GB1412257A - Complexes containing phosphorus - Google Patents
Complexes containing phosphorusInfo
- Publication number
- GB1412257A GB1412257A GB594072A GB594072A GB1412257A GB 1412257 A GB1412257 A GB 1412257A GB 594072 A GB594072 A GB 594072A GB 594072 A GB594072 A GB 594072A GB 1412257 A GB1412257 A GB 1412257A
- Authority
- GB
- United Kingdom
- Prior art keywords
- denotes
- denote
- compounds
- complexes
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 6
- 239000000460 chlorine Substances 0.000 abstract 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910052794 bromium Inorganic materials 0.000 abstract 3
- 229910052801 chlorine Inorganic materials 0.000 abstract 3
- 229910052740 iodine Inorganic materials 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910001513 alkali metal bromide Inorganic materials 0.000 abstract 1
- 229910001516 alkali metal iodide Inorganic materials 0.000 abstract 1
- -1 alkali metal thiocyanates Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000006459 hydrosilylation reaction Methods 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 150000003141 primary amines Chemical class 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 150000003573 thiols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
- C07F15/0066—Palladium compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
1412257 Binuclear metal-phosphorus complexes containing organo-silicon groups DOW CORNING Ltd 31 Jan 1973 [9 Feb 1972] 5940/72 Heading C3S The invention comprises complexes of the formulae in cis or trans form, and wherein M denotes Pt or Pd, X denotes Br, Cl, I; or -SCN, R<SP>1</SP> denotes R 3 SiQ- in which R denotes alkyl, aryl, aralkyl or alkaryl having less than 19 carbon atoms or not more than one R may also denote (CH 3 ) 3 Si-; and Q denotes a C 1-6 divalent hydrocarbon radical, R<SP>11</SP> and R<SP>111</SP> denote R 3 SiQ- or alkyl, aryl, aralkyl or alkaryl groups having less than 19 carbon atoms, Y denotes Br, Cl, I, -SCN or -SZ in which Z denotes phenyl or C 1-17 alkyl. Compounds in which M denotes Pt and X and Y denote halogen are prepared by reacting mononuclear complexes Pt(PR<SP>1</SP>R<SP>11</SP>R<SP>111</SP>) 2 X 2 with platinum II halides PtX 2 . Compounds in which M denotes Pd and X and Y denote chlorine are prepared by reacting mononuclear complexes with an ammonium or alkali metal chloropalladite. Compounds in which M denotes Pd and X and Y are Br or I are prepared by reacting together a phosphine PR<SP>1</SP>R<SP>11</SP>R<SP>111</SP>, sodium tetrachloropalladite hydrate and an alkali metal bromide or iodide. Compounds in which Y denotes -SZ are prepared by reacting an appropriate thiol with corresponding compounds in which Y denotes Cl. Compounds in which X and/or Y denote -SCN are prepared by the reaction of alkali metal thiocyanates with corresponding complexes in which X and Y denote Cl. An example describes the preparation of Uses.-As catalysts for the hydrosilation of aliphatic carbon to carbon double bonds and for hydrogenation reactions, and as intermediates in the reaction with primary and secondary amines to form nitrogen and phosphoruscontaining complexes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB594072A GB1412257A (en) | 1972-02-09 | 1972-02-09 | Complexes containing phosphorus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB594072A GB1412257A (en) | 1972-02-09 | 1972-02-09 | Complexes containing phosphorus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1412257A true GB1412257A (en) | 1975-10-29 |
Family
ID=9805482
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB594072A Expired GB1412257A (en) | 1972-02-09 | 1972-02-09 | Complexes containing phosphorus |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1412257A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4298541A (en) | 1979-02-12 | 1981-11-03 | Exxon Research & Engineering Co. | Trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous catalysts |
| US4450299A (en) * | 1980-10-01 | 1984-05-22 | Exxon Research And Engineering Co. | Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes |
| US4687874A (en) * | 1980-02-12 | 1987-08-18 | Exxon Research And Engineering Company | Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts |
-
1972
- 1972-02-09 GB GB594072A patent/GB1412257A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4298541A (en) | 1979-02-12 | 1981-11-03 | Exxon Research & Engineering Co. | Trihydrocarbyl silyl-substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous catalysts |
| US4687874A (en) * | 1980-02-12 | 1987-08-18 | Exxon Research And Engineering Company | Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts |
| US4450299A (en) * | 1980-10-01 | 1984-05-22 | Exxon Research And Engineering Co. | Homogeneous hydroformylation catalysis with silyl substituted alkyl diaryl phosphine metal complexes |
| US4451673A (en) * | 1981-08-21 | 1984-05-29 | Exxon Research And Engineering Co. | Trihydrocarbyl silyl substituted alkyl diaryl phosphine transition metal complexes and their use as homogeneous isomerization hydroformylation catalysts |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |