GB140439A - Improvements in and relating to the production of ammonia - Google Patents
Improvements in and relating to the production of ammoniaInfo
- Publication number
- GB140439A GB140439A GB7967/20A GB796720A GB140439A GB 140439 A GB140439 A GB 140439A GB 7967/20 A GB7967/20 A GB 7967/20A GB 796720 A GB796720 A GB 796720A GB 140439 A GB140439 A GB 140439A
- Authority
- GB
- United Kingdom
- Prior art keywords
- calcium
- cyanamide
- liquid ammonia
- solution
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title abstract 11
- 229910021529 ammonia Inorganic materials 0.000 title abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 8
- 229910052791 calcium Inorganic materials 0.000 abstract 8
- 239000011575 calcium Substances 0.000 abstract 8
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 abstract 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 5
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract 4
- MVXMNHYVCLMLDD-UHFFFAOYSA-N 4-methoxynaphthalene-1-carbaldehyde Chemical compound C1=CC=C2C(OC)=CC=C(C=O)C2=C1 MVXMNHYVCLMLDD-UHFFFAOYSA-N 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 3
- 239000005977 Ethylene Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 239000005997 Calcium carbide Substances 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- CWVZGJORVTZXFW-UHFFFAOYSA-N [benzyl(dimethyl)silyl]methyl carbamate Chemical compound NC(=O)OC[Si](C)(C)CC1=CC=CC=C1 CWVZGJORVTZXFW-UHFFFAOYSA-N 0.000 abstract 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 150000001247 metal acetylides Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910001961 silver nitrate Inorganic materials 0.000 abstract 2
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 abstract 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- -1 calcium carbide Chemical class 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 238000001311 chemical methods and process Methods 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000013065 commercial product Substances 0.000 abstract 1
- 150000001912 cyanamides Chemical class 0.000 abstract 1
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 238000007689 inspection Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000010955 niobium Substances 0.000 abstract 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 1
- 150000004767 nitrides Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
- C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
- C01C1/0411—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst characterised by the catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Ammonia is prepared by passing a mixture of nitrogen and hydrogen over a catalyst consisting of a mixture of an alkali or alkali earth metal cyanamide and a nitride-forming metal; such metals are iron, manganese, cobalt, ruthenium, osmium, vanadium, columbium, and tantalum, and as cyanamides those of calcium, barium, strontium, or potassium may be employed. It is not essential that the cyanamide should be initially present as such, but may be formed during the course of the process, being introduced in the form of carbide or cyanide; and the nitride-forming metal may be added as such or as a compound such as a nitride, ferrocyanide or ferricyanide, or as a compound containing a plurality of nitrogen-carriers such as manganese ferrocyanide, ferric cobaltocyanide, or manganese-iron cobaltocyanide. The process may be carried out at atmospheric pressure, although increased yields are obtained by employing higher pressures, for example, 10 atmospheres; and it is preferred to employ a nitride-forming metal such that the process may be carried out at a temperature below 600 DEG C., and above 400 DEG C., and preferably at about 450 DEG C. The materials constituting the catalyst are preferably purified or prepared as follows:-Calcium cyanamide, by dissolving the commercial products in water, treating with sufficient silver nitrate solution to precipitate sulphur, and then with carbonic acid to precipitate cyanamide, which is dissolved in liquid ammonia and reconverted into calcium cyanamide by adding metallic calcium; calcium carbide, by passing acetylene through a solution of calcium in liquid ammonia -such carbide has the formula CaC and gives ethylene when treated with water; calcium cyanide, by passing hydrocyanic acid gas through a solution of calcium in liquid ammonia. The materials for the catalyst may be briquetted together by treating with a solution of potassium cyanide in liquid ammonia. The Specification as open to inspection under Sect. 91 (3) (a) included also a process in which a cyanamide was employed alone in conjunction with the application of pressure, for example 100 atmospheres. This subject-matter does not appear in the Specification as accepted.ALSO:Ethylene is obtained by treating with water calcium &c carbides of the formula CaC.ALSO:Calcium cyanamide in a pure condition is prepared by dissolving the commercial product in water, treating with sufficient silver nitrate solution to precipitate any sulphur, and then with carbonic dioxide to precipitate cyanamide which is afterwards dissolved in liquid ammonia and reconverted in calcium cyanamide by adding metallic calcium. Calcium cyanide in a fine condition and as a white flocculent powder is prepared by passing hydrocyanic acid through a solution of metallic calcium in liquid ammonia. Carbides, particularly calcium carbide, of the formula CaC, and which give ethylene when treated with water, are prepared by passing acetylene through a solution of calcium in liquid ammonia. Reference has been directed by the Comptroller to Specification 143,550, [Class 1 (i), Chemical processes &c.]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US140439XA | 1919-03-17 | 1919-03-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB140439A true GB140439A (en) | 1921-09-19 |
Family
ID=21763223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7967/20A Expired GB140439A (en) | 1919-03-17 | 1920-03-17 | Improvements in and relating to the production of ammonia |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB140439A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3081294A4 (en) * | 2013-12-10 | 2017-06-14 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Catalyst for ammonia synthesis and ammonia decomposition |
| CN110461466A (en) * | 2017-03-17 | 2019-11-15 | 国立研究开发法人科学技术振兴机构 | Metal load content, metal supported catalyst, the manufacturing method of ammonia, the manufacturing method of method for preparing hydrogen and cyanamide compound |
-
1920
- 1920-03-17 GB GB7967/20A patent/GB140439A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3081294A4 (en) * | 2013-12-10 | 2017-06-14 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Catalyst for ammonia synthesis and ammonia decomposition |
| CN110461466A (en) * | 2017-03-17 | 2019-11-15 | 国立研究开发法人科学技术振兴机构 | Metal load content, metal supported catalyst, the manufacturing method of ammonia, the manufacturing method of method for preparing hydrogen and cyanamide compound |
| EP3597292A4 (en) * | 2017-03-17 | 2021-03-17 | Japan Science and Technology Agency | Metal support, supported metal catalyst, production method for ammonia, production method for hydrogen, and production method for cyanamide compound |
| IL269222A (en) * | 2017-03-17 | 2022-12-01 | Japan Science & Tech Agency | Supported metal material, supported metal catalyst, method of producing ammonia, method of producing hydrogen and method of producing cyanamide compound |
| IL269222B2 (en) * | 2017-03-17 | 2023-04-01 | Japan Science & Tech Agency | Supported metal material, supported metal catalyst, method of producing ammonia, method of producing hydrogen and method of producing cyanamide compound |
| US11819827B2 (en) | 2017-03-17 | 2023-11-21 | Japan Science And Technology Agency | Supported metal material, supported metal catalyst, method of producing ammonia, method of producing hydrogen and method of producing cyanamide compound |
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