GB1364367A - Epoxidation of olefinically unsaturated compounds - Google Patents

Epoxidation of olefinically unsaturated compounds

Info

Publication number
GB1364367A
GB1364367A GB3196372A GB3196372A GB1364367A GB 1364367 A GB1364367 A GB 1364367A GB 3196372 A GB3196372 A GB 3196372A GB 3196372 A GB3196372 A GB 3196372A GB 1364367 A GB1364367 A GB 1364367A
Authority
GB
United Kingdom
Prior art keywords
compounds
alcohol
july
catalyst
epoxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3196372A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MIJ NV
Shell Internationale Research Maatschappij BV
Original Assignee
MIJ NV
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MIJ NV, Shell Internationale Research Maatschappij BV filed Critical MIJ NV
Priority to GB3196372A priority Critical patent/GB1364367A/en
Priority to CA171,420A priority patent/CA1001640A/en
Priority to BE1005199A priority patent/BE801574A/en
Priority to IT2613773A priority patent/IT990889B/en
Priority to NL7309386A priority patent/NL7309386A/xx
Priority to FR7324710A priority patent/FR2192100B1/fr
Priority to ES416604A priority patent/ES416604A1/en
Priority to DE19732334315 priority patent/DE2334315A1/en
Priority to JP48075347A priority patent/JPS4955609A/ja
Publication of GB1364367A publication Critical patent/GB1364367A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1364367 Epoxidation process SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 5 July 1973 [7 July 1972] 31963/72 Heading C2C Oxirane compounds are prepared by reacting an ethylenically unsaturated compound with an organic hydroperoxide in the presence of one or more transition metal compounds as catalyst and of one or more chlorinated aliphatic hydrocarbons containing 2 or 3 carbon atoms and 3-5 chlorine atoms in the molecule as solvent. Suitable solvents are for example those of formula HC(Cl) 2 .C(Cl) 2 R in which R is H or Cl and the corresponding ethylenic compounds derived therefrom by dehydrochlorination. The catalyst may be soluble in the reaction medium, e.g. naphthenates, carbonyls and acetyl acetylacetonates of molybdenum, tungsten, titanium, zirconium and vanadium, or an insoluble salt, e.g. TiCl 4 , deposited on a support, e.g. Bilica. Suitable unsaturated compounds for use as starting materials are, for example, propene, butenes, 1-octene, 1-hexadecene, 1,3-butadiene, cyclohexene, cyclododecene, 1,5,9-cyclododecatriene, styrene, methylstyrene, allyl chloride, allyl alcohol, methallyl alcohol, crotyl alcohol and methyl oleate.
GB3196372A 1972-06-06 1972-07-07 Epoxidation of olefinically unsaturated compounds Expired GB1364367A (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
GB3196372A GB1364367A (en) 1972-07-07 1972-07-07 Epoxidation of olefinically unsaturated compounds
CA171,420A CA1001640A (en) 1972-07-07 1973-05-15 Epoxidation of olefinically unsaturated compounds
BE1005199A BE801574A (en) 1972-07-07 1973-06-28 PROCEDURE FOR EPOXYDING OLEFINIC UNSATURATED COMPOUNDS
IT2613773A IT990889B (en) 1972-06-06 1973-07-03 EPOXY OF UNSATURATED OLEPHIN COMPOUNDS SELECTIVE DRIVE MECHANISM FOR A SERIES OF PERCUSSION LAMPS FOR LAMP PHOTOGRAPHY
NL7309386A NL7309386A (en) 1972-07-07 1973-07-05
FR7324710A FR2192100B1 (en) 1972-07-07 1973-07-05
ES416604A ES416604A1 (en) 1972-07-07 1973-07-05 Epoxidation of olefinically unsaturated compounds
DE19732334315 DE2334315A1 (en) 1972-07-07 1973-07-05 PROCESS FOR THE PREPARATION OF OXIRANE COMPOUNDS BY EPOXIDIZATION OF ETHYLENIC UNSATURIZED OLEFINS
JP48075347A JPS4955609A (en) 1972-07-07 1973-07-05

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3196372A GB1364367A (en) 1972-07-07 1972-07-07 Epoxidation of olefinically unsaturated compounds

Publications (1)

Publication Number Publication Date
GB1364367A true GB1364367A (en) 1974-08-21

Family

ID=10330997

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3196372A Expired GB1364367A (en) 1972-06-06 1972-07-07 Epoxidation of olefinically unsaturated compounds

Country Status (8)

Country Link
JP (1) JPS4955609A (en)
BE (1) BE801574A (en)
CA (1) CA1001640A (en)
DE (1) DE2334315A1 (en)
ES (1) ES416604A1 (en)
FR (1) FR2192100B1 (en)
GB (1) GB1364367A (en)
NL (1) NL7309386A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111732559A (en) * 2020-06-17 2020-10-02 吴剑华 Chlorohydrin method epoxide production method of cyclic calcium carbonate dehydrochlorination

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6187934B1 (en) * 1997-03-26 2001-02-13 Sumitomo Chemical Company Limited Titanium-containing solid catalyst
JP4863256B2 (en) * 2005-11-16 2012-01-25 エア・ウォーター・ゾル株式会社 Suction type injector
JP4966068B2 (en) * 2007-03-29 2012-07-04 エア・ウォーター・ゾル株式会社 Suction type injector

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111732559A (en) * 2020-06-17 2020-10-02 吴剑华 Chlorohydrin method epoxide production method of cyclic calcium carbonate dehydrochlorination

Also Published As

Publication number Publication date
CA1001640A (en) 1976-12-14
BE801574A (en) 1973-12-28
DE2334315A1 (en) 1974-01-24
ES416604A1 (en) 1976-02-16
NL7309386A (en) 1974-01-09
FR2192100A1 (en) 1974-02-08
JPS4955609A (en) 1974-05-30
FR2192100B1 (en) 1976-11-12

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee