GB1476487A - Manufacture of lead dioxide/titanium composite electrodes - Google Patents
Manufacture of lead dioxide/titanium composite electrodesInfo
- Publication number
- GB1476487A GB1476487A GB3859574A GB3859574A GB1476487A GB 1476487 A GB1476487 A GB 1476487A GB 3859574 A GB3859574 A GB 3859574A GB 3859574 A GB3859574 A GB 3859574A GB 1476487 A GB1476487 A GB 1476487A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pbo
- spraying
- lead dioxide
- boride
- sept
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
1476487 Lead dioxide/titanium electrodes BASF AG 4 Sept 1974 [5 Sept 1973 29 July 1974] 38595/74 Heading C7B A PbO 2 /Ti composite electrode, for an anode in a high current density cell, is made by anodic deposition of PbO 2 on an intermediate layer of a carbide or boride of Ti, Ta, Zr, Hf, V or Nb and/or a (di) silicide of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo or W and/or SiC applied to a Ti surface, e.g. by plasma or cathodic spraying, flame spraying, (chemical) vapour or electro-phoretic deposition. A carbide or boride may be applied by plasma spraying a powder thereof having a particle size of 15-90Á; or a layer 20-200Á thick and containing silicide and/or SiC modified with Fe, Ni, Co or a halide thereof may be applied. The Ti e.g. expanded mesh may be cleaned by sand or corundum blasting prior to coating. PbO 2 may be anodically deposited from a solution containing 1 to 25%Pb(II) nitrate or perchlorate, optionally up to 0À5%Cu(NO 3 ) 2 and up to 0À2% wetting agent based on ethoxylated alcohol, using a Cu sheet cathode at CD 1 to 10 A/dm<SP>2</SP>, the pH being maintained between 1 and 5 by adding PbCO 3 .
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19732344645 DE2344645C3 (en) | 1973-09-05 | Process for the production of lead dioxide-titanium composite electrodes | |
DE2436394A DE2436394A1 (en) | 1974-07-29 | 1974-07-29 | Lead dioxide coated titanium electrode mfr - with intermediate layer of carbide, boride or silicide of a transition metal |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1476487A true GB1476487A (en) | 1977-06-16 |
Family
ID=25765740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3859574A Expired GB1476487A (en) | 1973-09-05 | 1974-09-04 | Manufacture of lead dioxide/titanium composite electrodes |
Country Status (8)
Country | Link |
---|---|
US (1) | US3880728A (en) |
JP (1) | JPS5072878A (en) |
CA (1) | CA1030482A (en) |
CH (1) | CH592162A5 (en) |
FR (1) | FR2242783B1 (en) |
GB (1) | GB1476487A (en) |
IT (1) | IT1019188B (en) |
SE (1) | SE392622B (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3945852A (en) * | 1974-09-06 | 1976-03-23 | P. R. Mallory & Co. Inc. | Current collector for organic electrolyte batteries |
CA1041944A (en) * | 1974-11-04 | 1978-11-07 | Shinichiro Abe | Non-contaminating anode suitable for electrowinning applications |
GB1476055A (en) * | 1975-03-05 | 1977-06-10 | Imp Metal Ind Kynoch Ltd | Eletro-winning metals |
US4040939A (en) * | 1975-12-29 | 1977-08-09 | Diamond Shamrock Corporation | Lead dioxide electrode |
US4038170A (en) * | 1976-03-01 | 1977-07-26 | Rhees Raymond C | Anode containing lead dioxide deposit and process of production |
US4236978A (en) * | 1980-02-08 | 1980-12-02 | Rsr Corporation | Stable lead dioxide anode and method for production |
JPS5923890A (en) * | 1982-07-29 | 1984-02-07 | Plasma Giken Kogyo Kk | Insoluble electrode |
CH665429A5 (en) * | 1985-04-04 | 1988-05-13 | Bbc Brown Boveri & Cie | Electrochemical cell anode - with titanium carbide layer between titanium support and lead di:oxide layer |
ES2037614B1 (en) * | 1991-12-26 | 1994-02-01 | Tudor Acumulador | PROCEDURE FOR THE PREPARATION OF PLATES OR BIPOLAR LEAD-BIOXIDE LEAD ELECTRODES FOR ELECTRIC ACCUMULATORS. |
JP3124848B2 (en) * | 1992-11-11 | 2001-01-15 | ペルメレック電極株式会社 | Manufacturing method of metal foil by electrolysis |
DE10200072A1 (en) * | 2002-01-03 | 2003-07-31 | Bayer Ag | Electrodes for electrolysis in acid media |
US8017273B2 (en) | 2008-04-28 | 2011-09-13 | Ut-Battelle Llc | Lightweight, durable lead-acid batteries |
US8808914B2 (en) | 2012-01-13 | 2014-08-19 | Energy Power Systems, LLC | Lead-acid battery design having versatile form factor |
US9595360B2 (en) | 2012-01-13 | 2017-03-14 | Energy Power Systems LLC | Metallic alloys having amorphous, nano-crystalline, or microcrystalline structure |
WO2013106419A1 (en) * | 2012-01-13 | 2013-07-18 | Energy Power Systems Llc. | Improved substrate for electrode of electrochemical cell |
US9263721B2 (en) | 2012-01-13 | 2016-02-16 | Energy Power Systems LLC | Lead-acid battery design having versatile form factor |
CN104562094B (en) * | 2015-01-20 | 2016-11-16 | 昆明理工恒达科技股份有限公司 | A kind of preparation method of non-ferrous metal electrodeposition graded composite anode |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2636856A (en) * | 1948-06-29 | 1953-04-28 | Mallory & Co Inc P R | Electrode for electrochemical oxidation |
US3499795A (en) * | 1968-04-08 | 1970-03-10 | Samuel Ruben | Storage battery having electrodes comprising a supporting base of titanium nitride |
US3486940A (en) * | 1968-07-30 | 1969-12-30 | Samuel Ruben | Storage battery having a positive electrode comprising a supporting base of titanium nitride having a surface film of non-polarizing material |
US3649485A (en) * | 1968-10-02 | 1972-03-14 | Ppg Industries Inc | Electrolysis of brine using coated carbon anodes |
-
1974
- 1974-08-30 JP JP49099067A patent/JPS5072878A/ja active Pending
- 1974-08-30 SE SE7411031A patent/SE392622B/en unknown
- 1974-09-03 CA CA208,327A patent/CA1030482A/en not_active Expired
- 1974-09-03 US US502666A patent/US3880728A/en not_active Expired - Lifetime
- 1974-09-04 IT IT7452873A patent/IT1019188B/en active
- 1974-09-04 GB GB3859574A patent/GB1476487A/en not_active Expired
- 1974-09-04 FR FR7430050A patent/FR2242783B1/fr not_active Expired
- 1974-09-05 CH CH1207174A patent/CH592162A5/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
SE7411031L (en) | 1975-03-06 |
IT1019188B (en) | 1977-11-10 |
CA1030482A (en) | 1978-05-02 |
US3880728A (en) | 1975-04-29 |
FR2242783A1 (en) | 1975-03-28 |
FR2242783B1 (en) | 1981-04-17 |
JPS5072878A (en) | 1975-06-16 |
SE392622B (en) | 1977-04-04 |
CH592162A5 (en) | 1977-10-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |