GB1402845A - Age resisters and age resistant polymeric compositions - Google Patents
Age resisters and age resistant polymeric compositionsInfo
- Publication number
- GB1402845A GB1402845A GB967775A GB967775A GB1402845A GB 1402845 A GB1402845 A GB 1402845A GB 967775 A GB967775 A GB 967775A GB 967775 A GB967775 A GB 967775A GB 1402845 A GB1402845 A GB 1402845A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- radicals
- hydrogen
- polymers
- alkyl radicals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/10—Esters
- C08F22/12—Esters of phenols or saturated alcohols
- C08F22/22—Esters containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1402845 Age resistant polymers and polymer compositions GOODYEAR TIRE & RUBBER CO 15 June 1972 [15 June 1971] 9677/75 Divided out of 1402720 Heading C3P [Also in Division C2] New compounds of the general formula below are used to give age resistant properties to polymers, either by addition to pre-formed polymers or by using them as one of the monomers in a polymerization recipe containing at least 40 wt. per cent (based on total monomers) of a diene. The compounds are of formula wherein R is selected from alkyl radicals having 1 to 12 carbon atoms, cycloalkyl radicals having 5 to 12 carbon atoms, aralkyl radicals having 7 to 24 carbon atoms and aryl radicals having 6 to 24 carbon atoms, wherein R<SP>1</SP> and R<SP>2</SP> are selected from hydrogen and alkyl groups having 1 to 4 carbon atoms and wherein R<SP>3</SP> is selected from hydrogen, alkyl radicals having 1 to 12 carbon atoms, cycloalkyl radicals having from 5 to 12 carbon atoms, and aralkyl radicals having 7 to 24 carbon atoms, wherein R<SP>4</SP>, R<SP>5</SP>, R<SP>6</SP> , R<SP>7</SP> and R<SP>8</SP> are selected from hydrogen and alkyl radicals having from 1 to 4 carbon atoms, wherein R<SP>9</SP> is selected from hydrogen, alkyl radicals having from 1 to 4 carbon atoms, carboxymethyl radical and carbalkoxymethyl radicals, and wherein R<SP>10</SP> is selected from hydrogen, alkyl radicals having from 1 to 4 carbon atoms, phenyl and substituted phenyl radicals, alkyl radicals having 1 to 4 carbon atoms, alkoxy radicals having 1 or 2 carbon atoms, carboxyl radical and carbalkoxy radicals. Compositions.-Examples illustrate the stabilization of SBR and nitrile rubber with 3-N-(41- anilinophenyl)-amino-2-hydroxypropyl methacrylate (the reaction product of glycidyl methacrylate and p-aminodiphenylamine). Polymers.-Examples describe the production, by conventional emulsion polymerization techniques, of terpolymers of (i) butadiene as major component, (ii) styrene or acrylonitrile, and (iii) the reaction product of glycidyl methacrylate with either p-aminodiphenylamine or N-phenyl- N<SP>1</SP>-1,3-dimethylbutyl-p-phenylene diamine.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00153446A US3817916A (en) | 1971-06-15 | 1971-06-15 | Oxidation resistant polymeric compositions prepared from 3 - n-(4' - anilinophenyl)amino - 2-hydroxypropyl methacrylate |
US05/153,449 US3953411A (en) | 1971-06-15 | 1971-06-15 | Age resistant polymers of 4-(arylamino)aryl esters of α,β unsaturated carboxylic acids |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1402845A true GB1402845A (en) | 1975-08-13 |
Family
ID=26850557
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB967775A Expired GB1402845A (en) | 1971-06-15 | 1972-06-15 | Age resisters and age resistant polymeric compositions |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS5515488B2 (en) |
AR (1) | AR195670A1 (en) |
AU (1) | AU461115B2 (en) |
BE (1) | BE784694A (en) |
CA (1) | CA993147A (en) |
DE (1) | DE2225279A1 (en) |
FR (1) | FR2142370A5 (en) |
GB (1) | GB1402845A (en) |
NL (1) | NL173962C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113956538A (en) * | 2020-07-20 | 2022-01-21 | 北京化工大学 | Novel anti-aging agent and preparation method and application thereof |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5127278B2 (en) * | 1972-06-30 | 1976-08-11 | ||
US4804028A (en) * | 1986-03-05 | 1989-02-14 | The Goodyear Tire & Rubber Company | Non-staining vulcanized elastomeric composition and tires having sidewalls comprising said composition |
US5049625A (en) * | 1990-03-08 | 1991-09-17 | The Goodyear Tire & Rubber Company | Polymeric diphenyldiamines |
WO2018008580A1 (en) * | 2016-07-06 | 2018-01-11 | セメダイン株式会社 | Curable composition and product |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1457152A (en) * | 1964-12-08 | 1966-07-08 | Bayer Ag | Process for the preparation of phenols containing unsaturated groups |
GB1307409A (en) * | 1969-06-23 | 1973-02-21 | Goodyear Tire & Rubber | Age resisters and age resistant polymeric compositions |
-
1972
- 1972-05-10 AU AU42134/72A patent/AU461115B2/en not_active Expired
- 1972-05-12 CA CA141,947A patent/CA993147A/en not_active Expired
- 1972-05-18 AR AR242060A patent/AR195670A1/en active
- 1972-05-24 DE DE19722225279 patent/DE2225279A1/en active Granted
- 1972-06-08 FR FR7220590A patent/FR2142370A5/fr not_active Expired
- 1972-06-09 BE BE784694A patent/BE784694A/en not_active IP Right Cessation
- 1972-06-13 JP JP5894172A patent/JPS5515488B2/ja not_active Expired
- 1972-06-15 NL NLAANVRAGE7208202,A patent/NL173962C/en not_active IP Right Cessation
- 1972-06-15 GB GB967775A patent/GB1402845A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113956538A (en) * | 2020-07-20 | 2022-01-21 | 北京化工大学 | Novel anti-aging agent and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
AR195670A1 (en) | 1973-10-31 |
BE784694A (en) | 1972-10-02 |
NL173962C (en) | 1984-04-02 |
AU4213472A (en) | 1973-11-15 |
NL173962B (en) | 1983-11-01 |
FR2142370A5 (en) | 1973-01-26 |
JPS4815988A (en) | 1973-02-28 |
DE2225279C2 (en) | 1987-12-23 |
NL7208202A (en) | 1972-12-19 |
DE2225279A1 (en) | 1972-12-21 |
CA993147A (en) | 1976-07-13 |
AU461115B2 (en) | 1975-05-15 |
JPS5515488B2 (en) | 1980-04-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PE20 | Patent expired after termination of 20 years |