GB1379847A - Method of preparing a hydrorefining catalyst - Google Patents
Method of preparing a hydrorefining catalystInfo
- Publication number
- GB1379847A GB1379847A GB1381972A GB1381972A GB1379847A GB 1379847 A GB1379847 A GB 1379847A GB 1381972 A GB1381972 A GB 1381972A GB 1381972 A GB1381972 A GB 1381972A GB 1379847 A GB1379847 A GB 1379847A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- hours
- period
- average pore
- weight per
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1379847 Hydrocarbon hydrorefining catalysts UNIVERSAL OIL PRODUCTS CO 24 March 1972 [25 March 1971] 13819/72 Heading B1E [Also in Division C5] Hydrocarbon hydrorefining catalyst comprising a Group VIB metal component and a Group VIII metal component is prepared by a method wherein refractory inorganic oxide carrier material is impregnated with an aqueous solution containing a soluble compound of a Group VIB metal and a soluble compound of a Group VIII metal and, after evaporating water therefrom, is calcined initially at a temperature of from 100 to 427‹C (212 to 800‹F) for a period of at least ¢ hour (for example at a temperature of from 260 to 427‹C (500 to 800‹F) for a period of from ¢ to 2 hours in an atmosphere containing less than 50 volume per cent steam, preferably substantially dry air) and thereafter at a temperature of from 427 to 621‹C (800 to 1150‹F) for a period of from 1 to 4 hours in an atmosphere containing at least 25, preferably from 60 to 80, volume per cent steam, the volume ratio of impregnating solution to carrier material being from 0.5:1 to 2:1, preferably from 0.6:1 to 1:1, for example about 0.7:1. Evaporation of water, which preferably is such as to provide material which exhibits a loss on ignition at 500‹C of less than 50, preferably from 35 to 45, weight per cent, may be effected for a period not greater than 4 hours. The refractory inorganic oxide carrier material may be alumina, silica, zirconia, boria, thoria or a combination thereof, for example silica-alumina having an Al 2 O 3 :SiO 2 molar ratio of at least 1:1, preferably an Al 2 O 3 :SiO 2 weight ratio of from 3:1 to 9:1; the carrier material preferably has a surface area of from 175 to 380m<SP>2</SP>/g, an average pore volume of from 0.5 to 0.9 ml/g and an average pore diameter of from 70 to 200 Angstroms. The metal of the Group VIB metal component may be selected from chromium, molybdenum and tungsten; the metal of the Group VIII metal component may be selected from iron, cobalt, nickel, ruthenium, rhodium. palladium, osmium, iridium and platinum; the Specification gives examples of suitable Group VIB metal compounds and Group VIII metal compounds for use in the preparation of the catalyst which may contain from 5 to 20 weight per cent molybdenum and from 0.1 to 10 weight per cent nickel. As exemplified, 1.6 mm spheres of silica-alumina containing 88 weight per cent Al 2 O 3 and 12 weight per cent SiO 2 and having a surface area of 285 m<SP>2</SP>/g, an average pore volume of 0.7 ml/g and an average bulk density of 0.44 g/ml are impregnated with a solution prepared by dissolving molybdic acid and nickel nitrate in aqueous ammonia and, after evaporating water therefrom over a period of 4 hours, are calcined initially at 343‹C (650‹F) for 1 hour in dry air and thereafter at 552‹C (1025‹F) for 2 hours in air containing 70 volume per cent steam to provide material haying a surface area of 150 m<SP>2</SP>/g, an average pore volume of 0.45 ml/g and an average pore diameter of 115 Angstroms, which material is used in the form of a plurality of beds separated by sand in a process for hydrorefining a residual crude oil.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12811471A | 1971-03-25 | 1971-03-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1379847A true GB1379847A (en) | 1975-01-08 |
Family
ID=22433707
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1381972A Expired GB1379847A (en) | 1971-03-25 | 1972-03-24 | Method of preparing a hydrorefining catalyst |
Country Status (14)
Country | Link |
---|---|
JP (1) | JPS5229717B1 (en) |
AU (1) | AU459131B2 (en) |
BR (1) | BR7201734D0 (en) |
CA (1) | CA986496A (en) |
DE (1) | DE2214207B2 (en) |
ES (1) | ES401056A1 (en) |
FR (1) | FR2130711B1 (en) |
GB (1) | GB1379847A (en) |
IT (1) | IT952359B (en) |
NL (1) | NL161371C (en) |
PL (1) | PL83329B1 (en) |
SE (1) | SE384802B (en) |
YU (1) | YU34627B (en) |
ZA (1) | ZA721900B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1386665A1 (en) * | 2002-08-01 | 2004-02-04 | Conoco Phillips Company | Hydrothermal pretreatment for increasing average pore size in catalyst supports |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53149412U (en) * | 1977-04-30 | 1978-11-24 | ||
FR2424577A1 (en) * | 1978-02-24 | 1979-11-23 | Scholtes Ets Eugen | Convector heaters network temp. controller - has programmable clock monitoring changeover with master control circuit operating with individual heater controllers |
-
1972
- 1972-03-20 ZA ZA721900A patent/ZA721900B/en unknown
- 1972-03-20 CA CA137,535A patent/CA986496A/en not_active Expired
- 1972-03-21 YU YU740/72A patent/YU34627B/en unknown
- 1972-03-22 AU AU40258/72A patent/AU459131B2/en not_active Expired
- 1972-03-22 IT IT49177/72A patent/IT952359B/en active
- 1972-03-22 ES ES401056A patent/ES401056A1/en not_active Expired
- 1972-03-23 DE DE19722214207 patent/DE2214207B2/en active Granted
- 1972-03-23 NL NL7203877.A patent/NL161371C/en not_active IP Right Cessation
- 1972-03-24 GB GB1381972A patent/GB1379847A/en not_active Expired
- 1972-03-24 BR BR721734A patent/BR7201734D0/en unknown
- 1972-03-24 FR FR7210543A patent/FR2130711B1/fr not_active Expired
- 1972-03-24 SE SE7203873A patent/SE384802B/en unknown
- 1972-03-24 PL PL1972154304A patent/PL83329B1/pl unknown
- 1972-03-25 JP JP47030232A patent/JPS5229717B1/ja active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1386665A1 (en) * | 2002-08-01 | 2004-02-04 | Conoco Phillips Company | Hydrothermal pretreatment for increasing average pore size in catalyst supports |
US6958309B2 (en) | 2002-08-01 | 2005-10-25 | Conocophillips Company | Hydrothermal pretreatment for increasing average pore size in a catalyst support |
Also Published As
Publication number | Publication date |
---|---|
FR2130711B1 (en) | 1977-08-05 |
BR7201734D0 (en) | 1973-06-14 |
IT952359B (en) | 1973-07-20 |
JPS5229717B1 (en) | 1977-08-03 |
NL161371C (en) | 1980-02-15 |
NL7203877A (en) | 1972-09-27 |
ZA721900B (en) | 1972-12-27 |
PL83329B1 (en) | 1975-12-31 |
ES401056A1 (en) | 1975-07-16 |
FR2130711A1 (en) | 1972-11-03 |
YU34627B (en) | 1979-12-31 |
NL161371B (en) | 1979-09-17 |
AU4025872A (en) | 1973-09-27 |
AU459131B2 (en) | 1975-02-28 |
DE2214207A1 (en) | 1972-10-12 |
SE384802B (en) | 1976-05-24 |
CA986496A (en) | 1976-03-30 |
YU74072A (en) | 1979-07-10 |
DE2214207B2 (en) | 1976-04-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |