GB1440273A - Aclated nitrogen compounds - Google Patents

Aclated nitrogen compounds

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Publication number
GB1440273A
GB1440273A GB5583573A GB5583573A GB1440273A GB 1440273 A GB1440273 A GB 1440273A GB 5583573 A GB5583573 A GB 5583573A GB 5583573 A GB5583573 A GB 5583573A GB 1440273 A GB1440273 A GB 1440273A
Authority
GB
United Kingdom
Prior art keywords
alkylene
acid
acylating
methyl
triamines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5583573A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Priority to GB5583573A priority Critical patent/GB1440273A/en
Publication of GB1440273A publication Critical patent/GB1440273A/en
Expired legal-status Critical Current

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Abstract

1440273 Polyolefin derivatives LUBRIZOL CORP 3 Dec 1973 55835/63 Headings C3P and C3R [Also in Division C5] Oil soluble dispersants having demulsifying properties comprise reaction products obtained by acylating (I) at least one polyoxyalkylene polyamine of molecular weight at least 200 of formula H 2 N - alkylene(O alkylene) m - NH 2 or of formula R-[alkylene(O alkylene) n NH 2 ] 3-6 where m is 3-70, n is 1-40 provided that the sum of all ns is 3-70 and R is a saturated hydrocarbon radical of up to 10 carbon atoms and valence 3 to 6 with (II) a carboxylic acid acylating agent having at least 8 carbon atoms in an aliphatic substituent derived from an olefin polymer and selected from acids, anhydrides, halides and alkyl esters, in amount of at least 0À001 equivalent of (I) per equivalent of (II). The polyolefin may be derived from ethylene, propylene, butenes, hexene-1, octene-1 2-methylheptene-1, 3-cyclohexylbutene-1, 2- methyl - 5 - propylhexene - 1, 3 - pentene or 4-octene, optionally together with minor proportions of cycloolefins, aryl-substituted olefins and polyenes. The products may be added to lubricating and fuel oil compositions. Many suitable reactants are specified and examples describe the reaction of polyisobutenyl succinic anhydride prepared from chlorinated polyisobutene and maleic anhydride with (1,2 and 4-13) polyoxypropylene diamines, (3) polyoxypropylene triamines and (14) polyoxyalkylene triamines; and the reaction of polyoxyethylene diamines with acylating agents prepared from chlorinated polyisobutene and (15) methyl methacrylate, (18 and 19) acrylic acid, (21) propyl α-chloracrylate, and (22) 3-butene-1,2,3- tricarboxylic acid, 1,2-diethyl 3-methyl ester, or with (17) polyethylene substituted malonic acid dimethyl ester or an acylating agent derived from (20) chlorinated polyethylene and ethyl acrylate; polyoxyethylene triamines with acylating agents prepared from (16) brominated polyhexene-1 and 2-pentene-1,3,5-tricarboxylic acid, and from chlorinated polyisobutene and (23) triethyl, (24) trimethyl and (25) 1,2-diethyl-3-methyl esters of 3-butene-1,2,3-tricarboxylic acid; and polyoxypropylene diamines with (27) stearic acid.
GB5583573A 1973-12-03 1973-12-03 Aclated nitrogen compounds Expired GB1440273A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2470140A1 (en) * 1979-11-27 1981-05-29 Ppg Industries Inc AMIDATION REACTION PRODUCTS OF POLYAMINES AND MATERIALS CONTAINING POLYCARBOXYL GROUPS AND COATING COMPOSITIONS COMPRISING THEM
WO1995035329A1 (en) * 1994-06-17 1995-12-28 Exxon Chemical Patents Inc. Derivatives of polyamines with one primary amine group and secondary or tertiary amines groups

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2470140A1 (en) * 1979-11-27 1981-05-29 Ppg Industries Inc AMIDATION REACTION PRODUCTS OF POLYAMINES AND MATERIALS CONTAINING POLYCARBOXYL GROUPS AND COATING COMPOSITIONS COMPRISING THEM
US5643859A (en) 1992-12-17 1997-07-01 Exxon Chemical Patents Inc. Derivatives of polyamines with one primary amine and secondary of tertiary amines
WO1995035329A1 (en) * 1994-06-17 1995-12-28 Exxon Chemical Patents Inc. Derivatives of polyamines with one primary amine group and secondary or tertiary amines groups

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