GB1459622A - Process for the production of allyl-esters - Google Patents

Process for the production of allyl-esters

Info

Publication number
GB1459622A
GB1459622A GB2072874A GB2072874A GB1459622A GB 1459622 A GB1459622 A GB 1459622A GB 2072874 A GB2072874 A GB 2072874A GB 2072874 A GB2072874 A GB 2072874A GB 1459622 A GB1459622 A GB 1459622A
Authority
GB
United Kingdom
Prior art keywords
chloro
allyl
sulphoxide
cocatalyst
amide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2072874A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19732324047 external-priority patent/DE2324047C3/en
Application filed by BASF SE filed Critical BASF SE
Publication of GB1459622A publication Critical patent/GB1459622A/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1459622 Allyl esters BASF AG 10 May 1974 [12 May 1973] 20728/74 Heading C2C Allyl esters of formula wherein R is an aliphatic radical, R<SP>1</SP>, R<SP>2</SP>, and R<SP>3</SP> are independently hydrogen or an alkyl (1-3C) and R<SP>4</SP> is a hydrocarbon radical (1-20C), optionally substituted by one or more inert substituents, are prepared by reacting an allyl chloride with an anhydrous salt of an aliphatic carboxylic acid R.COOH, in the presence of a basic nitrogen compound or a salt thereof as a catalyst and a polar aprotic compound with dipole moment at least 3À1 Debye, dielectric constant more than 15, and a MP<60‹ C. and/or an ionic iodide as cocatalyst. The cocatalyst may be an amide, sulphoxide, sulphone, nitrile, nitro compound or carbonate, especially dimethyl formamide or sulphoxide, and the ionic amide may be an alkali metal, ammonium or tetraalkyl ammonium iodide. The ester may be hydrolysed to the alcohol. Examples describe the reaction of 1- chloro - 3,7 - dimethyl - 2,6-, and 2,7 - octadiene, 1 - chloro - 3 - methyl - 2 - butene, 1 - chloro- 3,7,11 - trimethyldodeca - 2,6,10 - triene, and 1 - chloro - 3,7,11,15 - tetramethyl - hexadecene- (2) with anhydrous sodium acetate and 1- chloro - 3,7 - dimethylocta - 2,6 - diene with sodium formate using various catalysts and cocatalysts.
GB2072874A 1973-05-12 1974-05-10 Process for the production of allyl-esters Expired GB1459622A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19732324047 DE2324047C3 (en) 1973-05-12 Process for the preparation of aliphatic terpene allyl esters

Publications (1)

Publication Number Publication Date
GB1459622A true GB1459622A (en) 1976-12-22

Family

ID=5880745

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2072874A Expired GB1459622A (en) 1973-05-12 1974-05-10 Process for the production of allyl-esters

Country Status (3)

Country Link
CH (1) CH592039A5 (en)
FR (1) FR2228763B1 (en)
GB (1) GB1459622A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199112A (en) * 2011-04-01 2011-09-28 北京工商大学 Preparation method for sodium allyl sulfosuccinic alkyl ester

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4152530A (en) * 1978-07-24 1979-05-01 Rhone-Poulenc Inc. Process for preparing allylic alcohols from allylic halides

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199112A (en) * 2011-04-01 2011-09-28 北京工商大学 Preparation method for sodium allyl sulfosuccinic alkyl ester

Also Published As

Publication number Publication date
CH592039A5 (en) 1977-10-14
DE2324047A1 (en) 1974-11-28
DE2324047B2 (en) 1976-01-15
FR2228763A1 (en) 1974-12-06
FR2228763B1 (en) 1979-05-11

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19930510