GB1459622A - Process for the production of allyl-esters - Google Patents
Process for the production of allyl-estersInfo
- Publication number
- GB1459622A GB1459622A GB2072874A GB2072874A GB1459622A GB 1459622 A GB1459622 A GB 1459622A GB 2072874 A GB2072874 A GB 2072874A GB 2072874 A GB2072874 A GB 2072874A GB 1459622 A GB1459622 A GB 1459622A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chloro
- allyl
- sulphoxide
- cocatalyst
- amide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1459622 Allyl esters BASF AG 10 May 1974 [12 May 1973] 20728/74 Heading C2C Allyl esters of formula wherein R is an aliphatic radical, R<SP>1</SP>, R<SP>2</SP>, and R<SP>3</SP> are independently hydrogen or an alkyl (1-3C) and R<SP>4</SP> is a hydrocarbon radical (1-20C), optionally substituted by one or more inert substituents, are prepared by reacting an allyl chloride with an anhydrous salt of an aliphatic carboxylic acid R.COOH, in the presence of a basic nitrogen compound or a salt thereof as a catalyst and a polar aprotic compound with dipole moment at least 3À1 Debye, dielectric constant more than 15, and a MP<60‹ C. and/or an ionic iodide as cocatalyst. The cocatalyst may be an amide, sulphoxide, sulphone, nitrile, nitro compound or carbonate, especially dimethyl formamide or sulphoxide, and the ionic amide may be an alkali metal, ammonium or tetraalkyl ammonium iodide. The ester may be hydrolysed to the alcohol. Examples describe the reaction of 1- chloro - 3,7 - dimethyl - 2,6-, and 2,7 - octadiene, 1 - chloro - 3 - methyl - 2 - butene, 1 - chloro- 3,7,11 - trimethyldodeca - 2,6,10 - triene, and 1 - chloro - 3,7,11,15 - tetramethyl - hexadecene- (2) with anhydrous sodium acetate and 1- chloro - 3,7 - dimethylocta - 2,6 - diene with sodium formate using various catalysts and cocatalysts.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19732324047 DE2324047C3 (en) | 1973-05-12 | Process for the preparation of aliphatic terpene allyl esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1459622A true GB1459622A (en) | 1976-12-22 |
Family
ID=5880745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2072874A Expired GB1459622A (en) | 1973-05-12 | 1974-05-10 | Process for the production of allyl-esters |
Country Status (3)
| Country | Link |
|---|---|
| CH (1) | CH592039A5 (en) |
| FR (1) | FR2228763B1 (en) |
| GB (1) | GB1459622A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102199112A (en) * | 2011-04-01 | 2011-09-28 | 北京工商大学 | Preparation method for sodium allyl sulfosuccinic alkyl ester |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4152530A (en) * | 1978-07-24 | 1979-05-01 | Rhone-Poulenc Inc. | Process for preparing allylic alcohols from allylic halides |
-
1974
- 1974-05-08 CH CH628074A patent/CH592039A5/xx not_active IP Right Cessation
- 1974-05-09 FR FR7416029A patent/FR2228763B1/fr not_active Expired
- 1974-05-10 GB GB2072874A patent/GB1459622A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102199112A (en) * | 2011-04-01 | 2011-09-28 | 北京工商大学 | Preparation method for sodium allyl sulfosuccinic alkyl ester |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2228763A1 (en) | 1974-12-06 |
| DE2324047B2 (en) | 1976-01-15 |
| DE2324047A1 (en) | 1974-11-28 |
| CH592039A5 (en) | 1977-10-14 |
| FR2228763B1 (en) | 1979-05-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19930510 |