GB1469818A - Process for preparation of acetylenes - Google Patents
Process for preparation of acetylenesInfo
- Publication number
- GB1469818A GB1469818A GB1703174A GB1703174A GB1469818A GB 1469818 A GB1469818 A GB 1469818A GB 1703174 A GB1703174 A GB 1703174A GB 1703174 A GB1703174 A GB 1703174A GB 1469818 A GB1469818 A GB 1469818A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- phenyl
- alkoxy
- halogen
- optionally substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
- C07D263/54—Benzoxazoles; Hydrogenated benzoxazoles
- C07D263/56—Benzoxazoles; Hydrogenated benzoxazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/06—Benzimidazoles; Hydrogenated benzimidazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
- C07D235/08—Radicals containing only hydrogen and carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/06—Benzimidazoles; Hydrogenated benzimidazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
- C07D235/16—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
- C07D263/60—Naphthoxazoles; Hydrogenated naphthoxazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
- C07D263/62—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings
- C07D263/64—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings linked in positions 2 and 2' by chains containing six-membered aromatic rings or ring systems containing such rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D271/00—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
- C07D271/02—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D271/10—1,3,4-Oxadiazoles; Hydrogenated 1,3,4-oxadiazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/64—Benzothiazoles with only hydrocarbon or substituted hydrocarbon radicals attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/79—Benzo [b] furans; Hydrogenated benzo [b] furans with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/79—Benzo [b] furans; Hydrogenated benzo [b] furans with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
- C07D307/80—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/40—Ortho- or ortho- and peri-condensed systems containing four condensed rings
- C07C2603/42—Ortho- or ortho- and peri-condensed systems containing four condensed rings containing only six-membered rings
- C07C2603/50—Pyrenes; Hydrogenated pyrenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
1469818 Acetylene derivatives HOECHST AG 18 April 1974 [21 April 1973] 17031/74 Heading C2C The invention comprises compounds of the formula where X is a group of the formula in which R<SP>4</SP> is C 1 to C 4 alkyl or phenyl; n is zero or 1 and, if n is zero, A is naphthyl, anthryl, phenanthryl, pyrenyl, in which Y is -CH=, -N= or -NR<SP>7+</SP>=T<SP>-</SP> in which R<SP>7</SP> is hydrogen or C 1 to C 4 alkyl optionally substituted by hydroxy, cyano or phenyl and T is a colourless anion, Z is -O-, -S- or -NR<SP>8</SP>- in which R<SP>8</SP> has the same meanings as R<SP>7</SP>, R<SP>5</SP> and R<SP>6</SP> are each hydrogen, halogen, C 1 to C 4 alkyl, C 1 to C 4 alkoxy or phenyl or together R<SP>5</SP> and R<SP>6</SP> form a fused benzene ring; B has the same meanings as A or is phenyl; and if n is 1, A can also be phenyl, cyano, -COOR<SP>1</SP> (in which R<SP>1</SP> is C 1 to C 4 alkyl or phenyl optionally substituted by halogen, hydroxy, C 1 to C 4 alkoxy, amino, mono- or di- C 1 to C 4 alkylamino, or tri-C 1 to C 4 alkylammonium) or -CONR<SP>2</SP>R<SP>3</SP> (in which R<SP>2</SP> and R<SP>3</SP> are each hydrogen or C 1 to C 4 alkyl or R<SP>2</SP> and R<SP>3</SP> together with the nitrogen atom are morpholino or piperidino); and A and B are optionally substituted by halogen, C 1 to C 4 alkyl, C 1 to C 4 alkoxy, cyano, -COOR<SP>1</SP>, -CONR<SP>2</SP>,R<SP>3</SP>, -SO 2 OR<SP>1</SP>, sulpho, nitro, amino, mono- or di-C 1 to C 4 alkylamino, tri-C 1 to C 4 alkylammonium, C 1 to C 4 alkanoylamino, benzoylamino, C 1 to C 4 alkanoyloxy, benzoyloxy or benzocumarinyl. They may be prepared by reacting a vinyl sulphone of the formula wherein R is C 1 to C 4 alkyl or phenyl optionally substituted by halogen, nitro, C 1 to C 4 alkoxy or C 1 to C 4 alkanoylamino, with a stoichiometric amount of a strong base in a polar solvent at from - 30‹ to + 150‹ C. The compounds of Formula I are optical brightening agents.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2320528A DE2320528A1 (en) | 1973-04-21 | 1973-04-21 | PROCESS FOR THE PRODUCTION OF ACETYLENES |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1469818A true GB1469818A (en) | 1977-04-06 |
Family
ID=5878971
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1703174A Expired GB1469818A (en) | 1973-04-21 | 1974-04-18 | Process for preparation of acetylenes |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5030854A (en) |
BE (1) | BE814017A (en) |
CA (1) | CA1011749A (en) |
CH (2) | CH599388B5 (en) |
DE (1) | DE2320528A1 (en) |
FR (1) | FR2228044B1 (en) |
GB (1) | GB1469818A (en) |
NL (1) | NL7405106A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2155465A (en) * | 1984-01-23 | 1985-09-25 | Dainippon Ink & Chemicals | Tolan-type nematic liquid crystalline compounds |
FR2587341A1 (en) * | 1985-07-03 | 1987-03-20 | Nippon Shinyaku Co Ltd | BENZIMIDAZOLE DERIVATIVES |
GB2189785A (en) * | 1984-01-23 | 1987-11-04 | Dainippon Ink & Chemicals | Tolan-type nematic liquid crystalline compounds |
GB2190082A (en) * | 1984-12-11 | 1987-11-11 | Dainippon Ink & Chemicals | Tolan-type nematic liquid crystalline compounds |
EP1138328A1 (en) * | 2000-03-29 | 2001-10-04 | Eli Lilly And Company Limited | Naphthalene derivatives as CNS drugs |
WO2007091056A2 (en) * | 2006-02-07 | 2007-08-16 | The University Of York | Bicyclic compounds and their use |
WO2010141758A1 (en) * | 2009-06-04 | 2010-12-09 | Nitto Denko Corporation | Emissive aryl-heteroaryl acetylenes |
US8354668B2 (en) | 2009-06-29 | 2013-01-15 | Nitto Denko Corporation | Emissive triaryls |
US8420235B2 (en) | 2009-06-04 | 2013-04-16 | Nitto Denko Corporation | Emissive diaryl acetylenes |
US8927121B2 (en) | 2009-06-29 | 2015-01-06 | Nitto Denko Corporation | Emissive aryl-heteroaryl compounds |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1961052B1 (en) | 2005-12-12 | 2013-03-06 | Basf Se | Organic semiconductors and their manufacture |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1547502A (en) * | 1966-08-15 | 1968-11-29 | Ciba Geigy | New tolane derivatives, their use and process for their preparation |
-
1973
- 1973-04-21 DE DE2320528A patent/DE2320528A1/en active Pending
-
1974
- 1974-04-16 NL NL7405106A patent/NL7405106A/xx not_active Application Discontinuation
- 1974-04-17 CH CH529474A patent/CH599388B5/xx not_active IP Right Cessation
- 1974-04-17 CH CH529474D patent/CH529474A4/xx unknown
- 1974-04-18 GB GB1703174A patent/GB1469818A/en not_active Expired
- 1974-04-19 JP JP49043516A patent/JPS5030854A/ja active Pending
- 1974-04-19 CA CA197,843A patent/CA1011749A/en not_active Expired
- 1974-04-22 BE BE143464A patent/BE814017A/en unknown
- 1974-04-22 FR FR7413909A patent/FR2228044B1/fr not_active Expired
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2155465A (en) * | 1984-01-23 | 1985-09-25 | Dainippon Ink & Chemicals | Tolan-type nematic liquid crystalline compounds |
GB2189785A (en) * | 1984-01-23 | 1987-11-04 | Dainippon Ink & Chemicals | Tolan-type nematic liquid crystalline compounds |
GB2190082A (en) * | 1984-12-11 | 1987-11-11 | Dainippon Ink & Chemicals | Tolan-type nematic liquid crystalline compounds |
FR2587341A1 (en) * | 1985-07-03 | 1987-03-20 | Nippon Shinyaku Co Ltd | BENZIMIDAZOLE DERIVATIVES |
EP1138328A1 (en) * | 2000-03-29 | 2001-10-04 | Eli Lilly And Company Limited | Naphthalene derivatives as CNS drugs |
WO2007091056A2 (en) * | 2006-02-07 | 2007-08-16 | The University Of York | Bicyclic compounds and their use |
WO2007091056A3 (en) * | 2006-02-07 | 2008-01-03 | Univ York | Bicyclic compounds and their use |
WO2010141758A1 (en) * | 2009-06-04 | 2010-12-09 | Nitto Denko Corporation | Emissive aryl-heteroaryl acetylenes |
US8323805B2 (en) | 2009-06-04 | 2012-12-04 | Nitto Denko Corporation | Emissive aryl-heteroaryl acetylenes |
US8420235B2 (en) | 2009-06-04 | 2013-04-16 | Nitto Denko Corporation | Emissive diaryl acetylenes |
US8354668B2 (en) | 2009-06-29 | 2013-01-15 | Nitto Denko Corporation | Emissive triaryls |
US8927121B2 (en) | 2009-06-29 | 2015-01-06 | Nitto Denko Corporation | Emissive aryl-heteroaryl compounds |
Also Published As
Publication number | Publication date |
---|---|
NL7405106A (en) | 1974-10-23 |
JPS5030854A (en) | 1975-03-27 |
CH599388B5 (en) | 1978-05-31 |
DE2320528A1 (en) | 1974-11-07 |
CA1011749A (en) | 1977-06-07 |
FR2228044B1 (en) | 1977-10-21 |
BE814017A (en) | 1974-10-22 |
FR2228044A1 (en) | 1974-11-29 |
CH529474A4 (en) | 1977-07-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |