GB1431946A - Process for separation of unsaturated hydrocarbons - Google Patents

Process for separation of unsaturated hydrocarbons

Info

Publication number
GB1431946A
GB1431946A GB2136573A GB2136573A GB1431946A GB 1431946 A GB1431946 A GB 1431946A GB 2136573 A GB2136573 A GB 2136573A GB 2136573 A GB2136573 A GB 2136573A GB 1431946 A GB1431946 A GB 1431946A
Authority
GB
United Kingdom
Prior art keywords
semi
aqueous component
unsaturated hydrocarbon
barrier
permeable membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2136573A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of GB1431946A publication Critical patent/GB1431946A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/148Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/152Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by forming adducts or complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/38Liquid-membrane separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/56Polyamides, e.g. polyester-amides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/148Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/152Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by forming adducts or complexes
    • C07C7/156Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by forming adducts or complexes with solutions of copper salts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals

Abstract

1431946 Separating hydrocarbons STANDARD OIL CO 4 May 1973 [12 May 1972 13 Sept 1972] 21365/73 Heading C5E Aliphatically unsaturated hydrocarbon having 2 to 8 carbon atoms is separated from a mixture by selectively transferring it across a barrier which comprises an aqueous component containing metal ions which combine with the unsaturated hydrocarbon to form a water soluble complex and a semi-permeable member which is solid, water-insoluble and impermeable to the aqueous component; the partial pressure of the unsaturated hydrocarbon on the second side of the barrier being maintained lower than that on the first side so that the unsaturated hydrocarbon is released on the second side of the barrier. The metal ions can be silver, zinc or cuprous ammonium and the aqueous component can comprise silver nitrate, optionally together with UO 2 (NO 3 ) 2 or a nitrate of Cr, Ni, Zn, Cd, Al, Li, Sr, Ca, Mg, Co, Fe<SP>3+</SP>, Na, Pb, NH 4 or K. The semi-permeable membrane can comprise polyurethane, nylon, sodium cellulose xanthate or an ethylene glycol monomethacrylate polymer. The process can be used to separate acetylene and/or ethylene from mixtures which also comprise methane and/or ethane. Many examples are given in which the aqueous component is in the form of a liquid covering the first side of the semi-permeable membrane which is either in the form of a flat sheet or a hollow tube immersed in the liquid; alternatively the aqueous component can be held within the semi-permeable membrane, e.g. by being absorbed therein or absorbed on a material such as cellulose acetate which is held between two semi-permeable sheets.
GB2136573A 1972-05-12 1973-05-04 Process for separation of unsaturated hydrocarbons Expired GB1431946A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US25260772A 1972-05-12 1972-05-12
US28878172A 1972-09-13 1972-09-13

Publications (1)

Publication Number Publication Date
GB1431946A true GB1431946A (en) 1976-04-14

Family

ID=26942482

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2136573A Expired GB1431946A (en) 1972-05-12 1973-05-04 Process for separation of unsaturated hydrocarbons

Country Status (9)

Country Link
JP (1) JPS5331842B2 (en)
AU (1) AU476688B2 (en)
CA (1) CA1000307A (en)
DE (1) DE2323657C3 (en)
FR (1) FR2184809B1 (en)
GB (1) GB1431946A (en)
IT (1) IT985014B (en)
NL (1) NL158088B (en)
SU (1) SU1088659A3 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012167362A1 (en) 2011-06-07 2012-12-13 Imtex Membranes Corp. Replenising liquid material to membrane
CN112592251A (en) * 2020-12-23 2021-04-02 上海睿碳能源科技有限公司 Process and apparatus for separating a light hydrocarbon-containing stream

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4272364A (en) * 1980-03-24 1981-06-09 Calgon Corporation Frother for coal flotation
JPS5924732A (en) * 1982-08-02 1984-02-08 Mitsubishi Rayon Co Ltd Hydrophilic porous membrane and its production
EP2819770B8 (en) * 2012-03-02 2018-06-06 Saudi Arabian Oil Company Facilitated transport membrane for the separation of aromatics from non-aromatics
US10471381B2 (en) * 2016-06-09 2019-11-12 Uop Llc High selectivity facilitated transport membranes and their use for olefin/paraffin separations
CN114432910B (en) * 2022-01-29 2023-04-14 中国科学院过程工程研究所 Separation membrane and preparation method and application thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012167362A1 (en) 2011-06-07 2012-12-13 Imtex Membranes Corp. Replenising liquid material to membrane
EP2717996A1 (en) * 2011-06-07 2014-04-16 Imtex Membranes Corp. Replenising liquid material to membrane
EP2717996A4 (en) * 2011-06-07 2014-11-05 Imtex Membranes Corp Replenising liquid material to membrane
US9782724B2 (en) 2011-06-07 2017-10-10 Imtex Membranes Corp. Replenishing liquid material to membrane
AU2017228583B2 (en) * 2011-06-07 2019-09-19 Imtex Membranes Corp. Replenishing liquid material to membrane
CN112592251A (en) * 2020-12-23 2021-04-02 上海睿碳能源科技有限公司 Process and apparatus for separating a light hydrocarbon-containing stream

Also Published As

Publication number Publication date
JPS4948603A (en) 1974-05-11
CA1000307A (en) 1976-11-23
SU1088659A3 (en) 1984-04-23
AU5951173A (en) 1975-03-20
NL7306466A (en) 1973-11-14
AU476688B2 (en) 1975-03-20
FR2184809A1 (en) 1973-12-28
IT985014B (en) 1974-11-30
JPS5331842B2 (en) 1978-09-05
NL158088B (en) 1978-10-16
DE2323657C3 (en) 1979-04-19
FR2184809B1 (en) 1979-04-13
DE2323657B2 (en) 1978-08-24
DE2323657A1 (en) 1973-11-22

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee