GB1512730A - Manufacture of a titanium component for catalysts of the ziegler-natta type - Google Patents
Manufacture of a titanium component for catalysts of the ziegler-natta typeInfo
- Publication number
- GB1512730A GB1512730A GB35686/75A GB3568675A GB1512730A GB 1512730 A GB1512730 A GB 1512730A GB 35686/75 A GB35686/75 A GB 35686/75A GB 3568675 A GB3568675 A GB 3568675A GB 1512730 A GB1512730 A GB 1512730A
- Authority
- GB
- United Kingdom
- Prior art keywords
- grinding
- hours
- mixture
- mill
- whilst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1512730 Polymerisation catalyst BASF AG 29 Aug 1975 [30 Aug 1974] 35686/75 Heading BIE [Also in Division C3] A titanium component for use in the Ziegler polymerization of olefins is obtained by dry grinding, in a vibratory ball mill at a grinding acceleration of 30 to 80 m. sec<SP>-2</SP>, a mixture of (a) TiCl 3 . n AlCl 3 where n is 0 to 0.7 and (b) 0.01 to 1 mole per mole of (a) of a compound of the formula PO m X 3 , where m is 0 or I, X is R, OR or NR 2 and R is hydrocarbyl, in which procedure (i) a mill of useful volume 2 to 200 litres is used, (ii) the mill is first charged with 0.1 to 120 kg. of (a), (iii) thereafter the required amount of (b) is added over 2 to 100 hours, continuously or in small portions, whilst grinding at -50C to -5C, (iv) the mixture is then brought to 5 to 60C, over a period of 0.1 to 5 hours, and kept at these temperatures for 1 to 100 hours, whilst continuing grinding, (v) a finely divided particulate 1-alkene polymer, having a particle size of 1 to 10,000Á, a Tg of -100 to 60C and an intrinsic viscosity of 0.1 to 20, is added and (vi) the mixture is kept at -50 to -5C for 1 to 30 minutes, whilst continuing the grinding. The Examples refer to the milling of T : Cl 3 . 1/3AlCl 3 and n Bu 3 P, with addition of particulate polypropylene or poly-4-methyl pentene 1 in stage (v).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2441541A DE2441541C2 (en) | 1974-08-30 | 1974-08-30 | Process for producing a modified titanium component for catalysts of the Ziegler-Natta type |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1512730A true GB1512730A (en) | 1978-06-01 |
Family
ID=5924456
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB35686/75A Expired GB1512730A (en) | 1974-08-30 | 1975-08-29 | Manufacture of a titanium component for catalysts of the ziegler-natta type |
Country Status (13)
Country | Link |
---|---|
JP (1) | JPS5150295A (en) |
AT (1) | AT334623B (en) |
BE (1) | BE832886A (en) |
CA (1) | CA1055469A (en) |
DE (1) | DE2441541C2 (en) |
ES (1) | ES440555A1 (en) |
FR (1) | FR2288550A1 (en) |
GB (1) | GB1512730A (en) |
IT (1) | IT1041808B (en) |
NL (1) | NL7510015A (en) |
NO (1) | NO752976L (en) |
SE (1) | SE7509428L (en) |
ZA (1) | ZA755564B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0072128A2 (en) | 1981-08-07 | 1983-02-16 | Imperial Chemical Industries Plc | Spraying solid |
EP2277922A1 (en) * | 1998-10-27 | 2011-01-26 | Westlake Longview Corporation | Process for the polymerization of olefins; polyethylenes, and films and articles produced therefrom |
EP2565210A4 (en) * | 2010-04-28 | 2015-05-27 | Mitsui Chemicals Inc | Resin fine powder consisting of 4-methyl-1-pentene polymer, composition containing same, and process for production thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3125037C1 (en) * | 1981-06-26 | 1983-03-10 | Hans 3559 Battenberg Vießmann | Boiler |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5323351B1 (en) * | 1970-12-29 | 1978-07-14 | ||
DE2226167C3 (en) * | 1972-05-30 | 1979-04-26 | Basf Ag, 6700 Ludwigshafen | Process for the polymerization of α-olefins |
DE2400190C2 (en) * | 1974-01-03 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Process for producing a modified titanium component for catalysts of the Ziegler-Natta type |
-
1974
- 1974-08-30 DE DE2441541A patent/DE2441541C2/en not_active Expired
-
1975
- 1975-08-11 IT IT26289/75A patent/IT1041808B/en active
- 1975-08-18 CA CA233,667A patent/CA1055469A/en not_active Expired
- 1975-08-25 NL NL7510015A patent/NL7510015A/en not_active Application Discontinuation
- 1975-08-25 SE SE7509428A patent/SE7509428L/en unknown
- 1975-08-27 FR FR7526407A patent/FR2288550A1/en active Granted
- 1975-08-29 BE BE159580A patent/BE832886A/en not_active IP Right Cessation
- 1975-08-29 AT AT668575A patent/AT334623B/en not_active IP Right Cessation
- 1975-08-29 GB GB35686/75A patent/GB1512730A/en not_active Expired
- 1975-08-29 ES ES440555A patent/ES440555A1/en not_active Expired
- 1975-08-29 JP JP50104157A patent/JPS5150295A/en active Pending
- 1975-08-29 ZA ZA00755564A patent/ZA755564B/en unknown
- 1975-08-29 NO NO752976A patent/NO752976L/no unknown
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0072128A2 (en) | 1981-08-07 | 1983-02-16 | Imperial Chemical Industries Plc | Spraying solid |
EP0072128A3 (en) * | 1981-08-07 | 1984-02-22 | Imperial Chemical Industries Plc | Spraying solid |
US4465783A (en) * | 1981-08-07 | 1984-08-14 | Imperial Chemical Industries Plc | Spraying solid |
EP2277922A1 (en) * | 1998-10-27 | 2011-01-26 | Westlake Longview Corporation | Process for the polymerization of olefins; polyethylenes, and films and articles produced therefrom |
EP2277923A1 (en) * | 1998-10-27 | 2011-01-26 | Westlake Longview Corporation | Process for the polymerization of olefins; polyethylenes, and films and articles produced therefrom |
EP2565210A4 (en) * | 2010-04-28 | 2015-05-27 | Mitsui Chemicals Inc | Resin fine powder consisting of 4-methyl-1-pentene polymer, composition containing same, and process for production thereof |
US9260549B2 (en) | 2010-04-28 | 2016-02-16 | Mitsui Chemicals, Inc. | Resin fine powder consisting of 4-methyl-1-pentene polymer, composition containing same, and process for production thereof |
Also Published As
Publication number | Publication date |
---|---|
DE2441541C2 (en) | 1982-07-15 |
NL7510015A (en) | 1976-03-02 |
BE832886A (en) | 1976-03-01 |
SE7509428L (en) | 1976-03-01 |
JPS5150295A (en) | 1976-05-01 |
DE2441541A1 (en) | 1976-04-15 |
ES440555A1 (en) | 1977-03-01 |
NO752976L (en) | 1976-03-02 |
FR2288550B1 (en) | 1979-05-18 |
AT334623B (en) | 1976-01-25 |
FR2288550A1 (en) | 1976-05-21 |
ATA668575A (en) | 1976-05-15 |
IT1041808B (en) | 1980-01-10 |
AU8407975A (en) | 1977-02-24 |
CA1055469A (en) | 1979-05-29 |
ZA755564B (en) | 1976-08-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] |