GB1390115A - Benzofuran derivatives as plant growth regulants - Google Patents
Benzofuran derivatives as plant growth regulantsInfo
- Publication number
- GB1390115A GB1390115A GB3717472A GB3717472A GB1390115A GB 1390115 A GB1390115 A GB 1390115A GB 3717472 A GB3717472 A GB 3717472A GB 3717472 A GB3717472 A GB 3717472A GB 1390115 A GB1390115 A GB 1390115A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- plant growth
- methylbenzo
- furan
- aug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/82—Benzo [b] furans; Hydrogenated benzo [b] furans with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
- C07D307/84—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1390115 Benzofuran derivatives SHELL INTERNATIONALE RESEARCH MAATSOHAPPIJ BV 9 Aug 1973 [9 Aug 1972] 37174/72 Heading C2C Novel compounds have the Formula I wherein R 1 represents a carboxy group or a salt, ester, or an optionally mono- or di-N- alkyl substituted amide thereof; R 2 represents an alkyl group; and R 3 represents a hydrogen atom or an acyloxy group; with the proviso that when R 3 represents a hydrogen atom R 1 does not represent a carboxy group. Examples prepare (1) 2-methylbenzo(b)furan 3-carboxylic acid by the action of Br 2 /NaOH on the corresponding 3-acetyl derivative, (2) the methyl and ethyl esters of this acid using SOCl 2 and methanol or ethanol respectively on the latter, (3) the amide, N-methylamide and N,N- dimethylamide of the same acid by C.NH 3 , CH 3 NH 2 or (CH 3 ) 2 NH on the corresponding acid chloride, and (4) the tetramethylammonium salt of said acid by neutralization of the latter with the corresponding quaternary ammonium hydroxide. Also prepared from ethyl 5-hydroxy-2- methylbenzo(b)furan - 3 - carboxylate are the corresponding 5 - acetoxy, 5 - benzoyloxy, 5 - (N - methylcarbamoyloxy) and 5 - (N - 3,4- dichlorophenylcarbamoyloxy) derivatives using respectively acetic anhydride, benzoyl chloride, methyl isocyanate, and 3,4-dichlorophenylisocyanate. The compounds of Formula I, including those wherein R 3 is hydrogen and R 1 is carboxy, possess plant growth regulant properties.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3717472A GB1390115A (en) | 1972-08-09 | 1972-08-09 | Benzofuran derivatives as plant growth regulants |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3717472A GB1390115A (en) | 1972-08-09 | 1972-08-09 | Benzofuran derivatives as plant growth regulants |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1390115A true GB1390115A (en) | 1975-04-09 |
Family
ID=10394376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3717472A Expired GB1390115A (en) | 1972-08-09 | 1972-08-09 | Benzofuran derivatives as plant growth regulants |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1390115A (en) |
-
1972
- 1972-08-09 GB GB3717472A patent/GB1390115A/en not_active Expired
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |