GB1377303A - Ampholytic fluoroaliphatic surfactants - Google Patents

Ampholytic fluoroaliphatic surfactants

Info

Publication number
GB1377303A
GB1377303A GB197272A GB197272A GB1377303A GB 1377303 A GB1377303 A GB 1377303A GB 197272 A GB197272 A GB 197272A GB 197272 A GB197272 A GB 197272A GB 1377303 A GB1377303 A GB 1377303A
Authority
GB
United Kingdom
Prior art keywords
fluoroaliphatic
group
carbon atoms
ampholytic
terminal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB197272A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of GB1377303A publication Critical patent/GB1377303A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/16—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
    • C07D213/20—Quaternary compounds thereof
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071—Foams
    • A62D1/0085—Foams containing perfluoroalkyl-terminated surfactant
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/004—Surface-active compounds containing F

Abstract

1377303 Ampholytic fluoroaliphatic compounds MINNESOTA MINING & MFG CO 14 Jan 1972 [18 Jan 1971 9 Sept 1971] 1972/72 Headings C2C and C2P [Also in Division A5] Novel ampholytic fluoroaliphatic surfactants which contain in a single molecule at least one terminal fluoroaliphatic group, at least one terminal quaternary ammonium radical and at least one terminal anionogenic radical or salts thereof and particularly compounds having the general formula in which R<SP>f</SP> represents a fluoroaliphatic group containing 1 to 20 carbon atoms, Z represents an organic linking group, the three R groups each represent like or different unsubstituted alkyl or aralkyl groups containing 1 to 18 carbon atoms or alkyl or aralkyl groups containing 1 to 18 carbon atoms substituted by water-solubilizing groups, or in combination with the nitrogen atom to which they are attached the three R groups represent a heterocyclic group in combination with no more than one lower alkyl group, and A# represents the ion of an acid AH having an ionization constant in water at 25‹ C. of at least 1 Î 10<SP>-6</SP>, e.g. -COO-, -SO 3 -, -OSO 3 -, -PO(OH)O-, -OPO(OH)O- and -PO(Oalk)O-, are made by a variety of known methods. R<SP>f </SP>may contain not more than one H or Cl atom for every two carbons and must be terminated by CF 3 . The products are used in forming fire-fighting foams and for oleophobic coatings. C 8 F 17 SO 2 N#(CH 2 ) 3 N#(CH 3 ) 3 and C 6 F 13 SO 2 N#(CH 2 ) 3 N#(CH 3 ) 3 are prepared by the action of NaOMe on C 8 F 17 SO 2 NH(CH 2 ) 3 N#(CH 3 ) 3 Cl# and C 6 F 13 SO 2 NH(CH 2 ) 3 N#(CH 3 ) 3 Cl# respectively, and C 6 F 13 SO 2 N#C 3 H 6 N#(CH 3 ) 2 CH 2 CH 2 OH and C 6 F 13 SO 2 N#C 3 H 6 N#(CH 3 ) 2 (CH 2 CH 2 O) 2 H by the action of ethylene oxide on C 6 F 13 SO 2 NHC 3 H 6 N(CH 3 ) 2 .
GB197272A 1971-01-18 1972-01-14 Ampholytic fluoroaliphatic surfactants Expired GB1377303A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10757271A 1971-01-18 1971-01-18
US17920671A 1971-09-09 1971-09-09

Publications (1)

Publication Number Publication Date
GB1377303A true GB1377303A (en) 1974-12-11

Family

ID=26804930

Family Applications (1)

Application Number Title Priority Date Filing Date
GB197272A Expired GB1377303A (en) 1971-01-18 1972-01-14 Ampholytic fluoroaliphatic surfactants

Country Status (10)

Country Link
JP (1) JPS5216073B2 (en)
AU (1) AU432809B2 (en)
CA (1) CA974237A (en)
DE (1) DE2165057C3 (en)
FR (1) FR2122918A5 (en)
GB (1) GB1377303A (en)
IL (1) IL38573A (en)
IT (1) IT948233B (en)
NL (1) NL172651B (en)
SE (1) SE406194B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004064928A1 (en) * 2003-01-17 2004-08-05 Labutin, Alexandr Nikolaevich Compound for fighting flammable liquid fires

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA994998A (en) * 1972-03-24 1976-08-17 Roger R. Alm Low surface tension compositions
JPS5128383A (en) * 1973-11-24 1976-03-10 Asahi Denka Kogyo Kk SHOKAZAI
US4264484A (en) 1979-01-24 1981-04-28 Minnesota Mining And Manufacturing Company Carpet treatment
DE3051168C2 (en) * 1979-01-24 1998-08-27 Minnesota Mining & Mfg Soil-resistant treatment of carpets
FR2453145B1 (en) * 1979-04-06 1981-03-27 Ugine Kuhlmann
US4359096A (en) 1980-04-28 1982-11-16 Minnesota Mining And Manufacturing Company Aqueous film-forming foam fire extinguisher
JPS5795408A (en) * 1980-12-05 1982-06-14 Mitsubishi Plastics Ind Ltd Differential forming method for synthetic resin article
US4439329A (en) 1981-12-28 1984-03-27 Ciba-Geigy Corporation Aqueous based fire fighting foam compositions containing hydrocarbyl sulfide terminated oligomer stabilizers
US5127815A (en) * 1989-10-31 1992-07-07 Sekisui Kaseihin Kogyo Kabushiki Kaisha Apparatus for forming finished cups of expanded resin
US5085786A (en) * 1991-01-24 1992-02-04 Minnesota Mining And Manufacturing Company Aqueous film-forming foamable solution useful as fire extinguishing concentrate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004064928A1 (en) * 2003-01-17 2004-08-05 Labutin, Alexandr Nikolaevich Compound for fighting flammable liquid fires

Also Published As

Publication number Publication date
NL172651B (en) 1983-05-02
NL7200241A (en) 1972-07-20
FR2122918A5 (en) 1972-09-01
IL38573A0 (en) 1972-03-28
DE2165057A1 (en) 1972-08-03
CA974237A (en) 1975-09-09
IL38573A (en) 1975-02-10
DE2165057B2 (en) 1979-06-21
AU432809B2 (en) 1973-03-08
JPS4844182A (en) 1973-06-25
AU3802872A (en) 1973-03-08
JPS5216073B2 (en) 1977-05-06
SE406194B (en) 1979-01-29
IT948233B (en) 1973-05-30
DE2165057C3 (en) 1980-02-14

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years