GB1417499A - Method for making alkylene- or cycloalkylene bis nitrogenzoate s and of alkylene or cycloalkylene- bis amino-benzoate s therefrom - Google Patents

Method for making alkylene- or cycloalkylene bis nitrogenzoate s and of alkylene or cycloalkylene- bis amino-benzoate s therefrom

Info

Publication number
GB1417499A
GB1417499A GB1746274A GB1746274A GB1417499A GB 1417499 A GB1417499 A GB 1417499A GB 1746274 A GB1746274 A GB 1746274A GB 1746274 A GB1746274 A GB 1746274A GB 1417499 A GB1417499 A GB 1417499A
Authority
GB
United Kingdom
Prior art keywords
alkylene
cycloalkylene
bis
nitrobenzoate
reaction mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1746274A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1417499A publication Critical patent/GB1417499A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/04—Formation of amino groups in compounds containing carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/52—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C229/54—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton with amino and carboxyl groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C229/60—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton with amino and carboxyl groups bound to carbon atoms of the same non-condensed six-membered aromatic ring with amino and carboxyl groups bound in meta- or para- positions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1417499 Alkylene or cycloalkylene bis- (nitrobenzoate(s)) MONSANTO CO 22 April 1974 [23 April 1973] 17462/74 Heading C2C The invention comprises a method of producing an alkylene or cycloalkylene bis-(nitrobenzoate) of the formula wherein X is halogen, n is zero or one and R is a linear or branched C 2 to C 8 alkylene radical characterized by initially heating at a temperature of 150‹ to 300‹ C. substantially equimolar amounts of each of a nitrobenzoic acid and a C 2 to C 8 alkylene or cycloalkylene glycol to form the corresponding hydroxyalkyl-nitrobenzoate then adding an additional substantially molar amount of a nitrobenzoic acid to the reaction mixture, continuing heating the reaction mixture at a temperature of 150‹ to 300‹ C. to produce the alkylene- or cycloalkylene-bis- (nitrobenzoate) and separating the resulting benzoate product from the reaction mixture. Optionally water of reaction may be removed from the reaction mixture. Also part of the invention is a method of producing an alkylene- or cycloalkylene - bis - (aminobenzoate) which comprises reducing to amino groups the nitro groups of an alkylene- or cycloalkylene-bis-(nitro benzoate) according to the invention.
GB1746274A 1973-04-23 1974-04-22 Method for making alkylene- or cycloalkylene bis nitrogenzoate s and of alkylene or cycloalkylene- bis amino-benzoate s therefrom Expired GB1417499A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US35328573A 1973-04-23 1973-04-23

Publications (1)

Publication Number Publication Date
GB1417499A true GB1417499A (en) 1975-12-10

Family

ID=23388471

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1746274A Expired GB1417499A (en) 1973-04-23 1974-04-22 Method for making alkylene- or cycloalkylene bis nitrogenzoate s and of alkylene or cycloalkylene- bis amino-benzoate s therefrom

Country Status (8)

Country Link
JP (1) JPS5012045A (en)
BE (1) BE814024A (en)
DE (1) DE2419322A1 (en)
FR (1) FR2226384B1 (en)
GB (1) GB1417499A (en)
IT (1) IT1009978B (en)
LU (1) LU69912A1 (en)
NL (1) NL7405326A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE440773B (en) * 1977-12-12 1985-08-19 Bofors Ab SET TO MAKE 1,3-PROPANDIOL-DI-P-AMINOBENSOATE
DE2902740A1 (en) * 1979-01-25 1980-08-07 Hoechst Ag METHOD FOR THE PRODUCTION OF ALKANDIOL-BIS-AMINO-BENZOESAEESEESTERS
US5719307A (en) * 1994-04-13 1998-02-17 Air Products And Chemicals, Inc. Diamine chain extenders and method of use

Also Published As

Publication number Publication date
NL7405326A (en) 1974-10-25
JPS5012045A (en) 1975-02-07
IT1009978B (en) 1976-12-20
LU69912A1 (en) 1974-11-21
FR2226384B1 (en) 1977-10-21
DE2419322A1 (en) 1974-11-07
FR2226384A1 (en) 1974-11-15
BE814024A (en) 1974-10-22

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee