GB1365318A - Method and preparation for crystalline aluminosilicate zeolites - Google Patents

Method and preparation for crystalline aluminosilicate zeolites

Info

Publication number
GB1365318A
GB1365318A GB5955971A GB5955971A GB1365318A GB 1365318 A GB1365318 A GB 1365318A GB 5955971 A GB5955971 A GB 5955971A GB 5955971 A GB5955971 A GB 5955971A GB 1365318 A GB1365318 A GB 1365318A
Authority
GB
United Kingdom
Prior art keywords
substituted
alkyl
cycloalkyl
aryl
crystalline aluminosilicate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5955971A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1365318A publication Critical patent/GB1365318A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2876—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures from a reacting mixture containing an amine or an organic cation, e.g. a quaternary onium cation-ammonium, phosphonium, stibonium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1365318 Organo-alumino-silicate zeolites MOBIL OIL CORP 22 Dec 1971 [18 March 1971] 59559/71 Heading C1A Crystalline aluminosilicate zeolites which contain organic nitrogen cations are synthesized by crystallization from a reaction mixture containing sources of silica, alumina, alkali, water and two compounds having formulµ R1R2R3N and R4X where R1, R2 and R3 are aryl, substituted aryl, alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl or hydrogen, R4 is aryl, substituted aryl, alkyl, substituted alkyl, cycloalkyl or substituted cycloalkyl and X is an electronegative group. The preferred reaction temperature is 250‹ to 750‹ F. In cases specified R1, R2, R3 and R4 are alkyl groups of C1 to C5 especially ethyl and propyl. In a modification, R1R2R3N is R1R2R4N and R4X is omitted. Certain reaction mixtures are specified, most of the products being members of the ZSM-4, 5, 8, 11 or 12 families.
GB5955971A 1971-03-18 1971-12-22 Method and preparation for crystalline aluminosilicate zeolites Expired GB1365318A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12589871A 1971-03-18 1971-03-18

Publications (1)

Publication Number Publication Date
GB1365318A true GB1365318A (en) 1974-08-29

Family

ID=22421975

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5955971A Expired GB1365318A (en) 1971-03-18 1971-12-22 Method and preparation for crystalline aluminosilicate zeolites

Country Status (8)

Country Link
JP (1) JPS5725490B1 (en)
AU (1) AU461375B2 (en)
CA (1) CA933911A (en)
DE (1) DE2212810C3 (en)
FR (1) FR2130430B1 (en)
GB (1) GB1365318A (en)
IT (1) IT944038B (en)
NL (1) NL174453C (en)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2643929A1 (en) * 1975-09-29 1977-04-14 Ici Ltd METHOD OF PRODUCING ZEOLITHES
EP0002900A1 (en) * 1977-12-23 1979-07-11 The British Petroleum Company p.l.c. Method for producing aluminosilicates and their use as catalysts and supports
EP0011362A1 (en) * 1978-11-13 1980-05-28 Mobil Oil Corporation Method for synthesis of zeolite ZSM-5
EP0014546A1 (en) * 1979-02-01 1980-08-20 Mobil Oil Corporation Preparation of nitrogenous zeolites and zeolites so prepared
WO1980002026A1 (en) * 1979-03-28 1980-10-02 Grace W R & Co A cyclic process for forming high purity zsm-5 catalyst
US4242233A (en) 1977-12-23 1980-12-30 The British Petroleum Company Limited Method for preparing aluminosilicates, their use as catalyst supports and catalysts, and method for producing catalysts therefrom
EP0023089A1 (en) * 1979-07-12 1981-01-28 Mobil Oil Corporation Method of preparing zeolite ZSM-48, the zeolite so prepared and its use as catalyst for organic compound conversion
EP0030811A1 (en) * 1979-12-07 1981-06-24 The British Petroleum Company p.l.c. Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports
US4376104A (en) * 1979-01-05 1983-03-08 The British Petroleum Company Limited Method for preparing crystalline aluminosilicates
US4377502A (en) * 1979-12-26 1983-03-22 Standard Oil Company (Indiana) Synthesis of crystalline aluminosilicate molecular sieves
US4423021A (en) * 1979-08-08 1983-12-27 Mobil Oil Corporation Method of preparing silico-crystal ZSM-48
EP0101183A1 (en) * 1982-07-19 1984-02-22 Mobil Oil Corporation Synthesis of ZSM-5 and ZSM-11 utilizing a mixture of quaternary ammonium ions and amines
US4514516A (en) * 1981-08-28 1985-04-30 Standard Oil Company (Indiana) Method for manufacture of AMS-1B crystalline borosilicate molecular sieve with low sodium content
EP0142348A2 (en) * 1983-11-10 1985-05-22 Exxon Research And Engineering Company Process for preparing a zeolite of the L type using organic templates
US4522800A (en) * 1982-05-08 1985-06-11 Hoechst Aktiengesellschaft Process for the production of a crystalline aluminosilicate zeolite
US4526879A (en) * 1978-11-13 1985-07-02 Mobil Oil Corporation Synthesis of zeolite ZSM-5
US4528172A (en) * 1982-10-13 1985-07-09 Hoechst Aktiengesellschaft Process for the manufacture of zeolites
US4650656A (en) * 1977-05-25 1987-03-17 Mobil Oil Corporation Large crystal ZSM-5 from template addition to the gel
US4840779A (en) * 1985-07-08 1989-06-20 Uop Crystalline zeolite LZ-202 and process for preparing same
US5342596A (en) * 1981-01-08 1994-08-30 The British Petroleum Company Limited Process for making theta-1 zeolite

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4175114A (en) * 1973-12-13 1979-11-20 Mobil Oil Corporation Method for producing zeolites
US4199556A (en) * 1973-12-13 1980-04-22 Mobil Oil Corporation Method for producing zeolites
NZ186957A (en) * 1977-04-22 1979-10-25 Mobil Oil Corp Synthesis of crystalline aluminosilicate zeolite and catalytic conversion of organic compounds
NL7803662A (en) * 1978-04-06 1979-10-09 Shell Int Research PROCESS FOR THE PREPARATION OF ZEOLITES.
NL7908984A (en) * 1979-12-13 1981-07-16 Shell Int Research PROCESS FOR THE PREPARATION OF CRYSTALLINE SILICATES
BR8200670A (en) * 1981-02-09 1982-12-14 Mobil Oil Corp PROCESS TO SYNTHESIZE A ZEOLITE
DE3571598D1 (en) * 1984-04-16 1989-08-24 Mobil Oil Corp Preparation of zeolite beta
GB8413370D0 (en) * 1984-05-24 1984-06-27 British Petroleum Co Plc Theta-3
DE3569235D1 (en) * 1984-06-02 1989-05-11 Hoechst Ag Process for the isomerisation of mono- or dichlorotoluene
FR2567868A1 (en) * 1984-07-20 1986-01-24 Raffinage Cie Francaise NOVEL PROCESS FOR THE SYNTHESIS OF ALUMINOSILICATE-LIKE ZEOLITES, PRODUCTS OBTAINED THEREBY, AND THE USE THEREOF
JP4099223B2 (en) * 1992-12-16 2008-06-11 シェブロン ユー．エス．エー．インコーポレイテッド Production of crystalline zeolite

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3306922A (en) * 1961-03-22 1967-02-28 Union Carbide Corp Molecular sieve adsorbents

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2643929A1 (en) * 1975-09-29 1977-04-14 Ici Ltd METHOD OF PRODUCING ZEOLITHES
US4650656A (en) * 1977-05-25 1987-03-17 Mobil Oil Corporation Large crystal ZSM-5 from template addition to the gel
EP0002899B1 (en) * 1977-12-23 1983-03-16 The British Petroleum Company p.l.c. Method for preparing aluminosilicates and their use as catalyst supports and catalysts
EP0002900A1 (en) * 1977-12-23 1979-07-11 The British Petroleum Company p.l.c. Method for producing aluminosilicates and their use as catalysts and supports
US4407728A (en) 1977-12-23 1983-10-04 The British Petroleum Company Limited Method for producing crystalline aluminosilicates and their use as catalysts and catalyst supports
US4242233A (en) 1977-12-23 1980-12-30 The British Petroleum Company Limited Method for preparing aluminosilicates, their use as catalyst supports and catalysts, and method for producing catalysts therefrom
US4346021A (en) 1977-12-23 1982-08-24 The British Petroleum Company Limited Method for producing aluminosilicates, their use as catalysts and supports and method for producing catalysts therefrom
US4478806A (en) * 1977-12-23 1984-10-23 The British Petroleum Company Limited Crystalline aluminosilicates
EP0011362A1 (en) * 1978-11-13 1980-05-28 Mobil Oil Corporation Method for synthesis of zeolite ZSM-5
US4526879A (en) * 1978-11-13 1985-07-02 Mobil Oil Corporation Synthesis of zeolite ZSM-5
US4376104A (en) * 1979-01-05 1983-03-08 The British Petroleum Company Limited Method for preparing crystalline aluminosilicates
EP0014546A1 (en) * 1979-02-01 1980-08-20 Mobil Oil Corporation Preparation of nitrogenous zeolites and zeolites so prepared
WO1980002026A1 (en) * 1979-03-28 1980-10-02 Grace W R & Co A cyclic process for forming high purity zsm-5 catalyst
EP0023089A1 (en) * 1979-07-12 1981-01-28 Mobil Oil Corporation Method of preparing zeolite ZSM-48, the zeolite so prepared and its use as catalyst for organic compound conversion
US4423021A (en) * 1979-08-08 1983-12-27 Mobil Oil Corporation Method of preparing silico-crystal ZSM-48
EP0030811A1 (en) * 1979-12-07 1981-06-24 The British Petroleum Company p.l.c. Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports
US4377502A (en) * 1979-12-26 1983-03-22 Standard Oil Company (Indiana) Synthesis of crystalline aluminosilicate molecular sieves
US5342596A (en) * 1981-01-08 1994-08-30 The British Petroleum Company Limited Process for making theta-1 zeolite
US4514516A (en) * 1981-08-28 1985-04-30 Standard Oil Company (Indiana) Method for manufacture of AMS-1B crystalline borosilicate molecular sieve with low sodium content
US4522800A (en) * 1982-05-08 1985-06-11 Hoechst Aktiengesellschaft Process for the production of a crystalline aluminosilicate zeolite
EP0101183A1 (en) * 1982-07-19 1984-02-22 Mobil Oil Corporation Synthesis of ZSM-5 and ZSM-11 utilizing a mixture of quaternary ammonium ions and amines
US4528172A (en) * 1982-10-13 1985-07-09 Hoechst Aktiengesellschaft Process for the manufacture of zeolites
EP0142348A2 (en) * 1983-11-10 1985-05-22 Exxon Research And Engineering Company Process for preparing a zeolite of the L type using organic templates
EP0142348A3 (en) * 1983-11-10 1987-11-19 Exxon Research And Engineering Company Process for preparing a zeolite of the l type using organic templates
US4840779A (en) * 1985-07-08 1989-06-20 Uop Crystalline zeolite LZ-202 and process for preparing same

Also Published As

Publication number Publication date
AU461375B2 (en) 1975-05-07
CA933911A (en) 1973-09-18
DE2212810B2 (en) 1981-06-11
FR2130430A1 (en) 1972-11-03
NL174453C (en) 1984-06-18
FR2130430B1 (en) 1974-09-13
AU3837972A (en) 1973-08-02
NL174453B (en) 1984-01-16
JPS5725490B1 (en) 1982-05-29
DE2212810A1 (en) 1972-11-02
DE2212810C3 (en) 1982-05-19
NL7203646A (en) 1972-09-20
IT944038B (en) 1973-04-20

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee