-Culver Company | Personal cleansing composition and method |
Also Published As
| Publication number | Publication date |
|---|---|
| AU515143B2 (en) | 1981-03-19 |
| CA1100044A (en) | 1981-04-28 |
| NZ186708A (en) | 1980-02-21 |
| NL7803157A (en) | 1978-10-03 |
| FR2385793B1 (en) | 1983-02-04 |
| PH13266A (en) | 1980-02-27 |
| IT1156180B (en) | 1987-01-28 |
| JPS6220168B2 (en) | 1987-05-06 |
| IT7848622A0 (en) | 1978-03-28 |
| FR2385793A1 (en) | 1978-10-27 |
| AR217839A1 (en) | 1980-04-30 |
| AU3456378A (en) | 1979-10-04 |
| JPS53143613A (en) | 1978-12-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |