GB1386661A - Emulsion polymerization of vinyl monomers - Google Patents
Emulsion polymerization of vinyl monomersInfo
- Publication number
- GB1386661A GB1386661A GB1530872A GB1530872A GB1386661A GB 1386661 A GB1386661 A GB 1386661A GB 1530872 A GB1530872 A GB 1530872A GB 1530872 A GB1530872 A GB 1530872A GB 1386661 A GB1386661 A GB 1386661A
- Authority
- GB
- United Kingdom
- Prior art keywords
- examples
- methacrylate
- styrene
- butyl
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000178 monomer Substances 0.000 title abstract 5
- 238000007720 emulsion polymerization reaction Methods 0.000 title abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract 3
- 229920002554 vinyl polymer Polymers 0.000 title abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 10
- 239000003995 emulsifying agent Substances 0.000 abstract 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 5
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 abstract 4
- 239000004159 Potassium persulphate Substances 0.000 abstract 4
- 229920001577 copolymer Polymers 0.000 abstract 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 4
- 235000019394 potassium persulphate Nutrition 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 3
- 239000003973 paint Substances 0.000 abstract 3
- 229920002857 polybutadiene Polymers 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 239000004160 Ammonium persulphate Substances 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- 239000005062 Polybutadiene Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 2
- 229920000126 latex Polymers 0.000 abstract 2
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 abstract 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 abstract 1
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical class [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 abstract 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 1
- 238000007142 ring opening reaction Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP46021281A JPS4943381B1 (cg-RX-API-DMAC7.html) | 1971-04-05 | 1971-04-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1386661A true GB1386661A (en) | 1975-03-12 |
Family
ID=12050735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1530872A Expired GB1386661A (en) | 1971-04-05 | 1972-04-04 | Emulsion polymerization of vinyl monomers |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS4943381B1 (cg-RX-API-DMAC7.html) |
| CA (1) | CA951047A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2216175C3 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2136180A5 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1386661A (cg-RX-API-DMAC7.html) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5922723B2 (ja) * | 1975-10-23 | 1984-05-29 | 関西ペイント株式会社 | エマルジヨンソセイブツ |
-
1971
- 1971-04-05 JP JP46021281A patent/JPS4943381B1/ja active Pending
-
1972
- 1972-04-04 DE DE19722216175 patent/DE2216175C3/de not_active Expired
- 1972-04-04 GB GB1530872A patent/GB1386661A/en not_active Expired
- 1972-04-04 CA CA138,835,A patent/CA951047A/en not_active Expired
- 1972-04-05 FR FR7211905A patent/FR2136180A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4943381B1 (cg-RX-API-DMAC7.html) | 1974-11-20 |
| DE2216175B2 (de) | 1975-02-06 |
| CA951047A (en) | 1974-07-09 |
| DE2216175C3 (de) | 1975-10-02 |
| DE2216175A1 (de) | 1972-10-19 |
| FR2136180A5 (cg-RX-API-DMAC7.html) | 1972-12-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1468398A (en) | Polymeric pigments and method for preparation thereof | |
| US3644584A (en) | Graft copolymers bearing at least two unlike types of graft components | |
| US4173596A (en) | Soft-seeded tougheners for polyvinyl chloride | |
| GB1476703A (en) | Continuous mass polymerization process | |
| US3742092A (en) | Methacrylonitrile polymerization process | |
| GB1439010A (en) | Polymeric compositions and process for their manufacture | |
| US3438926A (en) | Water base unsaturated interpolymer coatings | |
| US2388373A (en) | Catalysts for the addition polymerization of unsaturated organic compounds | |
| GB1476702A (en) | Continuous mass polymerization process | |
| GB1477246A (en) | High impact polyblends from hydrogenated substrates | |
| ES475224A1 (es) | Procedimiento de polimerizacion o de copolimerizacion anio- nica de monomeros vinilicos, dienicos y heterociclicos | |
| EP1523510A2 (en) | Method for polymerizing ethylenically unsaturated monomers by degenerative iodine transfer | |
| US4594387A (en) | Thermoplastic resin composition having toughness and high thermal deformation resistance | |
| GB1313086A (en) | Styrene-butadiene graft polymers processes for their preparation and mixtures thereof with polyvinylchloride | |
| US3483174A (en) | Process for coagulating latices of copolymers and terpolymers of conjugated dienes and carboxylic acids | |
| AU766724B2 (en) | Bimodal rubbers and rubber modified high impact monovinylidene aromatic polymers produced therefrom | |
| ATE455136T1 (de) | Thermostabile vinylchlorid-mischpolymerisate | |
| JPS5523144A (en) | Vinyl chloride resin composition | |
| GB1435605A (en) | Polymerisation process | |
| AU717145B2 (en) | Simplified bimodal process | |
| US3887651A (en) | Process for preparing copolymer | |
| JPH04209611A (ja) | スチレン系樹脂組成物 | |
| JPS5861108A (ja) | 熱可塑性樹脂の製造方法 | |
| US5654361A (en) | Plastisols containing anionic polymers | |
| GB1508094A (en) | Acrylonitrile containing impact resistant polymers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |