GB1365318A - Method and preparation for crystalline aluminosilicate zeolites - Google Patents
Method and preparation for crystalline aluminosilicate zeolitesInfo
- Publication number
- GB1365318A GB1365318A GB5955971A GB5955971A GB1365318A GB 1365318 A GB1365318 A GB 1365318A GB 5955971 A GB5955971 A GB 5955971A GB 5955971 A GB5955971 A GB 5955971A GB 1365318 A GB1365318 A GB 1365318A
- Authority
- GB
- United Kingdom
- Prior art keywords
- substituted
- alkyl
- cycloalkyl
- aryl
- crystalline aluminosilicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2876—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures from a reacting mixture containing an amine or an organic cation, e.g. a quaternary onium cation-ammonium, phosphonium, stibonium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1365318 Organo-alumino-silicate zeolites MOBIL OIL CORP 22 Dec 1971 [18 March 1971] 59559/71 Heading C1A Crystalline aluminosilicate zeolites which contain organic nitrogen cations are synthesized by crystallization from a reaction mixture containing sources of silica, alumina, alkali, water and two compounds having formulµ R1R2R3N and R4X where R1, R2 and R3 are aryl, substituted aryl, alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl or hydrogen, R4 is aryl, substituted aryl, alkyl, substituted alkyl, cycloalkyl or substituted cycloalkyl and X is an electronegative group. The preferred reaction temperature is 250‹ to 750‹ F. In cases specified R1, R2, R3 and R4 are alkyl groups of C1 to C5 especially ethyl and propyl. In a modification, R1R2R3N is R1R2R4N and R4X is omitted. Certain reaction mixtures are specified, most of the products being members of the ZSM-4, 5, 8, 11 or 12 families.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12589871A | 1971-03-18 | 1971-03-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1365318A true GB1365318A (en) | 1974-08-29 |
Family
ID=22421975
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5955971A Expired GB1365318A (en) | 1971-03-18 | 1971-12-22 | Method and preparation for crystalline aluminosilicate zeolites |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5725490B1 (en) |
AU (1) | AU461375B2 (en) |
CA (1) | CA933911A (en) |
DE (1) | DE2212810C3 (en) |
FR (1) | FR2130430B1 (en) |
GB (1) | GB1365318A (en) |
IT (1) | IT944038B (en) |
NL (1) | NL174453C (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2643929A1 (en) * | 1975-09-29 | 1977-04-14 | Ici Ltd | METHOD OF PRODUCING ZEOLITHES |
EP0002900A1 (en) * | 1977-12-23 | 1979-07-11 | The British Petroleum Company p.l.c. | Method for producing aluminosilicates and their use as catalysts and supports |
EP0011362A1 (en) * | 1978-11-13 | 1980-05-28 | Mobil Oil Corporation | Method for synthesis of zeolite ZSM-5 |
EP0014546A1 (en) * | 1979-02-01 | 1980-08-20 | Mobil Oil Corporation | Preparation of nitrogenous zeolites and zeolites so prepared |
WO1980002026A1 (en) * | 1979-03-28 | 1980-10-02 | Grace W R & Co | A cyclic process for forming high purity zsm-5 catalyst |
US4242233A (en) | 1977-12-23 | 1980-12-30 | The British Petroleum Company Limited | Method for preparing aluminosilicates, their use as catalyst supports and catalysts, and method for producing catalysts therefrom |
EP0023089A1 (en) * | 1979-07-12 | 1981-01-28 | Mobil Oil Corporation | Method of preparing zeolite ZSM-48, the zeolite so prepared and its use as catalyst for organic compound conversion |
EP0030811A1 (en) * | 1979-12-07 | 1981-06-24 | The British Petroleum Company p.l.c. | Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports |
US4376104A (en) * | 1979-01-05 | 1983-03-08 | The British Petroleum Company Limited | Method for preparing crystalline aluminosilicates |
US4377502A (en) * | 1979-12-26 | 1983-03-22 | Standard Oil Company (Indiana) | Synthesis of crystalline aluminosilicate molecular sieves |
US4423021A (en) * | 1979-08-08 | 1983-12-27 | Mobil Oil Corporation | Method of preparing silico-crystal ZSM-48 |
EP0101183A1 (en) * | 1982-07-19 | 1984-02-22 | Mobil Oil Corporation | Synthesis of ZSM-5 and ZSM-11 utilizing a mixture of quaternary ammonium ions and amines |
US4514516A (en) * | 1981-08-28 | 1985-04-30 | Standard Oil Company (Indiana) | Method for manufacture of AMS-1B crystalline borosilicate molecular sieve with low sodium content |
EP0142348A2 (en) * | 1983-11-10 | 1985-05-22 | Exxon Research And Engineering Company | Process for preparing a zeolite of the L type using organic templates |
US4522800A (en) * | 1982-05-08 | 1985-06-11 | Hoechst Aktiengesellschaft | Process for the production of a crystalline aluminosilicate zeolite |
US4526879A (en) * | 1978-11-13 | 1985-07-02 | Mobil Oil Corporation | Synthesis of zeolite ZSM-5 |
US4528172A (en) * | 1982-10-13 | 1985-07-09 | Hoechst Aktiengesellschaft | Process for the manufacture of zeolites |
US4650656A (en) * | 1977-05-25 | 1987-03-17 | Mobil Oil Corporation | Large crystal ZSM-5 from template addition to the gel |
US4840779A (en) * | 1985-07-08 | 1989-06-20 | Uop | Crystalline zeolite LZ-202 and process for preparing same |
US5342596A (en) * | 1981-01-08 | 1994-08-30 | The British Petroleum Company Limited | Process for making theta-1 zeolite |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4175114A (en) * | 1973-12-13 | 1979-11-20 | Mobil Oil Corporation | Method for producing zeolites |
US4199556A (en) * | 1973-12-13 | 1980-04-22 | Mobil Oil Corporation | Method for producing zeolites |
NZ186957A (en) * | 1977-04-22 | 1979-10-25 | Mobil Oil Corp | Synthesis of crystalline aluminosilicate zeolite and catalytic conversion of organic compounds |
NL7803662A (en) * | 1978-04-06 | 1979-10-09 | Shell Int Research | PROCESS FOR THE PREPARATION OF ZEOLITES. |
NL7908984A (en) * | 1979-12-13 | 1981-07-16 | Shell Int Research | PROCESS FOR THE PREPARATION OF CRYSTALLINE SILICATES |
BR8200670A (en) * | 1981-02-09 | 1982-12-14 | Mobil Oil Corp | PROCESS TO SYNTHESIZE A ZEOLITE |
EP0159846B1 (en) * | 1984-04-16 | 1989-07-19 | Mobil Oil Corporation | Preparation of zeolite beta |
GB8413370D0 (en) * | 1984-05-24 | 1984-06-27 | British Petroleum Co Plc | Theta-3 |
EP0164045B1 (en) * | 1984-06-02 | 1989-04-05 | Hoechst Aktiengesellschaft | Process for the isomerisation of mono- or dichlorotoluene |
FR2567868A1 (en) * | 1984-07-20 | 1986-01-24 | Raffinage Cie Francaise | NOVEL PROCESS FOR THE SYNTHESIS OF ALUMINOSILICATE-LIKE ZEOLITES, PRODUCTS OBTAINED THEREBY, AND THE USE THEREOF |
DE69330963T2 (en) * | 1992-12-16 | 2002-04-25 | Chevron U.S.A. Inc., San Ramon | PRODUCTION OF ALUMINOSILICATE ZOLITHES |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3306922A (en) * | 1961-03-22 | 1967-02-28 | Union Carbide Corp | Molecular sieve adsorbents |
-
1971
- 1971-11-22 CA CA128241A patent/CA933911A/en not_active Expired
- 1971-12-16 IT IT3249671A patent/IT944038B/en active
- 1971-12-22 GB GB5955971A patent/GB1365318A/en not_active Expired
-
1972
- 1972-01-25 JP JP878672A patent/JPS5725490B1/ja active Pending
- 1972-01-27 AU AU38379/72A patent/AU461375B2/en not_active Expired
- 1972-03-16 DE DE19722212810 patent/DE2212810C3/en not_active Expired
- 1972-03-17 FR FR7209537A patent/FR2130430B1/fr not_active Expired
- 1972-03-17 NL NL7203646A patent/NL174453C/en not_active IP Right Cessation
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2643929A1 (en) * | 1975-09-29 | 1977-04-14 | Ici Ltd | METHOD OF PRODUCING ZEOLITHES |
US4650656A (en) * | 1977-05-25 | 1987-03-17 | Mobil Oil Corporation | Large crystal ZSM-5 from template addition to the gel |
EP0002899B1 (en) * | 1977-12-23 | 1983-03-16 | The British Petroleum Company p.l.c. | Method for preparing aluminosilicates and their use as catalyst supports and catalysts |
EP0002900A1 (en) * | 1977-12-23 | 1979-07-11 | The British Petroleum Company p.l.c. | Method for producing aluminosilicates and their use as catalysts and supports |
US4407728A (en) | 1977-12-23 | 1983-10-04 | The British Petroleum Company Limited | Method for producing crystalline aluminosilicates and their use as catalysts and catalyst supports |
US4242233A (en) | 1977-12-23 | 1980-12-30 | The British Petroleum Company Limited | Method for preparing aluminosilicates, their use as catalyst supports and catalysts, and method for producing catalysts therefrom |
US4346021A (en) | 1977-12-23 | 1982-08-24 | The British Petroleum Company Limited | Method for producing aluminosilicates, their use as catalysts and supports and method for producing catalysts therefrom |
US4478806A (en) * | 1977-12-23 | 1984-10-23 | The British Petroleum Company Limited | Crystalline aluminosilicates |
EP0011362A1 (en) * | 1978-11-13 | 1980-05-28 | Mobil Oil Corporation | Method for synthesis of zeolite ZSM-5 |
US4526879A (en) * | 1978-11-13 | 1985-07-02 | Mobil Oil Corporation | Synthesis of zeolite ZSM-5 |
US4376104A (en) * | 1979-01-05 | 1983-03-08 | The British Petroleum Company Limited | Method for preparing crystalline aluminosilicates |
EP0014546A1 (en) * | 1979-02-01 | 1980-08-20 | Mobil Oil Corporation | Preparation of nitrogenous zeolites and zeolites so prepared |
WO1980002026A1 (en) * | 1979-03-28 | 1980-10-02 | Grace W R & Co | A cyclic process for forming high purity zsm-5 catalyst |
EP0023089A1 (en) * | 1979-07-12 | 1981-01-28 | Mobil Oil Corporation | Method of preparing zeolite ZSM-48, the zeolite so prepared and its use as catalyst for organic compound conversion |
US4423021A (en) * | 1979-08-08 | 1983-12-27 | Mobil Oil Corporation | Method of preparing silico-crystal ZSM-48 |
EP0030811A1 (en) * | 1979-12-07 | 1981-06-24 | The British Petroleum Company p.l.c. | Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports |
US4377502A (en) * | 1979-12-26 | 1983-03-22 | Standard Oil Company (Indiana) | Synthesis of crystalline aluminosilicate molecular sieves |
US5342596A (en) * | 1981-01-08 | 1994-08-30 | The British Petroleum Company Limited | Process for making theta-1 zeolite |
US4514516A (en) * | 1981-08-28 | 1985-04-30 | Standard Oil Company (Indiana) | Method for manufacture of AMS-1B crystalline borosilicate molecular sieve with low sodium content |
US4522800A (en) * | 1982-05-08 | 1985-06-11 | Hoechst Aktiengesellschaft | Process for the production of a crystalline aluminosilicate zeolite |
EP0101183A1 (en) * | 1982-07-19 | 1984-02-22 | Mobil Oil Corporation | Synthesis of ZSM-5 and ZSM-11 utilizing a mixture of quaternary ammonium ions and amines |
US4528172A (en) * | 1982-10-13 | 1985-07-09 | Hoechst Aktiengesellschaft | Process for the manufacture of zeolites |
EP0142348A2 (en) * | 1983-11-10 | 1985-05-22 | Exxon Research And Engineering Company | Process for preparing a zeolite of the L type using organic templates |
EP0142348A3 (en) * | 1983-11-10 | 1987-11-19 | Exxon Research And Engineering Company | Process for preparing a zeolite of the l type using organic templates |
US4840779A (en) * | 1985-07-08 | 1989-06-20 | Uop | Crystalline zeolite LZ-202 and process for preparing same |
Also Published As
Publication number | Publication date |
---|---|
FR2130430B1 (en) | 1974-09-13 |
NL174453C (en) | 1984-06-18 |
DE2212810B2 (en) | 1981-06-11 |
AU3837972A (en) | 1973-08-02 |
NL7203646A (en) | 1972-09-20 |
CA933911A (en) | 1973-09-18 |
NL174453B (en) | 1984-01-16 |
AU461375B2 (en) | 1975-05-07 |
DE2212810A1 (en) | 1972-11-02 |
DE2212810C3 (en) | 1982-05-19 |
IT944038B (en) | 1973-04-20 |
FR2130430A1 (en) | 1972-11-03 |
JPS5725490B1 (en) | 1982-05-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |