GB1504706A - Gas purification liquors - Google Patents
Gas purification liquorsInfo
- Publication number
- GB1504706A GB1504706A GB3461674A GB3461674A GB1504706A GB 1504706 A GB1504706 A GB 1504706A GB 3461674 A GB3461674 A GB 3461674A GB 3461674 A GB3461674 A GB 3461674A GB 1504706 A GB1504706 A GB 1504706A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solution
- nucleus
- sulphur
- quinoid
- quinone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
1504706 Removing HIS from gases BRITISH GAS CORP 5 Aug 1975 [6 Aug 1974] 34616/74 Heading C1A A composition for absorbing H 2 S from gases and liquid hydrocarbons comprises an aqueous alkaline solution, e.g. pH 8À5-9À5) containing ions of a metal capable of exhibiting at least two valence states and a quinone of formula where A is an aryl or quinoid nucleus, X' and X<SP>2</SP> are OH when A is aryl or are the O atoms of the quinoid nucleus, R<SP>1</SP>, R<SP>2</SP>, R<SP>3</SP> and R<SP>4</SP> are H or solubilizing groups, e.g. SO 3 H, OH, NO 2 or ONO, provided that when A is an anthracyl or anthraquinoid nucleus, not more than one of R<SP>1</SP>, R<SP>2</SP>, R<SP>3</SP> and R<SP>4</SP> is SO 3 H. The quinone may be p-benzoquinone, hydroquinone, H-bonded quinhydrones, 1,4 - naphthaquinone - 2 - SO 3 H, 1 - SO 3 H - 6 - NO 2 (or - 7 - NO 2 )anthraquinone or 1 - SO 3 H - 6 - OH (or -7 - OH) - anthraquinone. The metal ions may be derived from a vanadate, e.g. Na ammonium vanadate or Na orthovanadate, or a salt of Fe or Co, e.g. FeSO 4 or FeCl 3 . A chelating agent may be added. In operation, H 2 S is absorbed in the solution with formation of sulphur and reduction of the solution, which may be reoxidized after removal of the sulphur. Alternatively, reoxidation and sulphur removal may be effected simultaneously by blowing air through the used solution.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3461674A GB1504706A (en) | 1975-08-05 | 1975-08-05 | Gas purification liquors |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3461674A GB1504706A (en) | 1975-08-05 | 1975-08-05 | Gas purification liquors |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1504706A true GB1504706A (en) | 1978-03-22 |
Family
ID=10367874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3461674A Expired GB1504706A (en) | 1975-08-05 | 1975-08-05 | Gas purification liquors |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1504706A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4325936A (en) | 1979-06-20 | 1982-04-20 | Union Oil Company Of California | Method for removing hydrogen sulfide from gas streams |
US4432962A (en) * | 1979-06-20 | 1984-02-21 | Union Oil Company Of California | Method for removing hydrogen sulfide from gas streams |
EP0787225A1 (en) * | 1994-10-13 | 1997-08-06 | Catachem, Inc. | Method for minimizing solvent degradation and corrosion in amine solvent treating systems |
-
1975
- 1975-08-05 GB GB3461674A patent/GB1504706A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4325936A (en) | 1979-06-20 | 1982-04-20 | Union Oil Company Of California | Method for removing hydrogen sulfide from gas streams |
US4432962A (en) * | 1979-06-20 | 1984-02-21 | Union Oil Company Of California | Method for removing hydrogen sulfide from gas streams |
EP0787225A1 (en) * | 1994-10-13 | 1997-08-06 | Catachem, Inc. | Method for minimizing solvent degradation and corrosion in amine solvent treating systems |
EP0787225A4 (en) * | 1994-10-13 | 1998-01-14 | Catachem Inc | Method for minimizing solvent degradation and corrosion in amine solvent treating systems |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
CSNS | Application of which complete specification have been accepted and published, but patent is not sealed |