GB1537375A - Soluble copper phthalocyanine dyes and their use - Google Patents

Soluble copper phthalocyanine dyes and their use

Info

Publication number
GB1537375A
GB1537375A GB571776A GB571776A GB1537375A GB 1537375 A GB1537375 A GB 1537375A GB 571776 A GB571776 A GB 571776A GB 571776 A GB571776 A GB 571776A GB 1537375 A GB1537375 A GB 1537375A
Authority
GB
United Kingdom
Prior art keywords
phenyl
copper phthalocyanine
groups
dyes
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB571776A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE19752506153 priority Critical patent/DE2506153A1/en
Application filed by BASF SE filed Critical BASF SE
Publication of GB1537375A publication Critical patent/GB1537375A/en
Application status is Expired legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
    • C08K5/00Use of organic ingredients
    • C08K5/0091Complexes with metal-heteroatom-bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B47/00Porphines; Azaporphines
    • C09B47/04Phthalocyanines abbreviation: Pc
    • C09B47/08Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex

Abstract

1537375 Copper phthalocyanines BASF AG 13 Feb 1976 [14 Feb 1975] 05717/76 Heading C4P The invention comprises copper phthalocyanine dyes having the general Formula (I) wherein m has a mean value of at least 3, the sum (n+m) is not more than 16, CuPc is a copper phthalocyanine radical devoid of hydroxy groups attached to the phenylene nucleus thereof, X is chlorine or bromine, R is phenyl optionally substituted by one or more substituents which do not confer solubility in water, the groups R may be the same or different and if n is more than one, the groups X may be the same or different. Preferred R groups are phenyl, methyl-phenyl, tbutylphenyl, i-propylphenyl, octylphenyl, dodecylphenyl, dimethylphenyl, diethylphenyl, trifluoromethylphenyl, methoxyphenyl, cyclohexylphenyl, diphenyl, bis-(phenylethyl)phenyl, 4-(α,α- dimethyl - p - hydroxybenzyl) phenyl, dimethyl-, aminophenyl, 2 - pyrrolidon - 1 - yl - phenyl, chlorophenyl and chloromethylphenyl. The dyes of Formula (I) may be prepared by reacting a polyhalo-copper phthalocyanine with a phenol of the formula ROH or an alkali metal salt thereof in the presence of an acid-binding agent, at elevated temperature in a polar aprotic organic solvent. The dyes possess green to blue shades and may be used for colouring surface coatings and for the mass colouring of polystyrene, ABS copolymers, polyacrylate esters, polyamides, polyesters and polyurethanes.
GB571776A 1975-02-14 1976-02-13 Soluble copper phthalocyanine dyes and their use Expired GB1537375A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19752506153 DE2506153A1 (en) 1975-02-14 1975-02-14 Soluble copper phthalocyanine and its application

Publications (1)

Publication Number Publication Date
GB1537375A true GB1537375A (en) 1978-12-29

Family

ID=5938845

Family Applications (1)

Application Number Title Priority Date Filing Date
GB571776A Expired GB1537375A (en) 1975-02-14 1976-02-13 Soluble copper phthalocyanine dyes and their use

Country Status (6)

Country Link
JP (1) JPS51106125A (en)
CH (1) CH601440A5 (en)
DE (1) DE2506153A1 (en)
FR (1) FR2300788B1 (en)
GB (1) GB1537375A (en)
IT (1) IT1053848B (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5135972A (en) * 1989-09-18 1992-08-04 Milliken Research Corporation Poly(oxyalkylene) modified phthalocyanine colorants
US5292855A (en) * 1993-02-18 1994-03-08 Eastman Kodak Company Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein
US5397819A (en) * 1991-11-08 1995-03-14 Eastman Chemical Company Thermoplastic materials containing near infrared fluorophores
US5423432A (en) * 1993-12-30 1995-06-13 Eastman Chemical Company Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein
US5990197A (en) * 1996-10-28 1999-11-23 Eastman Chemical Company Organic solvent based ink for invisible marking/identification
US6138913A (en) * 1997-11-05 2000-10-31 Isotag Technology, Inc. Security document and method using invisible coded markings
US6197851B1 (en) 1996-08-30 2001-03-06 Eastman Chemical Company Polyester compositions containing near infrared absorbing materials to improve reheat
US6217794B1 (en) 1998-06-01 2001-04-17 Isotag Technology, Inc. Fiber coating composition having an invisible marker and process for making same
US6432715B1 (en) 1998-02-24 2002-08-13 Isotag Technology, Inc. Method for marking items for identification

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61152769A (en) * 1984-12-26 1986-07-11 Tdk Corp Phthalocyanine compound
EP0523959B1 (en) * 1991-07-15 1999-10-13 Nippon Shokubai Co., Ltd. Novel phthalocyanine compounds, production method thereof, and near infrared ray absorption materials containing the same
JP5089190B2 (en) * 2006-02-15 2012-12-05 キヤノン株式会社 Water-based ink, ink set, ink jet recording method, ink cartridge, recording unit and ink jet recording apparatus

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5135972A (en) * 1989-09-18 1992-08-04 Milliken Research Corporation Poly(oxyalkylene) modified phthalocyanine colorants
US5397819A (en) * 1991-11-08 1995-03-14 Eastman Chemical Company Thermoplastic materials containing near infrared fluorophores
US5461136A (en) * 1991-11-08 1995-10-24 Eastman Chemical Company Method for tagging thermoplastic materials with near infrared fluorophores
US5553714A (en) * 1991-11-08 1996-09-10 Eastman Chemical Company Method for detecting and separating thermoplastic containers with near infrared fluorosphores
US5703229A (en) * 1991-11-08 1997-12-30 Eastman Chemical Company Method for tagging thermoplastic materials with near infrared fluorophores
US5292855A (en) * 1993-02-18 1994-03-08 Eastman Kodak Company Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein
US5423432A (en) * 1993-12-30 1995-06-13 Eastman Chemical Company Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein
US6197851B1 (en) 1996-08-30 2001-03-06 Eastman Chemical Company Polyester compositions containing near infrared absorbing materials to improve reheat
US5990197A (en) * 1996-10-28 1999-11-23 Eastman Chemical Company Organic solvent based ink for invisible marking/identification
US6138913A (en) * 1997-11-05 2000-10-31 Isotag Technology, Inc. Security document and method using invisible coded markings
US6432715B1 (en) 1998-02-24 2002-08-13 Isotag Technology, Inc. Method for marking items for identification
US6217794B1 (en) 1998-06-01 2001-04-17 Isotag Technology, Inc. Fiber coating composition having an invisible marker and process for making same

Also Published As

Publication number Publication date
FR2300788B1 (en) 1980-04-18
CH601440A5 (en) 1978-07-14
JPS51106125A (en) 1976-09-20
IT1053848B (en) 1981-10-10
FR2300788A1 (en) 1976-09-10
DE2506153A1 (en) 1976-08-26

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee