GB1484864A - Granular material and its use as a catalyst - Google Patents
Granular material and its use as a catalystInfo
- Publication number
- GB1484864A GB1484864A GB57321/73A GB5732173A GB1484864A GB 1484864 A GB1484864 A GB 1484864A GB 57321/73 A GB57321/73 A GB 57321/73A GB 5732173 A GB5732173 A GB 5732173A GB 1484864 A GB1484864 A GB 1484864A
- Authority
- GB
- United Kingdom
- Prior art keywords
- iron
- granules
- oxide
- contain
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000008187 granular material Substances 0.000 title abstract 12
- 239000003054 catalyst Substances 0.000 title abstract 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 14
- 239000011148 porous material Substances 0.000 abstract 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 6
- 229910052742 iron Inorganic materials 0.000 abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- -1 iron group metals Chemical class 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- 229910001567 cementite Inorganic materials 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 229910001337 iron nitride Inorganic materials 0.000 abstract 2
- 238000005245 sintering Methods 0.000 abstract 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000000292 calcium oxide Substances 0.000 abstract 1
- 235000012255 calcium oxide Nutrition 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 229910002090 carbon oxide Inorganic materials 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010304 firing Methods 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- 238000005469 granulation Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 150000004767 nitrides Chemical class 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/51—Spheres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1484864 Iron-containing catalysts IMPERIAL CHEMICAL INDUSTRIES Ltd 25 Nov 1974 [11 Dec 1973] 57321/73 Heading B1E [Also in Divisions Cl and El] A catalyst comprises over 70% w/w (calculated as Fe 3 O 4 ) of metallic iron and/or iron oxide and/or iron nitride and/or iron carbide in the form of approximately spherical granules having a pore volume of at least 0.01 ml/g in pores of radius greater than 104A. Suitably, the granules have a pore volume of at least 0.05 ml/g in pores of radius smaller of 104A and the iron is present in the metallic state. The granular material may contain 1-20% of other iron group metals, especially cobalt. The granules may comprise oxidic material, e.g. Fe 3 O 4 , metallic iron having a passivating outer oxide layer, iron nitride having an outer passivating oxide layer or a carbided iron material. For use in ammonia synthesis, the granules may contain up to 5.0 wt. % calcia, up to 2.0% wt. magnesia, 0.5 to 5.0% wt. alumina and 0.3 to 2.0% wt. potassia. Other oxides, e.g. of Rb, Cs, Be, lanthamides, actinides, Mo or W may be present, as may platinum group metals, cobalt metal or silica. For use as a catalyst for hydrogenating nitriles, the granules may contain up to 5% wt. refractory oxide. For use as a catalyst for the reaction of carbon oxides and hydrogen, the granules may contain alkali. For use as a catalyst for decomposing steam, the granules may contain refractory oxides to increase its resistance to sintering and also oxides reducible more or less easily than iron oxide. The oxidic form of the granules is formed by fusing iron oxide and any other components present, cooling, crushing, selecting a particle size fraction to give the required pore volume, granulating and sintering. Fugitive materials may be added during granulation and then burned-out of the granules during firing to give the required pore volume Pores of steel less than 104A may be formed by reduction of the oxide to metallic iron. The nitride may be formed by reaction of the reduced granules with ammonia. Partial conversion to iron carbide may be effected by treatment with carbon monoxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB57321/73A GB1484864A (en) | 1974-11-25 | 1974-11-25 | Granular material and its use as a catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB57321/73A GB1484864A (en) | 1974-11-25 | 1974-11-25 | Granular material and its use as a catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1484864A true GB1484864A (en) | 1977-09-08 |
Family
ID=10478915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB57321/73A Expired GB1484864A (en) | 1974-11-25 | 1974-11-25 | Granular material and its use as a catalyst |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1484864A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0115927A2 (en) * | 1983-02-09 | 1984-08-15 | Imperial Chemical Industries Plc | Catalyst supports and hydrocarbon conversion processes employing catalysts based on these supports |
| US4772579A (en) * | 1985-11-08 | 1988-09-20 | Imperial Chemical Industries Plc | Catalyst precursors |
| US4789659A (en) * | 1986-06-12 | 1988-12-06 | Imperial Chemical Industries Plc | Catalyst of a sintered iron oxide-containing article |
| CN109453775A (en) * | 2018-10-26 | 2019-03-12 | 东莞理工学院 | A kind of porous carbon load simple substance iron catalyst and its preparation method and application using humin preparation |
| CN110420655A (en) * | 2019-07-29 | 2019-11-08 | 中南民族大学 | A kind of graphitic carbon package iron-nitrogen-carbon solid phase fenton catalyst preparation method and applications |
-
1974
- 1974-11-25 GB GB57321/73A patent/GB1484864A/en not_active Expired
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0115927A2 (en) * | 1983-02-09 | 1984-08-15 | Imperial Chemical Industries Plc | Catalyst supports and hydrocarbon conversion processes employing catalysts based on these supports |
| EP0115927A3 (en) * | 1983-02-09 | 1984-09-12 | Imperial Chemical Industries Plc | Catalyst supports and hydrocarbon conversion processes employing catalysts based on these supports |
| US4526885A (en) * | 1983-02-09 | 1985-07-02 | Imperial Chemical Industries Plc | Catalyst supports and hydrocarbon conversion processes employing catalysts based on these supports |
| US4772579A (en) * | 1985-11-08 | 1988-09-20 | Imperial Chemical Industries Plc | Catalyst precursors |
| US4789659A (en) * | 1986-06-12 | 1988-12-06 | Imperial Chemical Industries Plc | Catalyst of a sintered iron oxide-containing article |
| CN109453775A (en) * | 2018-10-26 | 2019-03-12 | 东莞理工学院 | A kind of porous carbon load simple substance iron catalyst and its preparation method and application using humin preparation |
| CN110420655A (en) * | 2019-07-29 | 2019-11-08 | 中南民族大学 | A kind of graphitic carbon package iron-nitrogen-carbon solid phase fenton catalyst preparation method and applications |
| CN110420655B (en) * | 2019-07-29 | 2022-07-08 | 中南民族大学 | Preparation method and application of graphite carbon-coated iron-nitrogen-carbon solid-phase Fenton catalyst |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |