GB1502173A - Sulphuric acid alkylation process - Google Patents

Sulphuric acid alkylation process

Info

Publication number
GB1502173A
GB1502173A GB40163/75A GB4016375A GB1502173A GB 1502173 A GB1502173 A GB 1502173A GB 40163/75 A GB40163/75 A GB 40163/75A GB 4016375 A GB4016375 A GB 4016375A GB 1502173 A GB1502173 A GB 1502173A
Authority
GB
United Kingdom
Prior art keywords
alkyl
hydrocarbon
reaction zone
phase
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB40163/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texaco Development Corp
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/515,943 external-priority patent/US3956417A/en
Priority claimed from US05/515,942 external-priority patent/US4017263A/en
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of GB1502173A publication Critical patent/GB1502173A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1502173 Alkylating isoparaffins TEXACO DEVELOPMENT CORP 1 Oct 1975 [18 Oct 1974(2)] 40163/75 Heading C5E Isoparaffins are alkylated with C 3 -C 5 olefins in the liquid phase in the presence of H 2 SO 4 catalyst in a non-back-mixing reaction zone, the process comprising: (a) contacting isoparaffin and olefin reactant hydrocarbons with sulphuric acid alkylating catalyst containing 0À0005 to 0À5 weight per cent, based on sulphuric acid, of a micelle-forming amphiphilic compound (defined) to form a hydrocarbon in acid catalyst reaction emulsion; (b) flowing the reaction emulsion, at alkylation conditions, through the non-back-mixed reaction zone at a rate sufficient to provide a Reynolds number of at least 5000 for conversion of essentially all olefin reactant while maintaining the temperature within the reaction zone within the range of- 20‹ to 100‹ F., and; (c) centrifugally separating, in a separation zone, reaction zone effluent into a hydrocarbon phase comprising unreacted isoparaffin hydrocarbon and alkylate hydrocarbon, and an acid catalyst phase under dynamic separation conditions such that separated hydrocarbon phase is immediately removed from contact with separated acid catalyst phase. Suitable micelle-forming amphiphilic compounds are N(alkyl)alkyl sulphonamides, N(alkyl) benzene sulphonamides, alkyl sulphonium salts, alkylphosphonium salts, alkyl benzene sulphonic acids, aliphatic amines, N,N<SP>1</SP>,N<SP>11</SP>-tri(alkyl) phosphonic triamides, ammonium salts and salts of alkyl sulphates. Suitable compounds should contain at least one C 8 -C 24 alkyl radical.
GB40163/75A 1974-10-18 1975-10-01 Sulphuric acid alkylation process Expired GB1502173A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/515,943 US3956417A (en) 1974-10-18 1974-10-18 Isoparaffin-olefin alkylation utilizing a continuous sulfuric acid phase in a tubular reaction zone
US05/515,942 US4017263A (en) 1974-10-18 1974-10-18 Apparatus for sulfuric acid catalyzed alkylation process

Publications (1)

Publication Number Publication Date
GB1502173A true GB1502173A (en) 1978-02-22

Family

ID=27058661

Family Applications (1)

Application Number Title Priority Date Filing Date
GB40163/75A Expired GB1502173A (en) 1974-10-18 1975-10-01 Sulphuric acid alkylation process

Country Status (4)

Country Link
BR (1) BR7506788A (en)
DE (1) DE2541431A1 (en)
GB (1) GB1502173A (en)
SE (1) SE7511621L (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007031332A1 (en) * 2005-09-15 2007-03-22 Dsm Ip Assets B.V. Continuous chemical processes in centrifugal contact separators

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007031332A1 (en) * 2005-09-15 2007-03-22 Dsm Ip Assets B.V. Continuous chemical processes in centrifugal contact separators

Also Published As

Publication number Publication date
SE7511621L (en) 1976-04-20
DE2541431A1 (en) 1976-04-29
BR7506788A (en) 1976-07-06

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee