GB1387593A - Dithiophosphorylacetic acid esters and the preparation of dithiophosphoryl acetic acid amides - Google Patents
Dithiophosphorylacetic acid esters and the preparation of dithiophosphoryl acetic acid amidesInfo
- Publication number
- GB1387593A GB1387593A GB1334672A GB1334672A GB1387593A GB 1387593 A GB1387593 A GB 1387593A GB 1334672 A GB1334672 A GB 1334672A GB 1334672 A GB1334672 A GB 1334672A GB 1387593 A GB1387593 A GB 1387593A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- preparation
- reacting
- alkyl
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical class CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 title 1
- 150000002148 esters Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 abstract 1
- VGCXGMAHQTYDJK-UHFFFAOYSA-N Chloroacetyl chloride Chemical compound ClCC(Cl)=O VGCXGMAHQTYDJK-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical class OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
1387593 Dithiophosphoric acid esters HOECHST AG 22 March 1972 [23 March 1971] 13346/72 Headings C2P and C2C Compounds of Formula II where R and R<SP>1</SP> are C 1-4 alkyl, R 1 is hydrogen of C 1-4 alkyl and R 2 is C 1-4 alkyl or C 2-7 alkoxyalkyl or R 1 and R 2 together with the N atom are alkylene-imino having 4 to 6 carbon atoms, one of which may be replaced by oxygen, are prepared by reacting a compound of Formula III with an alkali metal or ammonium salt of an O,O-dialkyldithiophosphoric acid to form an intermediate of Formula I and reacting this intermediate, with or without isolation, with an amine of formula The compounds of Formula I are claimed per se. The compounds of Formula II have pesticidal properties. The starting material, di-(4-chloroacetoxypheyl)-sulphone, is prepared by reacting di- (4-hydroxyphenyl)-sulphone with chloroacetyl chloride.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2113979A DE2113979C3 (en) | 1971-03-23 | 1971-03-23 | Process for the preparation of 0,0-dialkyl-dithiophosphoryl-acetic acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1387593A true GB1387593A (en) | 1975-03-19 |
Family
ID=5802460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1334672A Expired GB1387593A (en) | 1971-03-23 | 1972-03-22 | Dithiophosphorylacetic acid esters and the preparation of dithiophosphoryl acetic acid amides |
Country Status (13)
| Country | Link |
|---|---|
| AT (1) | AT311996B (en) |
| BE (1) | BE781136A (en) |
| CA (1) | CA958413A (en) |
| CH (1) | CH566348A5 (en) |
| DD (1) | DD95229A5 (en) |
| DE (1) | DE2113979C3 (en) |
| DK (1) | DK134068C (en) |
| FR (1) | FR2130593B1 (en) |
| GB (1) | GB1387593A (en) |
| IL (1) | IL39030A (en) |
| IT (1) | IT953536B (en) |
| NL (1) | NL7203601A (en) |
| SU (1) | SU422162A3 (en) |
-
1971
- 1971-03-23 DE DE2113979A patent/DE2113979C3/en not_active Expired
-
1972
- 1972-03-13 DD DD161499A patent/DD95229A5/xx unknown
- 1972-03-17 NL NL7203601A patent/NL7203601A/xx unknown
- 1972-03-20 IL IL39030A patent/IL39030A/en unknown
- 1972-03-20 CH CH410272A patent/CH566348A5/xx not_active IP Right Cessation
- 1972-03-21 IT IT22179/72A patent/IT953536B/en active
- 1972-03-21 AT AT240872A patent/AT311996B/en not_active IP Right Cessation
- 1972-03-22 CA CA137,765A patent/CA958413A/en not_active Expired
- 1972-03-22 SU SU1762979A patent/SU422162A3/en active
- 1972-03-22 DK DK137172A patent/DK134068C/en active
- 1972-03-22 GB GB1334672A patent/GB1387593A/en not_active Expired
- 1972-03-23 FR FR7210186A patent/FR2130593B1/fr not_active Expired
- 1972-03-23 BE BE781136A patent/BE781136A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE2113979A1 (en) | 1972-10-05 |
| DE2113979B2 (en) | 1979-02-22 |
| DD95229A5 (en) | 1973-01-20 |
| IL39030A0 (en) | 1972-05-30 |
| CA958413A (en) | 1974-11-26 |
| DE2113979C3 (en) | 1979-10-31 |
| SU422162A3 (en) | 1974-03-30 |
| NL7203601A (en) | 1972-09-26 |
| DK134068B (en) | 1976-09-06 |
| AT311996B (en) | 1973-12-10 |
| IT953536B (en) | 1973-08-10 |
| FR2130593B1 (en) | 1977-12-23 |
| BE781136A (en) | 1972-09-25 |
| FR2130593A1 (en) | 1972-11-03 |
| CH566348A5 (en) | 1975-09-15 |
| DK134068C (en) | 1977-03-28 |
| IL39030A (en) | 1974-09-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |