GB1353544A - Supported bismuth/phosphorus molybdate catalysts - Google Patents
Supported bismuth/phosphorus molybdate catalystsInfo
- Publication number
- GB1353544A GB1353544A GB2112471A GB2112471A GB1353544A GB 1353544 A GB1353544 A GB 1353544A GB 2112471 A GB2112471 A GB 2112471A GB 2112471 A GB2112471 A GB 2112471A GB 1353544 A GB1353544 A GB 1353544A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- weight per
- per cent
- bismuth
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052797 bismuth Inorganic materials 0.000 title abstract 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 4
- 239000011574 phosphorus Substances 0.000 title abstract 4
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 title 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- 229910052750 molybdenum Inorganic materials 0.000 abstract 3
- 239000011733 molybdenum Substances 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 abstract 1
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
1353544 Acrylonitrile ERDOLCHEMIE GmbH 19 April 1971 [20 Feb 1970] 21124/71 Heading C2C [Also in Division B1] Ammoxidation is effected in the presence of catalyst which consists essentially of support material in association with bismuth, molybdenum and, optionally, phosphorus in oxidic form and which has been heated at a temperature of from 600 to 750 C., advantageously from 620 to 670 C. for example for a period of from 0À5 to 20 hours, advantageously from 3 to 5 hours, the catalyst being either fresh catalyst or catalyst which has been used in ammoxidation prior to such heating. The support material may constitute less than 85 weight per cent of the catalyst which may contain from 10 to 30 weight per cent bismuth, from 6 to 18 weight per cent molybdenum and up to 1 weight per cent phosphorus and which may have been prepared by a generally conventional procedure involving coprecipitation, impregnation or spray drying. Examples relate to the preparation of acrylonitrile by a procedure wherein a gaseous mixture comprising propylene, ammonia, air and steam is contacted, at a temperature of 460 C. and a pressure of 1À2-1À3 atmospheres, with a fluidized bed of catalyst which contains silica support material, bismuth and molybdenum, either with (Examples 1 to 4) or without (Example 5) phosphorus, which has been heated to a temperature in the 500-700 C. range and which either has been used in the ammoxidation of propylene prior to such heating (Example 1) or is fresh catalyst (Examples 2 to 5). Reference is made to Specification 867,458 in respect of catalyst preparation.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702007795 DE2007795C3 (en) | 1970-02-20 | Process for increasing the effectiveness of bismuth molybdate supported catalysts, which may contain phosphorus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1353544A true GB1353544A (en) | 1974-05-22 |
Family
ID=5762802
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2112471A Expired GB1353544A (en) | 1970-02-20 | 1971-04-19 | Supported bismuth/phosphorus molybdate catalysts |
Country Status (5)
| Country | Link |
|---|---|
| AT (1) | AT302255B (en) |
| BE (1) | BE763220A (en) |
| FR (1) | FR2078872A5 (en) |
| GB (1) | GB1353544A (en) |
| NL (1) | NL7101706A (en) |
-
1971
- 1971-02-09 NL NL7101706A patent/NL7101706A/xx unknown
- 1971-02-17 AT AT135371A patent/AT302255B/en not_active IP Right Cessation
- 1971-02-19 FR FR7105840A patent/FR2078872A5/fr not_active Expired
- 1971-02-19 BE BE763220A patent/BE763220A/en unknown
- 1971-04-19 GB GB2112471A patent/GB1353544A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AT302255B (en) | 1972-10-10 |
| FR2078872A5 (en) | 1971-11-05 |
| BE763220A (en) | 1971-08-19 |
| DE2007795A1 (en) | 1971-09-02 |
| DE2007795B2 (en) | 1976-01-29 |
| NL7101706A (en) | 1971-08-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |