GB1358068A - Continuous manufacture of alkali metal salts of amino polyacetic acids - Google Patents
Continuous manufacture of alkali metal salts of amino polyacetic acidsInfo
- Publication number
- GB1358068A GB1358068A GB4643571A GB4643571A GB1358068A GB 1358068 A GB1358068 A GB 1358068A GB 4643571 A GB4643571 A GB 4643571A GB 4643571 A GB4643571 A GB 4643571A GB 1358068 A GB1358068 A GB 1358068A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkali metal
- solution
- metal cyanide
- cyanide
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Abstract
1358068 Amino polyacetic acids BADISCHE ANILIN- & SODA-FABBIK AG 6 Oct 1971 [7 Oct 1970] 46435/71 Heading C2C [Also in Division G1] Alkali metal salts of amino polyacetic acid<SP>s</SP> are prepared from formaldehyde and an alkali metal cyanide or from formaldehyde, a non- aromatic diamine or triamine and an alkali metal cyanide in aqueous solution at elevated temperature in at least two reaction zones conheated in cascade, the formaldehyde solution and (where used) the stoichiometric amount of a solution of the amine being passed to the first zone or zones and the alkali metal cyanide solution being simultaneously metered thereto under the control of a potentiometric cell or cells such that the alkali metal cyanide concentration in the first zone or zones, as determined by the potentiometric cell or cells, assumes a nearly constant value, this being chosen so that the alkali metal cyanide concentration in the final reaction zone (which may also be determined by a potentiometric cell) is not more than 100 p.p.m. The potentiometric cell may comprise a noble metal electrode, e.g. of gold or silver, dipping into the solution whose cyanide concentration is to be measured and/or controlled, and connected to a reference, e.g. calomel, electrode in contact with the solution by way of a diaphragm. The resulting p.d. may be measured to determine the cyanide concentration, or used to control a metering device, e.g. a magnetic valve pre-set to operate at a given p.d., for the fed cyanide solution. With CH 2 O and alkali metal cyanide the product is a salt of nitrilotriacetic acid; with amines the product is a salt of the corresponding aminoacetic acid; specified amines are 1,2- and 1,3-propylenediamine, ethylenediamine, hexamethylenediamine, 1,2-diaminocyclohexane, piperazine and diethylenetriamine. Byproduct ammonia is preferably removed, e.g. by passage of an inert gas.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702049223 DE2049223C3 (en) | 1970-10-07 | Process for the continuous production of the alkali salts of aminopolyacetic acids |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1358068A true GB1358068A (en) | 1974-06-26 |
Family
ID=5784432
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4643571A Expired GB1358068A (en) | 1970-10-07 | 1971-10-06 | Continuous manufacture of alkali metal salts of amino polyacetic acids |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS5220967B1 (en) |
AT (1) | AT309396B (en) |
BE (1) | BE773447A (en) |
CA (1) | CA943558A (en) |
CH (1) | CH555319A (en) |
FR (1) | FR2109846A5 (en) |
GB (1) | GB1358068A (en) |
IT (1) | IT942206B (en) |
NL (1) | NL157294B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101723842B (en) * | 2009-11-06 | 2012-11-07 | 重庆紫光鼎福化工有限责任公司 | Method for preparing ethylene diamine tetraacetic acid (EDTA) disodium salt |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6030735U (en) * | 1983-08-05 | 1985-03-01 | リンナイ株式会社 | Baking machine |
-
1971
- 1971-08-17 CH CH1206571A patent/CH555319A/en not_active IP Right Cessation
- 1971-09-21 NL NL7112973A patent/NL157294B/en not_active IP Right Cessation
- 1971-09-28 FR FR7134820A patent/FR2109846A5/fr not_active Expired
- 1971-10-02 JP JP7683871A patent/JPS5220967B1/ja active Pending
- 1971-10-04 BE BE773447A patent/BE773447A/en not_active IP Right Cessation
- 1971-10-05 IT IT5327571A patent/IT942206B/en active
- 1971-10-06 AT AT861771A patent/AT309396B/en not_active IP Right Cessation
- 1971-10-06 GB GB4643571A patent/GB1358068A/en not_active Expired
- 1971-10-06 CA CA124,613A patent/CA943558A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101723842B (en) * | 2009-11-06 | 2012-11-07 | 重庆紫光鼎福化工有限责任公司 | Method for preparing ethylene diamine tetraacetic acid (EDTA) disodium salt |
Also Published As
Publication number | Publication date |
---|---|
DE2049223B2 (en) | 1976-07-08 |
BE773447A (en) | 1972-04-04 |
CA943558A (en) | 1974-03-12 |
JPS5220967B1 (en) | 1977-06-07 |
NL7112973A (en) | 1972-04-11 |
AT309396B (en) | 1973-08-10 |
CH555319A (en) | 1974-10-31 |
NL157294B (en) | 1978-07-17 |
DE2049223A1 (en) | 1972-04-13 |
FR2109846A5 (en) | 1972-05-26 |
IT942206B (en) | 1973-03-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |