GB1461846A - Process for producing highly chlorinated hydrocarbons - Google Patents
Process for producing highly chlorinated hydrocarbonsInfo
- Publication number
- GB1461846A GB1461846A GB1294874A GB1294874A GB1461846A GB 1461846 A GB1461846 A GB 1461846A GB 1294874 A GB1294874 A GB 1294874A GB 1294874 A GB1294874 A GB 1294874A GB 1461846 A GB1461846 A GB 1461846A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- hydrocarbons
- highly chlorinated
- chlorinated hydrocarbons
- mole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 title abstract 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract 2
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 2
- 150000002910 rare earth metals Chemical class 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- KJDRSWPQXHESDQ-UHFFFAOYSA-N 1,4-dichlorobutane Chemical compound ClCCCCCl KJDRSWPQXHESDQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052779 Neodymium Inorganic materials 0.000 abstract 1
- 229910052777 Praseodymium Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000001273 butane Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 abstract 1
- 229910052746 lanthanum Inorganic materials 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- -1 monochloroethylene, dichloroethylene Chemical group 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/10—Chlorides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/27—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a liquid or molten state
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1461846 Production of highly chlorinated hydrocarbons SUMITOMO CHEMICAL CO Ltd 22 March 1974 [22 March 1973] 12948/74 Heading C2C [Also in Division B1] Highly chlorinated hydrocarbons having at least one C atom per molecule to which at least two Cl atoms are bonded are produced by contacting saturated aliphatic hydrocarbons, partially chlorinated, saturated or unsaturated aliphatic hydrocarbons, or a mixture thereof, with oxygen and HCl and/or Cl 2 in the presence of an unsupported molten salt catalyst maintained at 250-650 C. and comprising (a) more than 95 mole per cent, but not more than 99À5 mole per cent, of a copper chloride optionally mixed with at least one alkali metal or alkaline earth metal chloride and (b) less than 5 mole per cent, but not less than 0À5 mole per cent, of at least one chloride of Pd and rare earth metals, the reaction conditions being chosen to achieve a conversion of #92 mol. per cent of the starting hydrocarbons to a product containing a major proportion of highly chlorinated hydrocarbons. The alkali metal chloride may be Li, Na or K and the alkaline earth metal chloride may be MgCl 2 . Suitable rare earth metals are La, Ce, Pr and Nd. The chlorine source is preferably contacted as 0À1-20 moles per mole of hydrocarbon feed material. The hydrocarbon feed may be methane, ethane, propane, butane, monochloromethane, dichloromethane, monochloroethane, 1,2 - dichloroethane, 1,1,2 - trichloroethane, 1,4-dichlorobutane, monochloroethylene, dichloroethylene.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3326373A JPS5312485B2 (en) | 1973-03-22 | 1973-03-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1461846A true GB1461846A (en) | 1977-01-19 |
Family
ID=12381620
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1294874A Expired GB1461846A (en) | 1973-03-22 | 1974-03-22 | Process for producing highly chlorinated hydrocarbons |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5312485B2 (en) |
| DE (1) | DE2413148C3 (en) |
| FR (1) | FR2222339B1 (en) |
| GB (1) | GB1461846A (en) |
| IT (1) | IT1003838B (en) |
| NL (1) | NL7403821A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084643C (en) * | 1994-11-14 | 2002-05-15 | 三井化学株式会社 | Catalysts for preparing chlorine from mydrogen chloride |
| WO2003066214A2 (en) * | 2002-02-05 | 2003-08-14 | Basf Aktiengesellschaft | Catalyst composition for oxychlorination |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS539723A (en) * | 1976-07-13 | 1978-01-28 | Ihara Chem Ind Co Ltd | Chlorination of aromtic hydrocarbons |
| JPH03128615U (en) * | 1990-03-31 | 1991-12-25 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3267161A (en) * | 1962-07-26 | 1966-08-16 | Osaka Kinzoku Kogyo Company Lt | Chlorination process |
| GB1054750A (en) * | 1963-03-26 | |||
| US3527819A (en) * | 1967-04-03 | 1970-09-08 | Fmc Corp | Oxychlorination process for preparing trichloroethylene and tetrachloroethylene |
| GB1213402A (en) * | 1968-02-19 | 1970-11-25 | British Petroleum Co | Preparation of chlorinated derivatives of ethylene |
-
1973
- 1973-03-22 JP JP3326373A patent/JPS5312485B2/ja not_active Expired
-
1974
- 1974-03-19 DE DE2413148A patent/DE2413148C3/en not_active Expired
- 1974-03-21 NL NL7403821A patent/NL7403821A/xx not_active Application Discontinuation
- 1974-03-22 IT IT49529/74A patent/IT1003838B/en active
- 1974-03-22 GB GB1294874A patent/GB1461846A/en not_active Expired
- 1974-03-22 FR FR7409964A patent/FR2222339B1/fr not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084643C (en) * | 1994-11-14 | 2002-05-15 | 三井化学株式会社 | Catalysts for preparing chlorine from mydrogen chloride |
| WO2003066214A2 (en) * | 2002-02-05 | 2003-08-14 | Basf Aktiengesellschaft | Catalyst composition for oxychlorination |
| WO2003066214A3 (en) * | 2002-02-05 | 2004-02-05 | Basf Ag | Catalyst composition for oxychlorination |
| US7126035B2 (en) | 2002-02-05 | 2006-10-24 | Basf Aktiengesellschaft | Catalyst composition for oxychlorination |
| US7902411B2 (en) | 2002-02-05 | 2011-03-08 | Basf Catalysts Llc | Catalyst composition for oxychlorination |
| EP2314374A1 (en) * | 2002-02-05 | 2011-04-27 | BASF Corporation | Catalytic converter for oxychlorination |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2413148B2 (en) | 1977-10-06 |
| IT1003838B (en) | 1976-06-10 |
| FR2222339B1 (en) | 1977-09-23 |
| DE2413148C3 (en) | 1978-05-24 |
| JPS49117406A (en) | 1974-11-09 |
| NL7403821A (en) | 1974-09-24 |
| DE2413148A1 (en) | 1974-10-03 |
| FR2222339A1 (en) | 1974-10-18 |
| JPS5312485B2 (en) | 1978-05-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |