GB1386630A - Sulphur-containing amino acids and their use in photographic materials - Google Patents
Sulphur-containing amino acids and their use in photographic materialsInfo
- Publication number
- GB1386630A GB1386630A GB3248572A GB3248572A GB1386630A GB 1386630 A GB1386630 A GB 1386630A GB 3248572 A GB3248572 A GB 3248572A GB 3248572 A GB3248572 A GB 3248572A GB 1386630 A GB1386630 A GB 1386630A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- lower alkyl
- alkyl group
- hydrogen atom
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 2
- 239000005864 Sulphur Substances 0.000 title abstract 2
- 150000001413 amino acids Chemical class 0.000 title abstract 2
- 239000000463 material Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 5
- -1 silver halide Chemical class 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 150000001447 alkali salts Chemical class 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000012458 free base Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
- G03C1/346—Organic derivatives of bivalent sulfur, selenium or tellurium
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1386630 Sulphur-containing amino acids ILFORD Ltd 12 July 1973 [12 July 1972] 32485/70 Heading C2C [Also in Division G2] New compounds, which reduce the tendency of silver halide emulsions to exhibit latent image regression have the formula wherein R 1 is a hydrogen atom, or a lower alkyl group, an acyl group, an alkoxycarbonyl group, an aralkoxycarbonyl group, an acyloxycarbonyl group or an aryloxycarbonyl group, R 2 is a hydrogen atom or a lower alkyl group, R 3 is a hydrogen atom or a lower alkyl group, R 4 is a lower alkyl group, R 5 is a hydrogen atom or a lower alkyl group, Y is a straight or branched alkylene chain having from 1 to 6 carbon atoms, X is an anion and n is 0 or 1, R 6 is a hydrogen atom or a lower alkyl group, an aralkyl group or an alkali metal cation but when n is 1, R 6 may not be an alkali metal cation. Those compounds which are salts are made by reacting an amine salt of formula with a compound of formula The basic salt or free base may be prepared from the above product in the usual way. The Specification also describes the preparation of the following intermediates (1) 2-phenyl-4-npropylidene-5-oxazolone, (2) α-benzoylamino- #-benzylmercapto-n-valeric acid and (3) α- amino-#-benzylmercapto-n-valeric acid and its hydrochloride.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3248572A GB1386630A (en) | 1972-07-12 | 1972-07-12 | Sulphur-containing amino acids and their use in photographic materials |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3248572A GB1386630A (en) | 1972-07-12 | 1972-07-12 | Sulphur-containing amino acids and their use in photographic materials |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1386630A true GB1386630A (en) | 1975-03-12 |
Family
ID=10339308
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3248572A Expired GB1386630A (en) | 1972-07-12 | 1972-07-12 | Sulphur-containing amino acids and their use in photographic materials |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1386630A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2307292A1 (en) * | 1975-04-09 | 1976-11-05 | Agfa Gevaert | PRODUCTION OF PHOTOGRAPHIC SILVER HALOGENIDE EMULSIONS |
US4314024A (en) | 1979-08-04 | 1982-02-02 | Agfa-Gevaert Aktiengesellschaft | Stabilized photographic emulsion, a process for its preparation and stabilized photographic materials |
-
1972
- 1972-07-12 GB GB3248572A patent/GB1386630A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2307292A1 (en) * | 1975-04-09 | 1976-11-05 | Agfa Gevaert | PRODUCTION OF PHOTOGRAPHIC SILVER HALOGENIDE EMULSIONS |
US4314024A (en) | 1979-08-04 | 1982-02-02 | Agfa-Gevaert Aktiengesellschaft | Stabilized photographic emulsion, a process for its preparation and stabilized photographic materials |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |