GB1409779A - Process for the preparation of catalysts for the dimerization or codimerization of linear olefins - Google Patents

Process for the preparation of catalysts for the dimerization or codimerization of linear olefins

Info

Publication number
GB1409779A
GB1409779A GB4274373A GB4274373A GB1409779A GB 1409779 A GB1409779 A GB 1409779A GB 4274373 A GB4274373 A GB 4274373A GB 4274373 A GB4274373 A GB 4274373A GB 1409779 A GB1409779 A GB 1409779A
Authority
GB
United Kingdom
Prior art keywords
zeolite
base
catalysts
mins
sept
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4274373A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societa Italiana Resine SpA SIR
Original Assignee
Societa Italiana Resine SpA SIR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societa Italiana Resine SpA SIR filed Critical Societa Italiana Resine SpA SIR
Publication of GB1409779A publication Critical patent/GB1409779A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1409779 Dimerisation catalyst SOC ITALIANA RESINE SIR SPA 11 Sept 1973 [20 Sept 1972] 42743/73 Heading B1E [Also in Division C5] Olefin dimerisation catalysts are formed by (i) depositing 0.1-50% wt. of one or more Gp VIII metals on a natural or synthetic zeolite by ion exchange; (ii) contacting with an organic or inorganic base in the liquid or gas form at -35 to 250‹C for at least 30 mins, and (iii) eliminating the excess of base and heat-treating at 50-450‹C for at least 30 mins. Suitably, the zeolite has a surface area of 200-1200 m<SP>2</SP>/g and a pore diameter of 6 to 15A‹ and the group VIII metal is nickel or cobalt. Specified bases are: ammonia, monoethylamine, diethylamine, butylamine, ethylenediamine; pyridine, piperidine, picoline, quinoline and isoquinoline. The zeolite may be suspended in a liquid base, such a base may be allowed to percolate through a bed of the zeolite or a gaseous stream of the base may be passed through a bed of the zeolite. Excess base may be removed by heating. The Examples relate to nickel-on-zeolite 13X catalysts.
GB4274373A 1972-09-20 1973-09-11 Process for the preparation of catalysts for the dimerization or codimerization of linear olefins Expired GB1409779A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT29427/72A IT967655B (en) 1972-09-20 1972-09-20 PROCEDURE FOR THE DIMERIZATION OF OLEFINS AND RELATIVE CATALYST

Publications (1)

Publication Number Publication Date
GB1409779A true GB1409779A (en) 1975-10-15

Family

ID=11226970

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4274373A Expired GB1409779A (en) 1972-09-20 1973-09-11 Process for the preparation of catalysts for the dimerization or codimerization of linear olefins

Country Status (8)

Country Link
JP (1) JPS5216877B2 (en)
CA (1) CA1008473A (en)
DE (1) DE2347235A1 (en)
FR (1) FR2200048B1 (en)
GB (1) GB1409779A (en)
IT (1) IT967655B (en)
NL (1) NL7312968A (en)
YU (1) YU35966B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2154603A (en) * 1984-02-27 1985-09-11 Chevron Res Catalytic oligomerization of liquid olefins
GB2246365A (en) * 1990-07-27 1992-01-29 Exxon Chemical Patents Inc Hydrocarbon treatment
GB2246307A (en) * 1990-07-27 1992-01-29 Exxon Chemical Patents Inc Desulphurising hydrocarbons

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA801758B (en) * 1979-04-04 1981-03-25 Mobil Oil Corp Steam-resistant zeolite catalyst
US4520221A (en) * 1984-04-09 1985-05-28 Mobil Oil Corporation Process of making high VI lubes
AU613954B2 (en) * 1987-10-07 1991-08-15 Mobil Oil Corporation Olefin oligomerization
GB9011411D0 (en) * 1990-05-22 1990-07-11 Shell Int Research Metals-containing zeolites,a process for preparing such zeolites and their use in catalytic processes
DE4339713A1 (en) * 1993-11-22 1995-05-24 Basf Ag Process for oligomerization of olefins to highly linear oligomers and catalysts therefor
DE19629906A1 (en) * 1996-07-24 1998-01-29 Huels Chemische Werke Ag Flexible production of butene oligomers and alkyl tertiary butyl ether(s) from Fischer-Tropsch olefin(s)
US20150148572A1 (en) 2013-11-27 2015-05-28 Saudi Arabian Oil Company Process for the Dimerization/Oligomerization of Mixed Butenes Over an Ion-Exchange Resin Catalyst

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3404085A (en) * 1966-08-30 1968-10-01 Exxon Research Engineering Co Hydrocracking process for high octane product
US3644200A (en) * 1968-12-23 1972-02-22 Union Oil Co Ammoniated zeolite catalysts
GB1266781A (en) * 1969-02-20 1972-03-15

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2154603A (en) * 1984-02-27 1985-09-11 Chevron Res Catalytic oligomerization of liquid olefins
GB2246365A (en) * 1990-07-27 1992-01-29 Exxon Chemical Patents Inc Hydrocarbon treatment
GB2246307A (en) * 1990-07-27 1992-01-29 Exxon Chemical Patents Inc Desulphurising hydrocarbons

Also Published As

Publication number Publication date
FR2200048A1 (en) 1974-04-19
FR2200048B1 (en) 1978-01-27
YU248273A (en) 1981-02-28
DE2347235A1 (en) 1974-04-11
CA1008473A (en) 1977-04-12
JPS5216877B2 (en) 1977-05-12
IT967655B (en) 1974-03-11
YU35966B (en) 1981-11-13
NL7312968A (en) 1974-03-22
JPS4970891A (en) 1974-07-09

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Legal Events

Date Code Title Description
PS Patent sealed
435 Patent endorsed 'licences of right' on the date specified (sect. 35/1949)
PCNP Patent ceased through non-payment of renewal fee