GB1419833A - Water-dispersible film-forming polymer compositions and latexes obtained therefrom - Google Patents

Water-dispersible film-forming polymer compositions and latexes obtained therefrom

Info

Publication number
GB1419833A
GB1419833A GB1188373A GB1188373A GB1419833A GB 1419833 A GB1419833 A GB 1419833A GB 1188373 A GB1188373 A GB 1188373A GB 1188373 A GB1188373 A GB 1188373A GB 1419833 A GB1419833 A GB 1419833A
Authority
GB
United Kingdom
Prior art keywords
acid
latex
carbocyclic compound
polymer
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1188373A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB1419833A publication Critical patent/GB1419833A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Nonwoven Fabrics (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

1419833 Water redispersible polymer compositions DOW CHEMICAL CO 13 March 1973 [13 March 1972] 11883/73 Heading C3P A film-forming latex composition having an average particle size of 500 to 10,000 Angstroms and which when dried at a pH greater than 7 is redispersible in water to form a latex having substantially the same particle size as the original latex, comprises an aqueous dispersion of particles of a copolymer of 1-10 wt. per cent of an alpha, beta-ethylenically unsaturated carboxylic acid and a balance of a polymerizable water-insoluble ethylenic monomer composition, and an effective amount to provide water redispersibility, of a six-membered ring carbocyclic compound having two vicinal carboxyl or carboxylic salt groups which is soluble in aqueous alkaline media; said copolymer being film-forming below 95‹ C. The dried composition is also claimed. The polymer may contain, as the comonomer(s), units derived from a conjugated aliphatic diene, an alkenyl aromatic compound such as styrene, an acrylic ester, vinylidene chloride or vinyl acetate. The carbocyclic compound may be a phthalic acid, a 1,2,3,6-tetrahydrophthalic acid, or a hexahydrophthalic acid, and is preferably used in an amount of 2-8 parts by weight per 100 parts by weight of polymer. The latex may be prepared by either mixing the carbocyclic compound physically with a preformed latex of the polymer, polymerization in the presence of said carbocyclic compound or by forming the carbocyclic compound in situ during the polymerization at acid pH to form the polymer latex. In the latter method, the carbocyclic compound may be formed by reaction between fumaric acid or a monomethyl, monoethyl or monopropyl ester of an alpha, beta-ethylenically unsaturated dicarboxylic acid in which the carboxyl groups are both attached to the doubly bonded carbon atoms, and part of an aliphatic conjugated diene monomer which is present in the reaction mixture. Acid monomers used in the examples are itaconic acid, fumaric acid, acrylic acid, monomethylmaleate, monoethylmaleate, monopropylmaleate and monobutylmaleate.
GB1188373A 1972-03-13 1973-03-13 Water-dispersible film-forming polymer compositions and latexes obtained therefrom Expired GB1419833A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US23431972A 1972-03-13 1972-03-13

Publications (1)

Publication Number Publication Date
GB1419833A true GB1419833A (en) 1975-12-31

Family

ID=22880876

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1188373A Expired GB1419833A (en) 1972-03-13 1973-03-13 Water-dispersible film-forming polymer compositions and latexes obtained therefrom

Country Status (9)

Country Link
JP (1) JPS5752364B2 (en)
AU (1) AU465674B2 (en)
BE (1) BE796694A (en)
CA (1) CA997090A (en)
DE (1) DE2312408A1 (en)
FR (1) FR2175837B1 (en)
GB (1) GB1419833A (en)
IT (1) IT979815B (en)
NL (1) NL7303439A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009099717A2 (en) * 2008-02-08 2009-08-13 Dow Global Technologies Inc. Water-redispersible polymer powder
WO2009099718A2 (en) * 2008-02-08 2009-08-13 Dow Global Technologies Inc. Improved flexible foams
WO2010028870A1 (en) * 2008-09-10 2010-03-18 Construction Research & Technology Gmbh Use of cyclohexane polycarboxylic acid derivatives for removing dust from chemical construction products
EP2399955A1 (en) * 2010-06-24 2011-12-28 Dow Global Technologies LLC Redispersible polymer powders prepared from blends of carboxylated styrene butadiene-based latexes
US8366822B2 (en) 2011-06-20 2013-02-05 Dow Global Technologies Llc Cementitious tile adhesives and method of applying the same to a tile substrate
RU2510371C2 (en) * 2008-11-25 2014-03-27 Констракшн Рисёрч Энд Текнолоджи Гмбх Using polyols and cyclohexane polycarboxylic acid derivatives to remove dust from construction chemical products
RU2531405C2 (en) * 2009-04-14 2014-10-20 Констракшн Рисёрч Энд Текнолоджи Гмбх Dust-free powdered composition of construction material
US9062143B2 (en) 2008-02-08 2015-06-23 Dow Global Technologies Llc Water-redispersible polymer powder
US9181130B2 (en) 2010-06-15 2015-11-10 Dow Global Technologies Llc Redispersible polymer powder compositions prepared from styrene butadiene-based latex for dry mix formulations

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5738907B2 (en) * 1974-05-28 1982-08-18
US3963961A (en) * 1974-12-23 1976-06-15 United Technologies Corporation Cathode ray tube phosphor protection circuit
JPS5831424B2 (en) * 1979-01-18 1983-07-06 旭化成株式会社 Method of producing non-woven fabrics from synthetic fibers
JPS5618420Y2 (en) * 1979-07-04 1981-04-30
JP2018172563A (en) * 2017-03-31 2018-11-08 住友化学株式会社 Gel having interpenetrating network structure
CN115515912B (en) 2020-05-28 2023-09-15 瓦克化学股份公司 Method for producing water-redispersible polymer powders for dry formulations of building materials

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3409578A (en) * 1963-04-16 1968-11-05 Rohm & Haas Powdered water-insoluble polymers dispersible in aqueous media and methods of making them

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009099717A2 (en) * 2008-02-08 2009-08-13 Dow Global Technologies Inc. Water-redispersible polymer powder
WO2009099718A2 (en) * 2008-02-08 2009-08-13 Dow Global Technologies Inc. Improved flexible foams
WO2009099717A3 (en) * 2008-02-08 2009-12-17 Dow Global Technologies Inc. Water-redispersible polymer powder
CN105061656B (en) * 2008-02-08 2019-03-01 陶氏环球技术有限公司 Can water redisperse polymer powder
WO2009099718A3 (en) * 2008-02-08 2010-03-18 Dow Global Technologies Inc. Improved flexible foams
CN105061656A (en) * 2008-02-08 2015-11-18 陶氏环球技术有限公司 Water-redispersible polymer powder
US9062143B2 (en) 2008-02-08 2015-06-23 Dow Global Technologies Llc Water-redispersible polymer powder
US8765828B2 (en) 2008-02-08 2014-07-01 Dow Global Technologies Llc Flexible foams
US8535436B2 (en) 2008-09-10 2013-09-17 Construction Research & Technology Gmbh Use of cyclohexane polycarboxylic acid derivatives for removing dust from chemical construction products
RU2501757C2 (en) * 2008-09-10 2013-12-20 Констракшн Рисёрч Энд Текнолоджи Гмбх Application of derivatives of cyclohexane-polycaboxylic acids for dedusting of building chemical products
WO2010028870A1 (en) * 2008-09-10 2010-03-18 Construction Research & Technology Gmbh Use of cyclohexane polycarboxylic acid derivatives for removing dust from chemical construction products
RU2510371C2 (en) * 2008-11-25 2014-03-27 Констракшн Рисёрч Энд Текнолоджи Гмбх Using polyols and cyclohexane polycarboxylic acid derivatives to remove dust from construction chemical products
RU2531405C2 (en) * 2009-04-14 2014-10-20 Констракшн Рисёрч Энд Текнолоджи Гмбх Dust-free powdered composition of construction material
US9181130B2 (en) 2010-06-15 2015-11-10 Dow Global Technologies Llc Redispersible polymer powder compositions prepared from styrene butadiene-based latex for dry mix formulations
US8268927B2 (en) 2010-06-24 2012-09-18 Dow Global Technologies Llc Redispersible polymer powders prepared from blends of carboxylate
EP2399955A1 (en) * 2010-06-24 2011-12-28 Dow Global Technologies LLC Redispersible polymer powders prepared from blends of carboxylated styrene butadiene-based latexes
US8366822B2 (en) 2011-06-20 2013-02-05 Dow Global Technologies Llc Cementitious tile adhesives and method of applying the same to a tile substrate

Also Published As

Publication number Publication date
JPS5752364B2 (en) 1982-11-08
DE2312408A1 (en) 1973-09-20
AU5316173A (en) 1974-09-12
AU465674B2 (en) 1975-10-02
FR2175837B1 (en) 1977-04-22
FR2175837A1 (en) 1973-10-26
IT979815B (en) 1974-09-30
NL7303439A (en) 1973-09-17
JPS492845A (en) 1974-01-11
CA997090A (en) 1976-09-14
BE796694A (en) 1973-09-13

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Legal Events

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PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee