GB1360570A - Vinyl chloride process - Google Patents
Vinyl chloride processInfo
- Publication number
- GB1360570A GB1360570A GB3029072A GB3029072A GB1360570A GB 1360570 A GB1360570 A GB 1360570A GB 3029072 A GB3029072 A GB 3029072A GB 3029072 A GB3029072 A GB 3029072A GB 1360570 A GB1360570 A GB 1360570A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chloride
- vinyl chloride
- dichloroethane
- recovered
- ethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 6
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 4
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 abstract 3
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 3
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 abstract 3
- 229960003750 ethyl chloride Drugs 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 abstract 2
- 239000000155 melt Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910001510 metal chloride Inorganic materials 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 229910021607 Silver chloride Inorganic materials 0.000 abstract 1
- -1 ZnCl 2 Chemical class 0.000 abstract 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 150000001805 chlorine compounds Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Inorganic materials [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 abstract 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 abstract 1
- GBECUEIQVRDUKB-UHFFFAOYSA-M thallium monochloride Chemical compound [Tl]Cl GBECUEIQVRDUKB-UHFFFAOYSA-M 0.000 abstract 1
Classifications
-
- B01J35/27—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/10—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/154—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of saturated hydrocarbons
Abstract
1360570 Vinyl chloride; 1,2-dichloroethane LUMMUS CO 28 June 1972 [28 June 1971] 30290/72 Addition to 1213202 Heading C2C Vinyl chloride is produced by (a) contacting, in the vapour phase, ethane and chlorine and/or hydrogen chloride as fresh feed, and unconverted ethane, ethyl chloride, and ethylene as recycle components, with a molten mixture comprising a multivalent metal chloride in both its higher and lower valence states and the oxychloride of the metal, to produce a reaction effluent comprising vinyl chloride, dichloroethane and the said recycle components; (b) recovering from the reaction effluent the vinyl chloride, dichloroethane and recycle components; and (c) passing the recovered recycle components to step (a), the ethyl chloride being recycled in an amount to provide an ethyl chloride to fresh feed ethane weight ratio of from 0À3 : 1 to 14 : 1 and an ethylene to feed ethane weight ratio of from 0À03 : 1 to 1À2 : 1. The dichloroethane is either recovered as co-reaction product, or is recovered and dehydrochlorinated to vinyl chloride in a variety of ways, the hydrogen chloride released being recycled to the chlorination step (a). The multivalent metal is preferably copper. The melt may contain other metal chlorides which are non-volatile and oxygen-resistant so as to lower the melting point of alkali metal chlorides such as KCl and LiCl and heavy metal chlorides such as ZnCl 2 , AgCl and thallium chloride. The melt recovered from step (a) is contacted with molecular oxygen to produce the oxychloride, and the regenerated oxychloride containing melt is recycled to step (a).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US157496A US3879482A (en) | 1969-06-09 | 1971-06-28 | Vinyl chloride process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1360570A true GB1360570A (en) | 1974-07-17 |
Family
ID=22563987
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3029072A Expired GB1360570A (en) | 1971-06-28 | 1972-06-28 | Vinyl chloride process |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5735166B1 (en) |
| DE (1) | DE2230259A1 (en) |
| FR (1) | FR2143850B2 (en) |
| GB (1) | GB1360570A (en) |
| IT (1) | IT1001497B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1109853A (en) * | 1977-10-19 | 1981-09-29 | Michael F. Lemanski | Catalyst and process for production of vcm |
| DE2853008C2 (en) * | 1978-12-07 | 1982-10-28 | geb. Kovačevič Alla Nikolaevna Mel'nik | Process for the production of vinyl chloride |
| NZ200032A (en) * | 1981-03-19 | 1985-07-12 | Ici Plc | Production of chlorinated hydrocarbons from alkanes |
| AU8168782A (en) * | 1981-03-19 | 1982-09-23 | Imperial Chemical Industries Plc | Production of monochlorinated compounds |
| TW201617304A (en) * | 2014-11-11 | 2016-05-16 | 藍色方塊智財有限責任公司 | Process for the production of ethylene, hydrogen chloride, and vinyl chloride from ethane |
| WO2016076960A1 (en) * | 2014-11-11 | 2016-05-19 | Blue Cube Ip Llc | Process for the production of heavies and hydrogen chloride from ethane |
| TW201617302A (en) * | 2014-11-11 | 2016-05-16 | 藍色方塊智財有限責任公司 | Process for the production of vinyl chloride, heavies, and hydrogen chloride from ethane |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3557229A (en) * | 1967-08-23 | 1971-01-19 | Lummus Co | Oxychlorination of ethane to vinyl chloride |
| JPS5125002A (en) * | 1974-08-26 | 1976-03-01 | Hitachi Ltd | ONSEIOTOSHISUTEMU |
-
1972
- 1972-06-21 DE DE2230259A patent/DE2230259A1/en active Pending
- 1972-06-27 IT IT26285/72A patent/IT1001497B/en active
- 1972-06-28 FR FR7223436A patent/FR2143850B2/fr not_active Expired
- 1972-06-28 GB GB3029072A patent/GB1360570A/en not_active Expired
- 1972-06-28 JP JP6416472A patent/JPS5735166B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2143850A2 (en) | 1973-02-09 |
| DE2230259A1 (en) | 1973-01-11 |
| IT1001497B (en) | 1976-04-20 |
| JPS5735166B1 (en) | 1982-07-27 |
| FR2143850B2 (en) | 1977-08-26 |
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| GB1437151A (en) | ||
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |