GB1501906A - N,n'-disubstituted sulphonyl hydrazines - Google Patents

N,n'-disubstituted sulphonyl hydrazines

Info

Publication number
GB1501906A
GB1501906A GB1843575A GB1843575A GB1501906A GB 1501906 A GB1501906 A GB 1501906A GB 1843575 A GB1843575 A GB 1843575A GB 1843575 A GB1843575 A GB 1843575A GB 1501906 A GB1501906 A GB 1501906A
Authority
GB
United Kingdom
Prior art keywords
formula
sulphonyl
reacting
hydrazines
haloformate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1843575A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Uniroyal Inc
Original Assignee
Uniroyal Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uniroyal Inc filed Critical Uniroyal Inc
Publication of GB1501906A publication Critical patent/GB1501906A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1501906 N,N<SP>1</SP>-disubstituted sulphonyl hydrazines UNIROYAL Inc 23 Dec 1975 [11 April 1975] 18435/75 Heading C2C [Also in Division C3] The invention comprises compounds of the formula wherein R is a hydrocarbyl radical, R<SP>1</SP> and R<SP>2</SP> are each -COOR<SP>3</SP> or -CONHR<SP>4</SP>, R<SP>3</SP> is a hydrocarbyl radical, R<SP>4</SP> is H or a hydrocarbyl radical and n is 1 or 2. N,N<SP>1</SP>-Dicarboxylate sulphonyl hydrazines may be obtained by (1) reacting a sulphinic acid of the formula with an azodiester of the formula (2) reacting a sulphonyl hydrazide of the formula with a haloformate of the formula wherein X is Cl or Br, or (3) reacting a sulphonyl carbazate of the formula with a haloformate of the above formula. N - Carboxylate - N<SP>1</SP> - carbamyl sulphonyl hydrazines may be obtained by reacting a sulphonyl semicarbazide with a haloformate of the above formula. N-Carbamyl-N<SP>1</SP>-carboxylate sulphonyl hydrazines may be obtained by (1) reacting a sulphonyl carbazate of the above formula with an isocyanate of the formula wherein R<SP>4</SP> is a hydrocarbyl radical; or (2) reacting a sulphinic acid of the above formula with a 1-carboxylate-2-carbonamide-diimide of the formula which also produces isomeric N-carboxylate-N<SP>1</SP>- carbamyl sulphonyl hydrazines. N,N<SP>1</SP>-Dicarbamyl sulphonyl hydrazines may be obtained by reacting an azodicarbonamide of the formula with a sulphinic acid of the above formula. Bis-compounds of the formula may be obtained by reacting a sulphonyl hydrazide of the formula with a haloformate of the above formula. Other bis-compounds are obtained by analogous methods. The products are useful as blowing agents for gas-expandable polymers.
GB1843575A 1975-04-11 1975-12-23 N,n'-disubstituted sulphonyl hydrazines Expired GB1501906A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US56716975A 1975-04-11 1975-04-11

Publications (1)

Publication Number Publication Date
GB1501906A true GB1501906A (en) 1978-02-22

Family

ID=24266011

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1843575A Expired GB1501906A (en) 1975-04-11 1975-12-23 N,n'-disubstituted sulphonyl hydrazines

Country Status (4)

Country Link
BE (1) BE829799A (en)
DE (2) DE2524615A1 (en)
GB (1) GB1501906A (en)
IT (1) IT1036169B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114105927B (en) * 2020-08-31 2023-10-24 湖南超亟检测技术有限责任公司 Construction of benzopyran nitrile fluorescent molecular probe and in-vitro diagnosis application thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE821423C (en) * 1949-04-06 1951-11-19 Bayer Ag Propellant for the production of sponge, foam and cellular rubber from natural or synthetic rubber and for the production of foam compounds from plastics
GB689438A (en) * 1950-08-01 1953-03-25 Us Rubber Co p,p-oxybis (benzene sulfonyl hydrazide)
US3235519A (en) * 1959-12-31 1966-02-15 Us Rubber Co Sulfonyl semicarbazides as blowing agents for polymeric materials

Also Published As

Publication number Publication date
DE2602808A1 (en) 1976-10-21
BE829799A (en) 1975-12-02
DE2524615A1 (en) 1976-10-21
IT1036169B (en) 1979-10-30
DE2602808C2 (en) 1986-12-04

Similar Documents

Publication Publication Date Title
GB1501607A (en) Substituted n-phenyl-n&#39;-benzoyl-ureas and their use as insecticides
GB1127050A (en) Substituted phenylcarbamates and herbicidal preparations thereof
AU553145B2 (en) N-meterocyclylmethyl amides
AU6897694A (en) Preparation of 1,2-diacyl-2-(t-alkyl)hydrazines
GB1505120A (en) Sulphonyl carbazides as blowing agents
IE36124B1 (en) Amino pyridine compounds and compositions
GB1501906A (en) N,n&#39;-disubstituted sulphonyl hydrazines
GB1491840A (en) Derivatives of copolymers of carbon monoxide and ethylene
GB1055305A (en) Process for the production of polymeric hydrazodicarbon amides
GB1503932A (en) 2,3-dihalogen-alkanoyl-ureas and their use as fungicides
IE35753B1 (en) Bis-pyridyl amine compounds
GB825693A (en) Benzyl isothiocyanates
GB1328947A (en) Phenylhydrazones a process for their preparation and their use as insecticides acaricides and fungicides
GB1526466A (en) Stabilized olefin polymer compositions
GB1514036A (en) Process for the preparation of triazine-2,4-diones and their use as pesticides
GB1407743A (en) Peptide compounds and methods for their production
GB1505868A (en) I-alkyl-i-cyanohydrazines and their use for the production of 1,2,4-triazole derivatives
GB1530416A (en) N,n&#39;-diphenyl-guanidine derivatives
ES464855A1 (en) 1-aziridine-carboxylic acid ester derivatives
GB1422922A (en) Process for the production of highly elastic polyurethane foams
GB1466623A (en) Nutrient compsoitions including heterocyclic compounds and methods involving the use of such compounds
GB1385802A (en) Substituted phenylthiocarbamates
GB1343791A (en) Benzothiadiazine carbamic acid derivatives and their use as fungicides
ES461076A1 (en) Carbamic acid ester, process for making the same and composition containing same
GB1351032A (en) Fluoroaminopyridazines

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee