GB1469003A - Preparation of substituted phosphorus halides - Google Patents
Preparation of substituted phosphorus halidesInfo
- Publication number
- GB1469003A GB1469003A GB5091974A GB5091974A GB1469003A GB 1469003 A GB1469003 A GB 1469003A GB 5091974 A GB5091974 A GB 5091974A GB 5091974 A GB5091974 A GB 5091974A GB 1469003 A GB1469003 A GB 1469003A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pcl
- halophosphines
- hydrocarbyl
- nov
- halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- -1 phosphorus halides Chemical class 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- LHHMNJZNWUJFOC-UHFFFAOYSA-N 1-chloro-2-[2-chloroethoxy(ethenyl)phosphoryl]oxyethane Chemical compound ClCCOP(=O)(C=C)OCCCl LHHMNJZNWUJFOC-UHFFFAOYSA-N 0.000 abstract 1
- 125000005810 2,5-xylyl group Chemical group [H]C1=C([H])C(=C(*)C([H])=C1C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- ZMQFCCAWWXHOFA-UHFFFAOYSA-N dichloro(ethenyl)phosphane Chemical compound ClP(Cl)C=C ZMQFCCAWWXHOFA-UHFFFAOYSA-N 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 abstract 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 abstract 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/52—Halophosphines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1469003 Hydrocarbyl halophosphines MOBIL OIL CORP 25 Nov 1974 [28 Nov 1973] 50919/74 Heading C2P Hydrocarbyl halophosphines are prepared by contacting a P<SP>III</SP> halide with ethylene or an aromatic hydrocarbon at 147-475‹ C. in the presence of a crystalline aluminosilicate zeolite in the hydrogen form having a silica/alumina mole ratio of at least 12 and a " constraint index " (defined) of 1-12. The P<SP>III</SP> halide may be PCl 3 or PhPCl 2 . Specified products are CH 2 =CH-PCl 2 , Ph 2 PCl and ArPCl 2 where Ar is phenyl, o-, m- or p-tolyl, α- or #-naphthyl or 2,5-xylyl. Bis-(2-chloroethyl) vinylphosphonate is prepared from vinylphosphorus dichloride by the successive actions of ethylene oxide and N 2 O 4 /CH 2 Cl 2 .
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41984273A | 1973-11-28 | 1973-11-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1469003A true GB1469003A (en) | 1977-03-30 |
Family
ID=23663989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5091974A Expired GB1469003A (en) | 1973-11-28 | 1974-11-25 | Preparation of substituted phosphorus halides |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE822737A (en) |
| CA (1) | CA1027139A (en) |
| DE (1) | DE2456095A1 (en) |
| FR (1) | FR2252349B1 (en) |
| GB (1) | GB1469003A (en) |
| IT (1) | IT1026558B (en) |
| NL (1) | NL7415498A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0024128A2 (en) * | 1979-08-14 | 1981-02-25 | Imperial Chemical Industries Plc | Phosphorylation process |
-
1974
- 1974-10-31 CA CA212,733A patent/CA1027139A/en not_active Expired
- 1974-11-12 FR FR7437246A patent/FR2252349B1/fr not_active Expired
- 1974-11-25 GB GB5091974A patent/GB1469003A/en not_active Expired
- 1974-11-27 NL NL7415498A patent/NL7415498A/en not_active Application Discontinuation
- 1974-11-27 IT IT2988074A patent/IT1026558B/en active
- 1974-11-27 DE DE19742456095 patent/DE2456095A1/en active Pending
- 1974-11-28 BE BE150979A patent/BE822737A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0024128A2 (en) * | 1979-08-14 | 1981-02-25 | Imperial Chemical Industries Plc | Phosphorylation process |
| EP0024128A3 (en) * | 1979-08-14 | 1982-02-10 | Imperial Chemical Industries Plc | Phosphorylation process and use of the so prepared compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1027139A (en) | 1978-02-28 |
| BE822737A (en) | 1975-05-28 |
| IT1026558B (en) | 1978-10-20 |
| FR2252349A1 (en) | 1975-06-20 |
| DE2456095A1 (en) | 1975-07-10 |
| FR2252349B1 (en) | 1979-02-23 |
| NL7415498A (en) | 1975-05-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |