GB1449528A - Chelating polymers - Google Patents

Chelating polymers

Info

Publication number
GB1449528A
GB1449528A GB4318574A GB4318574A GB1449528A GB 1449528 A GB1449528 A GB 1449528A GB 4318574 A GB4318574 A GB 4318574A GB 4318574 A GB4318574 A GB 4318574A GB 1449528 A GB1449528 A GB 1449528A
Authority
GB
United Kingdom
Prior art keywords
imine
oct
poly
waste water
hydrogen atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4318574A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carapus Co Ltd
Original Assignee
Carapus Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP11150773A external-priority patent/JPS53950B2/ja
Priority claimed from JP48111508A external-priority patent/JPS5247755B2/ja
Priority claimed from JP3248574A external-priority patent/JPS5320079B2/ja
Application filed by Carapus Co Ltd filed Critical Carapus Co Ltd
Publication of GB1449528A publication Critical patent/GB1449528A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/52Amino carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Epoxy Resins (AREA)

Abstract

1449528 Purification of waste water by ion exchange CARAPUS CO Ltd 4 Oct 1974 [5 Oct 1973 (2) 25 March 1974] 43185/74 Heading C1C [Also in Division C3] Detrimental heavy metals, (e.g. Hg, Cd, Zn, Cu, Pb) are removed from industrial waste water (e.g. in electrolytic processes, dyeing, pigment and polymer industries) by contact with a chelating polymer prepared by saponifying with acid or alkali a reaction product of a bisepoxide with a poly-N-substituted polyamine or poly-N-substituted polyalkylene imine, the amine or imine having been prepared by substituting an alkali metal salt or an alkyl ester of a carboxyalkyl group or cyanoalkyl group for active hydrogen atoms of the polyamine or imine to an extent that at least 2 active hydrogen atoms remain. In a typical example (1) the methyl ester of ethylenediamine di(methylpropionic acid) is reacted with the diglycidyl ether of bisphenol A and the product saponified with NaOH. Examples relate to the removal by ion-exchange of metal values from aqueous solutions of CuSO 4 , CdSO 4 , Pb(NO 3 ) 2 and HgCl 2 .
GB4318574A 1973-10-05 1974-10-04 Chelating polymers Expired GB1449528A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP11150773A JPS53950B2 (en) 1973-10-05 1973-10-05
JP48111508A JPS5247755B2 (en) 1973-10-05 1973-10-05
JP3248574A JPS5320079B2 (en) 1974-03-25 1974-03-25

Publications (1)

Publication Number Publication Date
GB1449528A true GB1449528A (en) 1976-09-15

Family

ID=27287723

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4318574A Expired GB1449528A (en) 1973-10-05 1974-10-04 Chelating polymers

Country Status (2)

Country Link
DE (1) DE2447305C3 (en)
GB (1) GB1449528A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018948A2 (en) * 1979-05-08 1980-11-12 Ciba-Geigy Ag N-substituted derivatives of aspartic acid, process for their preparation, their use and epoxy resins produced with their aid
US9796604B2 (en) 2014-07-17 2017-10-24 King Fahd University Of Petroleum And Minerals Cross-linked (bisphenol-S, formaldehyde, 1,6-hexadiamine) terpolymer for the adsorption of Pb2+ ions from aqueous solutions
CN116535669A (en) * 2023-05-10 2023-08-04 北京盈合微纳科技有限公司 Degradable heavy metal chelating agent and preparation method thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4186086A (en) * 1978-06-26 1980-01-29 The Dow Chemical Company Weak base ion exchange resins of a polyalkylenepolyamine and polyepoxide
US5965695A (en) * 1990-05-15 1999-10-12 Chiron Corporation Modified peptide and peptide libraries with protease resistance, derivatives thereof and methods of producing and screening such
US5877278A (en) * 1992-09-24 1999-03-02 Chiron Corporation Synthesis of N-substituted oligomers
HUT72614A (en) * 1992-09-24 1996-05-28 Chiron Corp Synthesis of n-substituted oligomers
US5958792A (en) * 1995-06-07 1999-09-28 Chiron Corporation Combinatorial libraries of substrate-bound cyclic organic compounds

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0018948A2 (en) * 1979-05-08 1980-11-12 Ciba-Geigy Ag N-substituted derivatives of aspartic acid, process for their preparation, their use and epoxy resins produced with their aid
EP0018948A3 (en) * 1979-05-08 1981-06-03 Ciba-Geigy Ag N-substituted derivatives of aspartic acid, process for their preparation, their use and epoxy resins produced with their aid
US9796604B2 (en) 2014-07-17 2017-10-24 King Fahd University Of Petroleum And Minerals Cross-linked (bisphenol-S, formaldehyde, 1,6-hexadiamine) terpolymer for the adsorption of Pb2+ ions from aqueous solutions
US9878923B1 (en) 2014-07-17 2018-01-30 King Fahd University Of Petroleum And Minerals Adsorbent comprising bisphenol, formaldehyde and hexadiamine terpolymer with adsorbed Pb
CN116535669A (en) * 2023-05-10 2023-08-04 北京盈合微纳科技有限公司 Degradable heavy metal chelating agent and preparation method thereof
CN116535669B (en) * 2023-05-10 2023-12-08 北京盈合微纳科技有限公司 Degradable heavy metal chelating agent and preparation method thereof

Also Published As

Publication number Publication date
DE2447305A1 (en) 1975-04-24
DE2447305B2 (en) 1979-01-11
DE2447305C3 (en) 1979-09-13

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19941003