GB1512414A - Process for preparing butanediol-(1,4) - Google Patents

Process for preparing butanediol-(1,4)

Info

Publication number
GB1512414A
GB1512414A GB3044875A GB3044875A GB1512414A GB 1512414 A GB1512414 A GB 1512414A GB 3044875 A GB3044875 A GB 3044875A GB 3044875 A GB3044875 A GB 3044875A GB 1512414 A GB1512414 A GB 1512414A
Authority
GB
United Kingdom
Prior art keywords
diol
butane
chromium oxide
ene
promoter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3044875A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of GB1512414A publication Critical patent/GB1512414A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1512414 Butane-1,4-diol HOECHST AG 21 July 1975 [20 July 1974] 30448/75 Heading C2C Butane-1,4-diol is obtained by catalytically reacting but - 2 - ene - 1,4 - diol diacetate (I), but - 2 - ene - 1,4 - diol monoacetate (II), butane-1,4-diol diacetate (III) or butane-1,4- diol monoacetate IV, or a mixture of two or more thereof, with hydrogen. The catalyst is for example copper-chromium oxide to which may be added as promoter thorium or an element from Groups IVa, Va, VIa, VIIa or VIII of the Periodic Table. In the examples, copper chromium oxide was used with Mu, Re, Mo, V and Th as promoter; rhenium or rhodium on active carbon was also used mixed with the copper chromium oxide catalyst. When using I as starting material II, III and IV may be obtained as intermediates which need not be separated. Temperatures of 100-300‹ C. and pressures of 50-400 bars are suitable.
GB3044875A 1974-07-20 1975-07-21 Process for preparing butanediol-(1,4) Expired GB1512414A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2434991A DE2434991A1 (en) 1974-07-20 1974-07-20 PROCESS FOR PREPARING BUTANDIOL- (1,4)

Publications (1)

Publication Number Publication Date
GB1512414A true GB1512414A (en) 1978-06-01

Family

ID=5921083

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3044875A Expired GB1512414A (en) 1974-07-20 1975-07-21 Process for preparing butanediol-(1,4)

Country Status (3)

Country Link
JP (1) JPS5136404A (en)
DE (1) DE2434991A1 (en)
GB (1) GB1512414A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2715666A1 (en) * 1977-04-07 1978-10-12 Hoechst Ag PROCESS FOR THE MANUFACTURING OF ETHYLENE GLYCOL
DE2847068A1 (en) * 1978-10-28 1980-05-08 Basf Ag METHOD FOR PRODUCING BUTEDIOL DIACETATES AND BUTANDIOL

Also Published As

Publication number Publication date
JPS5136404A (en) 1976-03-27
DE2434991A1 (en) 1976-02-05

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee