GB1435675A - Process for recovering fatty acids - Google Patents
Process for recovering fatty acidsInfo
- Publication number
- GB1435675A GB1435675A GB2320374A GB2320374A GB1435675A GB 1435675 A GB1435675 A GB 1435675A GB 2320374 A GB2320374 A GB 2320374A GB 2320374 A GB2320374 A GB 2320374A GB 1435675 A GB1435675 A GB 1435675A
- Authority
- GB
- United Kingdom
- Prior art keywords
- paraffins
- fatty acids
- methyl esters
- oxidation
- methanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
- C07C69/26—Synthetic waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1435675 Fatty acid recovery AJINOMOTO CO Inc 23 May 1974 [31 May 1973] 23203/74 Heading C2C Fatty acids are recovered as their methyl esters from the product mixture of fatty acids and unreacted paraffins obtained by catalytic oxidation of paraffins with gaseous oxygen, by reacting the mixture with methanol and fractionally distilling the higher boiling methyl esters. The oxidation may be of paraffins of 10 to 35 carbon atoms in the presence of a manganese catalyst to give a product containing 20-50% fatty acids and unsaponifiable unreacted paraffin 80-50%. The reaction with methanol may be at 70-150‹ C. in the presence of an acid or cation exchange resin, and the methyl esters recovered may be converted to free acids and the higher boiling fraction may be separated to paraffins and esters by conventional saponification. Examples describe the treatment of products cf the oxidation of n-tetradecane, n-docosane, C 14 -C 21 , and C 13 -C 16 paraffinic straight chain mixtures and the recovery of methyl esters therefrom.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6107773A JPS5549063B2 (en) | 1973-05-31 | 1973-05-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1435675A true GB1435675A (en) | 1976-05-12 |
Family
ID=13160692
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2320374A Expired GB1435675A (en) | 1973-05-31 | 1974-05-23 | Process for recovering fatty acids |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS5549063B2 (en) |
FR (1) | FR2231658B3 (en) |
GB (1) | GB1435675A (en) |
IT (1) | IT1019624B (en) |
RO (1) | RO63854A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016100180A1 (en) * | 2014-12-15 | 2016-06-23 | The Lubrizol Corporation | Catalytic oxidation of hydrocarbons |
-
1973
- 1973-05-31 JP JP6107773A patent/JPS5549063B2/ja not_active Expired
-
1974
- 1974-05-22 IT IT2311474A patent/IT1019624B/en active
- 1974-05-23 GB GB2320374A patent/GB1435675A/en not_active Expired
- 1974-05-29 RO RO7898774A patent/RO63854A/en unknown
- 1974-05-31 FR FR7419112A patent/FR2231658B3/fr not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016100180A1 (en) * | 2014-12-15 | 2016-06-23 | The Lubrizol Corporation | Catalytic oxidation of hydrocarbons |
CN107207977A (en) * | 2014-12-15 | 2017-09-26 | 路博润公司 | The catalysis oxidation of hydrocarbon |
Also Published As
Publication number | Publication date |
---|---|
FR2231658A1 (en) | 1974-12-27 |
FR2231658B3 (en) | 1977-04-08 |
RO63854A (en) | 1979-02-15 |
JPS5549063B2 (en) | 1980-12-10 |
JPS5012014A (en) | 1975-02-07 |
IT1019624B (en) | 1977-11-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |