GB1393104A - Reinforcement for elastomeric material - Google Patents

Reinforcement for elastomeric material

Info

Publication number
GB1393104A
GB1393104A GB1109572A GB1109572A GB1393104A GB 1393104 A GB1393104 A GB 1393104A GB 1109572 A GB1109572 A GB 1109572A GB 1109572 A GB1109572 A GB 1109572A GB 1393104 A GB1393104 A GB 1393104A
Authority
GB
United Kingdom
Prior art keywords
retarder
fibres
elastomer
vulcanisation
bundle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1109572A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Owens Corning
Original Assignee
Owens Corning Fiberglas Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Owens Corning Fiberglas Corp filed Critical Owens Corning Fiberglas Corp
Publication of GB1393104A publication Critical patent/GB1393104A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/27—Rubber latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10S156/91—Bonding tire cord and elastomer: improved adhesive system
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2973—Particular cross section
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926—Coated or impregnated inorganic fiber fabric
    • Y10T442/2934—Coating or impregnation contains vinyl polymer or copolymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926—Coated or impregnated inorganic fiber fabric
    • Y10T442/2951—Coating or impregnation contains epoxy polymer or copolymer or polyether
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926—Coated or impregnated inorganic fiber fabric
    • Y10T442/2959—Coating or impregnation contains aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926—Coated or impregnated inorganic fiber fabric
    • Y10T442/2992—Coated or impregnated glass fiber fabric

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

1393104 Impregnated fibre bundle; yams OWENS-CORNING FIBERGLAS CORP 9 March 1972 [9 March 1971] 11095/72 Headings D1P D1R and D1W [Also in Division B2] A reinforcement for elastomeric material comprises a bundle of fibres having a coating of, and/or impregnated with, an elastomer compatible material and a vulcanisation or cure retarder which is acidic and capable of reacting with low molecular weight components of the elastomer compatible material thereby preventing said components from migrating from the coating or impregnant and is selected from N-nitrosoamines having boiling point greater than 200‹C, carboxylic acids and anhydrides or acid halides having a boiling point greater than 200‹C and cobalt amines. The term "fibre bundle" is defined as meaning a strand, yarn or cord formed from a plurality of filaments, woven or non-woven fabric formed from fibres in the form of cords, or any arrangement, woven or non-woven, of fibres or filaments. The term "elastomer" includes natural rubber and synthetic rubbers such as butadiene-styrene copolymer, butadiene-acrylonitrile copolymer, polychloroprene, polyisoprene, polyneoprene, isobutyl rubber, inter-polymers of ethylene, propylene, and a polyene such as dicyclopentadiene, 1, 4-hexadiene and preferably an alkylene and alkylidene norbornene such as 5-alkylidene-2- norbornene, and polysulfone rubber. The reinforcement may be used in belt manufacture, rubber tyres. A fibre-reinforced elastomer product is produced by combining the reinforcement with an elastomeric material and moulding the resulting combination under heat and pressure so that a uniform rate of vulcanisation or cure is achieved throughout the reinforced elastomeric product. The vulcanisation retarder is said to moderate the rate of vulcanisation and/or cure of the elastomeric material immediately adjacent to the fibre bundle with the result that a more uniform rate of vulcanisation and/or cure takes place throughout the fibre bundle elastomeric composite. The fibres may be metal, polyester, nylon, rayon, glass. Examples of specific retarders are given. The retarder may be present in the form of a thin coating on the impregnated or coated bundle, or the retarder may be admixed with the elastomer compatible material. The elastomer compatible material may be a mixture of an elastomer latex with an amine--modified resorcinol aldehyde resin, a butadiene-styrene-vinyl pyridene terpolymer, a urea-aldehyde resin, a melamine-aldehyde resin, a polyester, a polyamide or a polyepoxide. The retarder may be present in amount 0.1-25% by weight based on the weight of the elastomer compatible material in the bundle. The impregnating or coating composition may also include an anchoring agent in the form of an organo silicon compound which serves to anchor the fibres more securely to elastomeric materials. In an Example a strand of glass fibres is passed through a bath containing a natural rubber latex and resorcinol formaldehyde resin, and through a roller to remove excess impregnating composition, dried and then coated with a solution of a retarder by roller coating. The retarder solution comprises a solution of N-nitroso diphenylamine dissolved in acetone.
GB1109572A 1971-03-09 1972-03-09 Reinforcement for elastomeric material Expired GB1393104A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12239471A 1971-03-09 1971-03-09

Publications (1)

Publication Number Publication Date
GB1393104A true GB1393104A (en) 1975-05-07

Family

ID=22402459

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1109572A Expired GB1393104A (en) 1971-03-09 1972-03-09 Reinforcement for elastomeric material

Country Status (9)

Country Link
US (1) US3793130A (en)
JP (1) JPS5343985B1 (en)
BE (1) BE780371A (en)
BR (1) BR7201290D0 (en)
CA (1) CA983369A (en)
DE (1) DE2209082A1 (en)
FR (1) FR2128732B1 (en)
GB (1) GB1393104A (en)
NL (1) NL7203020A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2924602A1 (en) * 1979-02-02 1980-08-14 Ppg Industries Inc COMPOSITE THREAD
GB2435262A (en) * 2006-02-16 2007-08-22 Ngf Europ Ltd Reinforcing rubber articles

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4216856A (en) * 1975-04-25 1980-08-12 Dunlop Limited Reinforcement for elastomeric articles
GB1524232A (en) * 1975-07-24 1978-09-06 Pilkington Brothers Ltd Glass fibres for use as reinforcement in cement products
JPS5228580A (en) * 1975-08-29 1977-03-03 Honny Chem Ind Co Ltd Method for adhering metals with rubbers
JPS5782578A (en) * 1980-11-11 1982-05-24 Unitika Ltd Production of polyester fiber having good adhesion with rubbers
US4923517A (en) * 1987-09-17 1990-05-08 Exxon Research And Engineering Company Glass fiber reinforced cement compositions
US5173141A (en) * 1988-05-25 1992-12-22 Minnesota Mining And Manufacturing Company Preparing tape having improved tear strength
US5079066A (en) * 1988-05-25 1992-01-07 Minnesota Mining And Manufacturing Company Tape having improved tear strength
JPH0618951B2 (en) * 1989-07-17 1994-03-16 チッソ株式会社 Method for producing polyolefin-based thermoplastic elastomer composition
US5145544A (en) * 1989-08-01 1992-09-08 Minnesota Mining And Manufacturing Company Method for preparing tape having improved tear strength
US5260111A (en) * 1991-08-08 1993-11-09 Bridgestone Corporation Thermoplastic films for heat seaming roof sheeting and method for covering roofs
JP3565036B2 (en) * 1998-07-30 2004-09-15 豊田合成株式会社 Brake hose
EP1137694A1 (en) 1998-10-15 2001-10-04 N.V. Bekaert S.A. Coated metal reinforcement element and coating methods
DE10026761C1 (en) * 2000-05-30 2002-01-10 Daimler Chrysler Ag Process for recycling fiber composite materials
JP5118299B2 (en) * 2005-12-13 2013-01-16 オーシーヴィー インテレクチュアル キャピタル エルエルシー Glass fiber for rubber product reinforcement

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1844943A (en) * 1928-10-27 1932-02-16 Naugatuck Chem Co Treatment of rubber
US2100085A (en) * 1932-01-05 1937-11-23 Us Rubber Co Production of vulcanized rubber
US2577843A (en) * 1943-03-08 1951-12-11 Dayton Rubber Company Method of manufacturing wire cord
US2773795A (en) * 1953-01-05 1956-12-11 Phillips Petroleum Co Rubber-fabric laminates and method of making same
US2974062A (en) * 1956-02-14 1961-03-07 Owens Corning Fiberglass Corp Epoxy-glass fiber systems and method for improving the bonding relation therebetween
US2953549A (en) * 1957-02-01 1960-09-20 Exxon Research Engineering Co Preparation and recovery of modified rubbery copolymers
BE599957A (en) * 1958-11-26 1900-01-01
US3258388A (en) * 1962-08-31 1966-06-28 Lord Corp Adhesive composition for bonding rubber to metal
FR1414295A (en) * 1963-11-13 1965-10-15 Dunlop Rubber Co Improvements in the bonding of textile materials to rubbers
US3367793A (en) * 1964-01-15 1968-02-06 Burlington Industries Inc Coated glass textile and process of making same
US3384613A (en) * 1964-08-20 1968-05-21 Goodyear Tire & Rubber Retardation of scorch in rubber compounds containing dicumyl peroxide as the vulcanizing agent
US3410749A (en) * 1964-11-12 1968-11-12 Uniroyal Inc Adhesion of polyester cords to elastomers
US3432332A (en) * 1965-01-21 1969-03-11 Owens Corning Fiberglass Corp Method for the impregnation of fibrous glass
US3419463A (en) * 1965-11-12 1968-12-31 Celanese Corp Adhesion of polyester to rubber
US3437610A (en) * 1965-12-27 1969-04-08 Koppers Co Inc Resorcinol-aldehyde resin and polyester tire cord adhesive made therefrom
DE1811467A1 (en) * 1968-11-28 1970-06-18 Henkel & Cie Gmbh Process for coating strand-like structures with adhesion promoters for rubber
US3591357A (en) * 1969-08-13 1971-07-06 Owens Corning Fiberglass Corp Method for treating and impregnating glass fiber bundles for reinforcement of elastomeric materials

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2924602A1 (en) * 1979-02-02 1980-08-14 Ppg Industries Inc COMPOSITE THREAD
GB2435262A (en) * 2006-02-16 2007-08-22 Ngf Europ Ltd Reinforcing rubber articles
WO2007093770A2 (en) 2006-02-16 2007-08-23 Ngf Europe Limited Method. coating latex and reinforcing cord for forming a rubber article by extrusion or moulding
WO2007093770A3 (en) * 2006-02-16 2007-11-15 Ngf Europ Ltd Method. coating latex and reinforcing cord for forming a rubber article by extrusion or moulding
GB2435262B (en) * 2006-02-16 2011-08-31 Ngf Europ Ltd Method, composition and articles

Also Published As

Publication number Publication date
CA983369A (en) 1976-02-10
BR7201290D0 (en) 1973-06-14
US3793130A (en) 1974-02-19
NL7203020A (en) 1972-09-12
FR2128732A1 (en) 1972-10-20
DE2209082A1 (en) 1972-09-14
BE780371A (en) 1972-07-03
JPS5343985B1 (en) 1978-11-24
FR2128732B1 (en) 1976-08-06

Similar Documents

Publication Publication Date Title
GB1393104A (en) Reinforcement for elastomeric material
US3190764A (en) Method of bonding a rubbery composition to a reinforcing element
US3247043A (en) Adhesion of a reinforcing element to a rubbery composition
US3591357A (en) Method for treating and impregnating glass fiber bundles for reinforcement of elastomeric materials
US4915739A (en) Modified carbon fiber reinforced cement
US3085027A (en) Polyurethane coated fabric filled with isocyanate free elastomer and method of making same
US3968295A (en) Preparation of rubberized cord fabric
US2349290A (en) Method of improving the adhesion of nylon to rubber
IE42355B1 (en) Aromatic polyamide fibre reinforcement of rubber
ES461321A1 (en) Adhesive-coating composition for organic or mineral filaments
US3143405A (en) Method of producing polyamide coated glass fibers
US3642518A (en) Treatment of polyester materials
US3256137A (en) Adhering textile materials to rubber
US2927051A (en) Bonding textiles to rubbers with resorcinol and diaryl guanidinine formaldehyde reaction product
US4572863A (en) Aqueous polyester/epoxy emulsion treatment for yarn, method of preparation and a rubber/cord composite
GB1181482A (en) Adhering Textiles to Rubber
US3212955A (en) Tire cord bonding with polymethylolmelamine resins
CN101654527A (en) Production process of glass fiber cord for rubber reinforcement
US3318750A (en) Method of reinforcing rubber articles with an adhesive composition comprising the reaction product of an aldehyde with the reaction product of trialkyl cyanurate with a polyhydric phenol
US5403661A (en) Preadhered melt spun spin-drawn polyester filaments
US3783001A (en) Treated glass fibers for glass fiber-elastomeric products and method
US3684470A (en) Method for treating glass fibers
US3446003A (en) Glass fiber cord construction
GB1486746A (en) Reinforcing yarns
US3661692A (en) Coated fabrics

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees