GB1419769A - Complexes containing phosphorus - Google Patents
Complexes containing phosphorusInfo
- Publication number
- GB1419769A GB1419769A GB2178272A GB2178272A GB1419769A GB 1419769 A GB1419769 A GB 1419769A GB 2178272 A GB2178272 A GB 2178272A GB 2178272 A GB2178272 A GB 2178272A GB 1419769 A GB1419769 A GB 1419769A
- Authority
- GB
- United Kingdom
- Prior art keywords
- denotes
- complexes
- rhodium
- iii
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 229910052794 bromium Inorganic materials 0.000 abstract 3
- 229910052740 iodine Inorganic materials 0.000 abstract 3
- -1 rhodium (III) halide Chemical class 0.000 abstract 3
- 230000001476 alcoholic effect Effects 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- PZSJYEAHAINDJI-UHFFFAOYSA-N rhodium(3+) Chemical class [Rh+3] PZSJYEAHAINDJI-UHFFFAOYSA-N 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910001513 alkali metal bromide Inorganic materials 0.000 abstract 1
- 229910001516 alkali metal iodide Inorganic materials 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000001309 chloro group Chemical class Cl* 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000006459 hydrosilylation reaction Methods 0.000 abstract 1
- 150000004694 iodide salts Chemical class 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- XFARCVVMIMKPGK-UHFFFAOYSA-N methyl-phenyl-(2-trimethylsilylphenyl)phosphane Chemical compound C[Si](C)(C)C1=C(C=CC=C1)P(C1=CC=CC=C1)C XFARCVVMIMKPGK-UHFFFAOYSA-N 0.000 abstract 1
- WJIBZZVTNMAURL-UHFFFAOYSA-N phosphane;rhodium Chemical class P.[Rh] WJIBZZVTNMAURL-UHFFFAOYSA-N 0.000 abstract 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
- C07F7/0878—Si-C bond
- C07F7/0879—Hydrosilylation reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1419769 Silylated rhodium phosphine complexes DOW CORNING Ltd 8 May 1973 [10 May 1972] 21782/72 Heading C3S The invention comprises rhodium (III) complexes of the formula wherein Y denotes Cl, Br or I, X denotes H or Y, R<SP>1</SP> denotes R 3 SiQ-, R denotes alkyl, aryl, aralkyl, alkaryl or (CH 3 ) 3 Si-, provided not more than one R denotes (CH 3 ) 3 Si-, Q denotes a C 1-6 divalent aliphatic hydrocarbon radical, and R<SP>11</SP> and R<SP>111</SP> denote alkyl, aryl, aralkyl, alkaryl or R 3 SiQ-. Complexes in which both X and Y denote Cl, Br or I may be prepared by reacting a rhodium (III) halide with an appropriate stoichiometric amount of in an alcohol solvent. Alternatively complexes in which X and Y denote bromine or iodine may be prepared from the corresponding chlorine complexes by reaction with alkali metal bromides or iodides. Complexes in which X denotes H may be prepared by adding PR<SP>1</SP>R<SP>11</SP>R<SP>111</SP> to a hot solution of rhodium (III) halide in alcoholic, acetanic or aqueous solution and subsequently refluxing. Alternatively alcoholic solutions of rhodium (III) halides and PR<SP>1</SP>R<SP>11</SP>R<SP>111</SP> are reacted with hypophosphorous acid at room temperature. Examples describe the preparation of trichlorotris- and hydridodichlorotris - (trimethylsilyl - methyldiphenylphosphine)rhodium (III). Uses.-As hydrosilylation, hydrogenation, hydroformylation and isomerization catalysts. In examples the specific rhodium (III) complexes referred to above are used to catalyse the addition of (Me 3 SiO) 2 SiMeH to vinyl to give a product of the formula
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2178272A GB1419769A (en) | 1972-05-10 | 1972-05-10 | Complexes containing phosphorus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2178272A GB1419769A (en) | 1972-05-10 | 1972-05-10 | Complexes containing phosphorus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1419769A true GB1419769A (en) | 1975-12-31 |
Family
ID=10168716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2178272A Expired GB1419769A (en) | 1972-05-10 | 1972-05-10 | Complexes containing phosphorus |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1419769A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4298541A (en) | 1979-02-12 | 1981-11-03 | Exxon Research & Engineering Co. | Trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous catalysts |
| US4450299A (en) * | 1980-10-01 | 1984-05-22 | Exxon Research And Engineering Co. | Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes |
| US4785126A (en) * | 1985-04-26 | 1988-11-15 | E. I. Du Pont De Nemours And Company | 1,4-O-metallation process and composition |
| US5332852A (en) * | 1985-04-26 | 1994-07-26 | E. I. Du Pont De Nemours And Company | 1,4-O-metallation process |
-
1972
- 1972-05-10 GB GB2178272A patent/GB1419769A/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4298541A (en) | 1979-02-12 | 1981-11-03 | Exxon Research & Engineering Co. | Trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous catalysts |
| US4480137A (en) * | 1979-02-12 | 1984-10-30 | Exxon Research & Engineering Company | Trihydrocarbyl silyl substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous carbonylation catalysts |
| US4450299A (en) * | 1980-10-01 | 1984-05-22 | Exxon Research And Engineering Co. | Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes |
| US4451673A (en) * | 1981-08-21 | 1984-05-29 | Exxon Research And Engineering Co. | Trihydrocarbyl silyl substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous isomerization hydroformylation catalysts |
| US4454353A (en) * | 1981-08-21 | 1984-06-12 | Exxon Research And Engineering Co. | Trihydrocarbyl silyl substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous hydroformylation-aldolization catalysts |
| US4785126A (en) * | 1985-04-26 | 1988-11-15 | E. I. Du Pont De Nemours And Company | 1,4-O-metallation process and composition |
| US5332852A (en) * | 1985-04-26 | 1994-07-26 | E. I. Du Pont De Nemours And Company | 1,4-O-metallation process |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |