GB1448586A - 3-substituted-2,2,dimethyl cyclopropane carboxylic acid esters and their use as insecticides - Google Patents

3-substituted-2,2,dimethyl cyclopropane carboxylic acid esters and their use as insecticides

Info

Publication number
GB1448586A
GB1448586A GB2719473A GB2719473A GB1448586A GB 1448586 A GB1448586 A GB 1448586A GB 2719473 A GB2719473 A GB 2719473A GB 2719473 A GB2719473 A GB 2719473A GB 1448586 A GB1448586 A GB 1448586A
Authority
GB
United Kingdom
Prior art keywords
formula
carboxylic acid
cyclopropane carboxylic
substituted
insecticides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2719473A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Research Development Corp UK
Original Assignee
National Research Development Corp UK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Research Development Corp UK filed Critical National Research Development Corp UK
Priority to GB2719473A priority Critical patent/GB1448586A/en
Priority to JP49063486A priority patent/JPS5851922B2/en
Priority to FR7419611A priority patent/FR2232273B1/fr
Publication of GB1448586A publication Critical patent/GB1448586A/en
Priority to CN 85102916 priority patent/CN1026649C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/58—One oxygen atom, e.g. butenolide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/30—Hetero atoms other than halogen
    • C07D333/32—Oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)

Abstract

1448586 3 - Substituted - 2,2 - dimethyl cyclopropane carboxylic esters NATIONAL RESEARCH DEVELOPMENT CORP 6 June 1974 [7 June 1973] 27194/73 Heading C2C Novel compounds of the formula wherein X represents a radical of the formula -CH 2 -CH 2 - Y is -O- or -S-; Z is H, CH 3 , -CN or -C # CH; Z<SP>1</SP> and Z<SP>2</SP> are halogen or methyl, and n is 0, 1 or 2, are prepared by reacting a cyclopropane carboxylic acid or derivative thereof having the formula with an alcohol or derivative thereof having the formula wherein Q and CoP are functional groups or atoms which will react together to form an ester linkage. The carboxylic acid or an alkyl ester thereof may be prepared by reacting a phosphorane or ylide of the formula with either carbonaldehyde of the formula or an alkyl ester thereof under the conditions of the Wittig reaction; or with an ester of the formula The novel compounds possess insecticidal properties.
GB2719473A 1973-06-07 1973-06-07 3-substituted-2,2,dimethyl cyclopropane carboxylic acid esters and their use as insecticides Expired GB1448586A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB2719473A GB1448586A (en) 1973-06-07 1973-06-07 3-substituted-2,2,dimethyl cyclopropane carboxylic acid esters and their use as insecticides
JP49063486A JPS5851922B2 (en) 1973-06-07 1974-06-06 Satsuchi Yuzai Oyobi Sono Seizouhou
FR7419611A FR2232273B1 (en) 1973-06-07 1974-06-06
CN 85102916 CN1026649C (en) 1973-06-07 1985-04-18 Improvements of pesticides

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2719473A GB1448586A (en) 1973-06-07 1973-06-07 3-substituted-2,2,dimethyl cyclopropane carboxylic acid esters and their use as insecticides

Publications (1)

Publication Number Publication Date
GB1448586A true GB1448586A (en) 1976-09-08

Family

ID=10255708

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2719473A Expired GB1448586A (en) 1973-06-07 1973-06-07 3-substituted-2,2,dimethyl cyclopropane carboxylic acid esters and their use as insecticides

Country Status (3)

Country Link
JP (1) JPS5851922B2 (en)
FR (1) FR2232273B1 (en)
GB (1) GB1448586A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2428029A1 (en) * 1978-06-06 1980-01-04 Roussel Uclaf ESTERS OF CYCLOPROPANE CARBOXYLIC ACIDS SUBSTITUTED BY A-CYANE ALCOHOL, PROCESS FOR THEIR PREPARATION AND INSECTICIDE OR NEMATICIDE COMPOSITIONS CONTAINING THEM
FR2450830A1 (en) * 1978-07-24 1980-10-03 Roussel Uclaf NOVEL PROCESS FOR THE PREPARATION OF 3-SUBSTITUTED CYCLOPROPANE-1-CARBOXYLIC ACIDS
FR2499071A1 (en) * 1981-02-05 1982-08-06 Roussel Uclaf NOVEL DERIVATIVES OF CYCLOPROPANE CARBOXYLIC ACID SUBSTITUTED INTO 3 BY A VINYL CHAIN, PROCESS FOR THEIR PREPARATION AND THEIR APPLICATION AS SCENTED AGENTS
FR2512815B1 (en) * 1981-04-16 1989-04-14 Roussel Uclaf NOVEL DERIVATIVES OF CYCLOPROPANE CARBOXYLIC ACID, THEIR PREPARATION METHOD, THEIR APPLICATION TO THE CONTROL OF PESTS

Also Published As

Publication number Publication date
FR2232273B1 (en) 1980-06-27
JPS5046831A (en) 1975-04-25
FR2232273A1 (en) 1975-01-03
JPS5851922B2 (en) 1983-11-19

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee