GB1400978A - Stabilized ethylenically unsaturated beta-hydroxy esters - Google Patents
Stabilized ethylenically unsaturated beta-hydroxy estersInfo
- Publication number
- GB1400978A GB1400978A GB1702573A GB1702573A GB1400978A GB 1400978 A GB1400978 A GB 1400978A GB 1702573 A GB1702573 A GB 1702573A GB 1702573 A GB1702573 A GB 1702573A GB 1400978 A GB1400978 A GB 1400978A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylenically unsaturated
- hydroxy esters
- april
- ester
- tin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
- C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
- C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
- C08G59/1461—Unsaturated monoacids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Resins (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1400978 Ethylenically unsaturated ester CONTINENTAL CAN CO Inc 10 April 1973 [10 April 1972 13 Nov 1972] 17025/73 Headings C3B and C3P Ethylenically unsaturated #-hydroxy esters, stable to premature gelation and which are polymerizable by ionizing radiation, are prepared by reacting a polyepoxide containing at least 2 epoxy groups per molecule with an α,#-ethylenically unsaturated C 3-6 monocarboxylic acid in the presence of a tin halide, e.g. SnCl 2 . The tin halide may be used at 0À1-1% by wt. of the reaction mixture. An alkaline catalyst such as a tertiary amine, e.g. benzyldimethylamine is also present. The tin salt may be deactivated by treatment with phosphoric acid. The ester may be polymerized by ultraviolet radiation, optionally in the presence of other ethylenically unsaturated materials, e.g. polyethylene glycol diacrylate or pentaerythritol tetraacrylate.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24277772A | 1972-04-10 | 1972-04-10 | |
| US30610672A | 1972-11-13 | 1972-11-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1400978A true GB1400978A (en) | 1975-07-16 |
Family
ID=26935330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1702573A Expired GB1400978A (en) | 1972-04-10 | 1973-04-10 | Stabilized ethylenically unsaturated beta-hydroxy esters |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5610299B2 (en) |
| CA (1) | CA1010189A (en) |
| DD (1) | DD107014A5 (en) |
| DE (1) | DE2317523C2 (en) |
| FR (1) | FR2179893B1 (en) |
| GB (1) | GB1400978A (en) |
| IT (1) | IT988619B (en) |
| NL (1) | NL7304913A (en) |
| RO (1) | RO62889A (en) |
| SE (1) | SE403771B (en) |
| SU (1) | SU474971A4 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0126341A2 (en) * | 1983-05-06 | 1984-11-28 | BASF Aktiengesellschaft | Process for the preparation of esters of (meth)-acrylic acid, and their use |
| EP0214444A2 (en) * | 1985-08-08 | 1987-03-18 | BASF Aktiengesellschaft | Process for the preparation of vinyl ester resins |
| US6706208B2 (en) | 1999-12-22 | 2004-03-16 | Nippon Shokubai Co., Ltd. | Stabilized hydroxyalkyl (meth)acrylate |
-
1973
- 1973-03-22 SE SE7304028A patent/SE403771B/en unknown
- 1973-03-30 IT IT2239973A patent/IT988619B/en active
- 1973-04-07 DE DE19732317523 patent/DE2317523C2/en not_active Expired
- 1973-04-09 RO RO7442273A patent/RO62889A/en unknown
- 1973-04-09 JP JP3964873A patent/JPS5610299B2/ja not_active Expired
- 1973-04-09 CA CA168,205A patent/CA1010189A/en not_active Expired
- 1973-04-09 NL NL7304913A patent/NL7304913A/xx not_active Application Discontinuation
- 1973-04-09 SU SU1907616A patent/SU474971A4/en active
- 1973-04-10 DD DD17007273A patent/DD107014A5/xx unknown
- 1973-04-10 GB GB1702573A patent/GB1400978A/en not_active Expired
- 1973-04-10 FR FR7312799A patent/FR2179893B1/fr not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0126341A2 (en) * | 1983-05-06 | 1984-11-28 | BASF Aktiengesellschaft | Process for the preparation of esters of (meth)-acrylic acid, and their use |
| EP0126341A3 (en) * | 1983-05-06 | 1987-02-04 | Basf Aktiengesellschaft | Process for the preparation of esters of (meth)-acrylic acid, and their use |
| EP0214444A2 (en) * | 1985-08-08 | 1987-03-18 | BASF Aktiengesellschaft | Process for the preparation of vinyl ester resins |
| EP0214444A3 (en) * | 1985-08-08 | 1988-04-06 | BASF Aktiengesellschaft | Process for the preparation of vinyl ester resins |
| US6706208B2 (en) | 1999-12-22 | 2004-03-16 | Nippon Shokubai Co., Ltd. | Stabilized hydroxyalkyl (meth)acrylate |
Also Published As
| Publication number | Publication date |
|---|---|
| IT988619B (en) | 1975-04-30 |
| JPS497213A (en) | 1974-01-22 |
| CA1010189A (en) | 1977-05-10 |
| NL7304913A (en) | 1973-10-12 |
| FR2179893B1 (en) | 1977-08-19 |
| DD107014A5 (en) | 1974-07-12 |
| JPS5610299B2 (en) | 1981-03-06 |
| SE403771B (en) | 1978-09-04 |
| RO62889A (en) | 1978-01-15 |
| DE2317523C2 (en) | 1982-07-29 |
| DE2317523A1 (en) | 1973-11-08 |
| FR2179893A1 (en) | 1973-11-23 |
| SU474971A4 (en) | 1975-06-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |