GB1384176A - Process for preventing the staining of polyamide fibre material treated with fluorescent whiteners - Google Patents

Process for preventing the staining of polyamide fibre material treated with fluorescent whiteners

Info

Publication number
GB1384176A
GB1384176A GB2592772A GB2592772A GB1384176A GB 1384176 A GB1384176 A GB 1384176A GB 2592772 A GB2592772 A GB 2592772A GB 2592772 A GB2592772 A GB 2592772A GB 1384176 A GB1384176 A GB 1384176A
Authority
GB
United Kingdom
Prior art keywords
fixing agent
bis
compounds
nylon
whitener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2592772A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB1384176A publication Critical patent/GB1384176A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
    • D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
    • D06P1/928—Solvents other than hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • D06L4/679—Fixing treatments in optical brightening, e.g. heating, steaming or acid shock
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/622—Sulfonic acids or their salts
    • D06P1/625—Aromatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
    • D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
    • D06P1/922—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents hydrocarbons

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)

Abstract

1384176 Stain-proofing optically brightened materials CIBA-GEIGY AG 2 June 1972 [7 June 1971] 25927/72 Heading D1P Synthetic polyamide material, e.g. yarns and textiles, which has been treated with fluorescent whiteners is proofed against staining, i.e. the pick up of dyes, e.g. during laundry, by the application of a water-soluble fixing agent dispersed in an organic liquid containing up to 10% of water at a temperature of 20 to 120‹C. The fixing agent may be applied simultaneously with the fluorescent whitener or at a later stage. The treated materials may be partly or wholly composed of nylon 6, nylon 66, nylon 6, 10, nylon 11 or nylon 6, 6/6. Preferably the fixing agent is accompanied by an organo-soluble surfactant acting as a dispersing agent. The fixing agent is preferably a condensation polymer of one or more aryl compounds with formaldehyde, suitable aryl compounds are sulphones, especially diaryl sulphones having at least one phenoline group, and sulphonated aryl compounds. In example 1 4, 4' dihydroxydiphenylsulphone is sulphonated with concentrated sulphuric acid and then condensed with formaldehyde. Many dispersing agents are specified, in particular nonionic or anionic compounds obtained by the addition of ethylene oxide to long chain amines or alcohols or to phenols or fatty acid esters. The fluorescent whitener is preferably watersoluble. Specified classes of whitener are mono or di (sulphonic acid, sulphonamide or carboxylic acid) substituted 4, 4' bis (acylamino) stilbenes, 4, 4' bis-(triazinylamino)-stilbenes 4, 4' bis-(azoyl) stilbenes, stilbylnaphthatriazoles, bis- (benzoxazol-2-yl)-derivatives, monomethine cyanines, 2, 7-bis (aroylamino)-dibenzothiophene dioxides-1, 3 diarylpyrazolines, styrylbenzoxazoles, bis-styrylaryl compounds, bisbenzoxazolylarylene compounds, oxdiazole compounds or quaternary benzofuranylbenzimidazoles. Examples 1-3 disclose the simultaneous application of a solution of a fluorescent whitener and a dispersion of a fixing agent solution in a single organic solvent. Example 4 discloses treatment of polyamide filament yarn with fluorescent whitener in trichloroethylene followed by the application of fixing agent dispersed in benzene. It is also possible to apply an aqueous solution of the whitener, dry the fabric and apply fixing agent dispersed in an organic solvent. 0.1% to 10% by weight of fixing agent relative to the fibre material is used. The ratio of fixing agent to dispersing agent is between 1:100 and 1:2. Padding and exhaust processes may be used.
GB2592772A 1971-06-07 1972-06-02 Process for preventing the staining of polyamide fibre material treated with fluorescent whiteners Expired GB1384176A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH827471 1971-06-07

Publications (1)

Publication Number Publication Date
GB1384176A true GB1384176A (en) 1975-02-19

Family

ID=4337811

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2592772A Expired GB1384176A (en) 1971-06-07 1972-06-02 Process for preventing the staining of polyamide fibre material treated with fluorescent whiteners

Country Status (11)

Country Link
US (1) US3849162A (en)
AT (1) AT321859B (en)
BE (1) BE784446A (en)
CA (1) CA973659A (en)
CH (1) CH827471A4 (en)
DE (1) DE2226243A1 (en)
FR (1) FR2140449A1 (en)
GB (1) GB1384176A (en)
IT (1) IT958207B (en)
NL (1) NL7207666A (en)
ZA (1) ZA723582B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5438605B2 (en) * 1974-06-07 1979-11-22
US4592940A (en) * 1983-12-16 1986-06-03 Monsanto Company Stain-resistant nylon carpets impregnated with condensation product of formaldehyde with mixture of diphenolsulfone and phenolsulfonic acid
DE3673008D1 (en) * 1983-12-16 1990-08-30 Monsanto Co Stain-resistant NYLON CARPETS.
US4619853A (en) * 1983-12-21 1986-10-28 Monsanto Company Easy-clean carpets which are stain resistant and water impervious
EP0242496B1 (en) * 1986-03-06 1991-12-27 Monsanto Company Stain-resistant nylon fibers
US4839212A (en) * 1986-03-06 1989-06-13 Monsanto Company Stain resistant nylon carpets
US4879180A (en) * 1986-03-06 1989-11-07 Monsanto Company Stain-resistant nylon fibers
US4800118A (en) * 1987-11-04 1989-01-24 West Point Pepperell Compositions and methods for imparting stain resistance to textile articles
US5520962A (en) * 1995-02-13 1996-05-28 Shaw Industries, Inc. Method and composition for increasing repellency on carpet and carpet yarn
US7335234B2 (en) * 2002-10-16 2008-02-26 Columbia Insurance Company Method of treating fibers, carpet yarns and carpets to enhance repellency
JP5653160B2 (en) * 2010-10-15 2015-01-14 ダンロップスポーツ株式会社 Golf ball

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH3710A (en) * 1891-06-11 1891-12-15 G Daverio New roller bearing regulating device on three-roller mills
CH7796A (en) * 1893-10-30 1894-06-30 Scudder Wilbur Stefan Die setting and stereotype line casting machine
CH12362A (en) * 1896-04-24 1896-12-15 Abraham Weil Press for the production of roof panels
GB715919A (en) * 1952-03-24 1954-09-22 Ici Ltd Process for improving the fastness of dyeings
CH446261A (en) * 1960-06-02 1968-03-15 Ciba Geigy Process for the optical brightening of textile fibers
DE1155088B (en) * 1960-11-02 1963-10-03 Basf Ag Process for coloring, printing and / or optical brightening of textile goods
DE1159899B (en) * 1961-02-04 1963-12-27 Basf Ag Process for dyeing or printing textile goods
GB978523A (en) * 1961-08-25 1964-12-23 Hooker Chemical Corp Benzene catalytic oxychlorination
US3182059A (en) * 1961-12-29 1965-05-04 Daito Chemical Industry Compan Method of preparing halogenomethylated derivative of alpha, beta-(aryloxazolyl-(2)-ethylene-onium compound
BE637209A (en) * 1962-09-18
DE1444015A1 (en) * 1963-08-10 1969-10-09 Bayer Ag Bis-triazinylaminostilbene-disulfonic acid compounds
FR1479071A (en) * 1965-05-10 1967-07-19
FR1535352A (en) * 1966-09-01 1968-08-02 Henkel & Cie Gmbh Process for dyeing a fibrous material in organic solvents
US3485761A (en) * 1967-02-15 1969-12-23 Procter & Gamble Production of detergent compositions containing finely dispersed optical brighteners
US3490860A (en) * 1967-09-05 1970-01-20 Geigy Ag J R Process for aftertreatment of freshly colored polyamide fibers

Also Published As

Publication number Publication date
US3849162A (en) 1974-11-19
ZA723582B (en) 1973-03-28
CA973659A (en) 1975-09-02
CH827471A4 (en) 1975-11-28
DE2226243A1 (en) 1973-01-04
FR2140449A1 (en) 1973-01-19
NL7207666A (en) 1972-12-11
IT958207B (en) 1973-10-20
BE784446A (en) 1972-12-06
AT321859B (en) 1975-04-25

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees