GB1416060A - Preparation of polymerization catalyst and polymerization therewith - Google Patents
Preparation of polymerization catalyst and polymerization therewithInfo
- Publication number
- GB1416060A GB1416060A GB4548473A GB4548473A GB1416060A GB 1416060 A GB1416060 A GB 1416060A GB 4548473 A GB4548473 A GB 4548473A GB 4548473 A GB4548473 A GB 4548473A GB 1416060 A GB1416060 A GB 1416060A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nickel
- catalyst
- butadiene
- cis
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002685 polymerization catalyst Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- 229910052759 nickel Inorganic materials 0.000 abstract 4
- 239000003381 stabilizer Substances 0.000 abstract 3
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- 150000001993 dienes Chemical class 0.000 abstract 2
- 150000002222 fluorine compounds Chemical class 0.000 abstract 2
- 150000002899 organoaluminium compounds Chemical class 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- UVPKUTPZWFHAHY-UHFFFAOYSA-L 2-ethylhexanoate;nickel(2+) Chemical compound [Ni+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O UVPKUTPZWFHAHY-UHFFFAOYSA-L 0.000 abstract 1
- 101100001475 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) alr-1 gene Proteins 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- -1 nickel carboxylates Chemical class 0.000 abstract 1
- 150000002816 nickel compounds Chemical class 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920003048 styrene butadiene rubber Polymers 0.000 abstract 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00301397A US3845029A (en) | 1972-10-27 | 1972-10-27 | Polymerization of butadiene with stabilized catalyst system |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1416060A true GB1416060A (en) | 1975-12-03 |
Family
ID=23163168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4548473A Expired GB1416060A (en) | 1972-10-27 | 1973-09-28 | Preparation of polymerization catalyst and polymerization therewith |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3845029A (cg-RX-API-DMAC7.html) |
| JP (1) | JPS5442031B2 (cg-RX-API-DMAC7.html) |
| AR (1) | AR196171A1 (cg-RX-API-DMAC7.html) |
| AU (1) | AU476439B2 (cg-RX-API-DMAC7.html) |
| BE (1) | BE806610A (cg-RX-API-DMAC7.html) |
| BR (1) | BR7308294D0 (cg-RX-API-DMAC7.html) |
| CA (1) | CA1013897A (cg-RX-API-DMAC7.html) |
| DD (1) | DD107295A5 (cg-RX-API-DMAC7.html) |
| DE (1) | DE2350941A1 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2204634B1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1416060A (cg-RX-API-DMAC7.html) |
| IT (1) | IT997771B (cg-RX-API-DMAC7.html) |
| NL (1) | NL173754C (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA737563B (cg-RX-API-DMAC7.html) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1417608A (en) * | 1972-03-01 | 1975-12-10 | Sumitomo Chemical Co | Polymeric aluminium fluoride compounds and their use as catalysts in process for producing butadiene polymers |
| US4020255A (en) * | 1975-05-07 | 1977-04-26 | The Goodyear Tire & Rubber Company | Continuous insitu catalyst addition for polybutadiene polymerization |
| CA1108798A (en) * | 1978-05-08 | 1981-09-08 | Evalds Lasis | Low benzene butadiene polymerization |
| US4463146A (en) * | 1982-12-23 | 1984-07-31 | The Goodyear Tire & Rubber Company | Syndiotactic 1,2-polybutadiene synthesis process |
| US4501866A (en) * | 1984-07-23 | 1985-02-26 | The Firestone Tire & Rubber Company | Continuous method for preparing high cis-1,4 polybutadiene |
| US7749934B2 (en) * | 2005-02-22 | 2010-07-06 | Rohm And Haas Company | Protected catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers |
| CN100469798C (zh) * | 2005-02-22 | 2009-03-18 | 罗门哈斯公司 | 保护的催化组合物及其制备方法以及在由烯键式不饱和单体制备聚合物中的应用 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3464965A (en) * | 1965-10-08 | 1969-09-02 | Japan Synthetic Rubber Co Ltd | Process for producing polybutadienes having reduced cold flow tendency |
-
1972
- 1972-10-27 US US00301397A patent/US3845029A/en not_active Expired - Lifetime
-
1973
- 1973-09-20 CA CA181,491A patent/CA1013897A/en not_active Expired
- 1973-09-25 ZA ZA737563*A patent/ZA737563B/xx unknown
- 1973-09-27 AU AU60793/73A patent/AU476439B2/en not_active Expired
- 1973-09-28 GB GB4548473A patent/GB1416060A/en not_active Expired
- 1973-10-04 AR AR250371A patent/AR196171A1/es active
- 1973-10-10 DE DE19732350941 patent/DE2350941A1/de not_active Ceased
- 1973-10-23 IT IT53287/73A patent/IT997771B/it active
- 1973-10-24 BR BR8294/73A patent/BR7308294D0/pt unknown
- 1973-10-25 DD DD174297*A patent/DD107295A5/xx unknown
- 1973-10-25 FR FR7338128A patent/FR2204634B1/fr not_active Expired
- 1973-10-26 BE BE137150A patent/BE806610A/xx not_active IP Right Cessation
- 1973-10-26 NL NLAANVRAGE7314780,A patent/NL173754C/xx not_active IP Right Cessation
- 1973-10-27 JP JP12116173A patent/JPS5442031B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DD107295A5 (cg-RX-API-DMAC7.html) | 1974-07-20 |
| AR196171A1 (es) | 1973-11-30 |
| US3845029A (en) | 1974-10-29 |
| JPS5442031B2 (cg-RX-API-DMAC7.html) | 1979-12-12 |
| AU476439B2 (en) | 1976-09-23 |
| BE806610A (fr) | 1974-02-15 |
| NL7314780A (cg-RX-API-DMAC7.html) | 1974-05-01 |
| DE2350941A1 (de) | 1974-05-02 |
| FR2204634B1 (cg-RX-API-DMAC7.html) | 1978-02-17 |
| AU6079373A (en) | 1975-03-27 |
| BR7308294D0 (pt) | 1974-08-29 |
| JPS4976984A (cg-RX-API-DMAC7.html) | 1974-07-24 |
| IT997771B (it) | 1975-12-30 |
| FR2204634A1 (cg-RX-API-DMAC7.html) | 1974-05-24 |
| ZA737563B (en) | 1974-08-28 |
| CA1013897A (en) | 1977-07-12 |
| NL173754C (nl) | 1984-03-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |